Samsung Sdi Co., Inc.

Samsung Electronics Co., Ltd.

Sang-kook Mah

Jae-jun Lee

Han-su Kim

Myung-Sup Jung

Jin-gyu Lee

Do-yun Kim

Dong-min Im

Young-Gyoon Ryu

Gue-sung Kim

Ryoung-hee Kim

Jao-jun Lee

An anode active material for a lithium rechargeable battery, the anode active material including: a base material which is alloyable with lithium and a metal nitride disposed on the base material.

Anode active material for lithium rechargeable battery, method of preparing the same, and lithium battery including the anode active material

An electrode active material, a method of preparing the electrode active material, an electrode including the electrode active material, and a lithium secondary battery including the electrode; the electrode active material comprising a core active material; and a coating layer formed on a surface of the core active material, wherein the coating layer comprises a composition including a compound represented by Formula 1 below and a carbonaceous material, or a first coating layer including a carbonaceous material and a second coating layer including the compound represented by Formula 1 below:LiM(PO),&#x2003;&#x2003;Formula 1

Electrode active material, method of preparing electrode active material, electrode including electrode active material, and lithium secondary battery including electrode

An Si/C composite includes carbon (C) dispersed in porous silicon (Si) particles. The Si/C composite may be used to form an anode active material to provide a lithium battery having a high capacity and excellent capacity retention.

Si/C composite, anode active materials, and lithium battery including the same

Provided are a porous anode active material, a method of preparing the same, and an anode and a lithium battery employing the same. The porous anode active material includes fine particles of metallic substance capable of forming a lithium alloy; a crystalline carboneous substance; and a porous carboneous material coating and attaching to the fine particles of metallic substance and the crystalline carboneous substance, the porous anode active material having pores exhibiting a bimodal size distribution with two pore diameter peaks as measured by a Barrett-Joyner-Halenda (BJH) pore size distribution from a nitrogen adsorption. The porous anode active material has the pores having a bimodal size distribution, and thus may efficiently remove a stress occurring due to a difference of expansion between a carboneous material and a metallic active material during charging and discharging. Further, the anode electrode and the lithium battery comprising the anode active material have excellent charge/discharge characteristics.

Porous anode active material, method of preparing the same, and anode and lithium battery employing the same

Provided is a composite for anode material, a method of manufacturing the composite for anode material, and a cathode and a lithium battery that includes the composite for anode material, and more particularly, to a composite for anode material that has a large charge and discharge capacity and a high capacity retention, a method of manufacturing the composite for anode material, and a cathode and a lithium battery that includes the composite for anode material. Also, the composite for anode material in which Si or Si and carbon are distributed in silicon oxide particles is provided.

Composite for anode material, anode materials and lithium battery using the same

Provided are a dendrimer solid acid and a polymer electrolyte membrane using the same. The polymer electrolyte membrane includes a macromolecule of a dendrimer solid acid having ionically conductive terminal groups at the surface thereof and a minimum amount of ionically conductive terminal groups required for ionic conduction, thus suppressing swelling and allowing a uniform distribution of the dendrimer solid acid, thereby improving ionic conductivity. Since the number of ionically conductive terminal groups in the polymer electrolyte membrane is minimized and the polymer matrix in which swelling is suppressed is used, methanol crossover and difficulties of outflow due to a large volume may be reduced, and a macromolecule of the dendrimer solid acid having the ionically conductive terminal groups on the surface thereof is uniformly distributed. Accordingly, ionic conductivity is high and thus, the polymer electrolyte membrane shows good ionic conductivity even in non-humidified conditions.

Dendrimer solid acid and polymer electrolyte membrane including the same

A solid acid having a core of calixarene or calix resorcinarene. The solid acid is an ion conducting compound in which at least one of the hydroxyl groups is substituted by an organic group having a cation exchange group at a terminal end, a polymer electrolyte membrane including the same, and a fuel cell using the polymer electrolyte membrane. The polymer electrolyte membrane can provide low methanol crossover and high ionic conductivity. Accordingly, a fuel cell having high efficiency can be obtained by using the polymer electrolyte membrane.

Solid acid, polymer electrolyte membrane including the same, and fuel cell using the polymer electrolyte membrane

A sulfonated copolymer including a crosslinking functional group and a fuel cell including a polymeric composition of the same are provided. The sulfonated copolymer including a crosslinking functional group can remarkably reduce methanol crossover and maintain superior dimensional stability and ionic conductivity by reducing swelling.

Crosslinkable sulfonated copolymer and fuel cell including polymeric composition of the same

An ion-conducting, sulfonated and crosslinked copolymer for use in a fuel cell is disclosed. The ion-conducting, sulfonated and crosslinked copolymer is made up of four monomers. The first monomer is an aromatic diol. The second monomer includes two groups, each group capable of reacting with the hydroxy groups of the first monomer, and each group independently selected from a nitro group and a halogen group. The third monomer is one of the first monomer or the second monomer, except that one of the hydrogen atoms attached to a benzene ring is substituted with &#x2014;SOY, where Y is selected from hydrogen (H), lithium (Li), sodium (Na), potassium (K) and trialkyl ammonium of the form HNRwhere R is an alkyl group having from 1 to 5 carbon atoms. The fourth monomer includes at least three groups, each independently selected from a hydroxy group, a nitro group, and a halogen group.

Ion-conducting crosslinked copolymer and fuel cell comprising the same

A polymer electrolyte membrane including a polysilsesquioxane group-containing copolymer and an ionic conductive polymer is provided. A method of preparing the polymer electrolyte membrane and a fuel cell including the polymer electrolyte membrane is also provided. The polymer electrolyte membrane has improved ion conductivity and an improved ability to suppress methanol crossover, and therefore can be used as an electrolyte membrane for a fuel cell, including a direct methanol fuel cell.

Polymer electrolyte membrane, method of preparing the same and fuel cell including the same

A solid acid including a carbon nanotube (CNT), a spacer group combined with the CNT and an ionically conductive functional group connected to the spacer group. A polymer electrolyte membrane may include the same composition, and may be used in a fuel cell. The polymer electrolyte membrane using the solid acid has excellent ionic conductivity and suppresses the cross-over of methanol. The polymer electrolyte membrane is used as an electrolyte membrane of a fuel cell, for example, a direct methanol fuel cell.

Polymer electrolyte membrane and fuel cell including the polymer electrolyte membrane

Silicon oxide based composite anode active materials including amorphous silicon oxides are provided. In one embodiment, the amorphous silicon oxide is represented by SiO(where 0&#x3c;x&#x3c;2), has a binding energy of about 103 to about 106 eV, a silicon peak with a full width at half maximum (FWHM) ranging from about 1.6 to about 2.4 as measured by X-ray photoelectron spectrometry, and an atomic percentage of silicon greater than or equal to about 10 as calculated from an area of the silicon peak. The anode active material is a composite anode active material obtained by sintering hydrogen silsesquioxane (HSQ). Anodes and lithium batteries including the anode active material exhibit improved charge and discharge characteristics.

Anode active material, method of preparing the same, and anode and lithium battery containing the material

A polysiloxane compound and a fuel cell including the same where the polysiloxane compound is an organic polymer siloxane compound containing sulfonic acid groups. By using the organic polymer siloxane compound containing sulfonic acid groups, a polymer electrolyte membrane having superior characteristics such as dimensional stability and ionic conductivity, without affecting the amount of methanol crossover, can be obtained by reducing swelling due to liquids.

Growing community of inventors

Seoul, South Korea

Sang-kook Mah