The Dow Chemical Company

Noding, Stephen A.

Siegel, Sanford A.

Sanford A Siegel

Stephen A Noding

Che-I Kao

Masao Yoshimine

Donald W Pennington

This invention relates to a solid polyelectrolyte polymer film which comprises a polymer, a plasticizer for the polymer, an epoxidized vegetable oil, and an electrolyte.

Solid polyelectrolyte polymer film

This invention relates to a static dissipative laminate film produced by: coating a surface of a first plasticized thermoplastic film with graphite or carbon; overlaying the coated surface of the first film with a second plasticized thermoplastic film; and pressing the first and second films together to form a laminate film.

Static dissipative thermoplastic laminate film

This invention relates to a secondary battery comprised of a polymer film, and first and second collector plates. The polymer film comprises a polymer, a plasticizer for the polymer, an epoxidized vegetable oil, graphite and a salt disassociatingly solubilized by the plasticizer. The salt has the formula MX.sub.a, wherein X is chloride, bromide or iodide, M is a metal ion having a reduction-oxidation potential greater than that of X and a is the oxidation number of M.

Secondary battery

This invention relates to a secondary battery comprised of three polymer films, the third containing an electrolyte and the first and second containing an electrochemical species which may be in an anodic or a cathodic state depending upon whether the battery is discharging or is being recharged. The third polymer sheet is substantially not electrically conductive under battery discharge voltages, but is electrically conductive under battery recharge voltages. The first and second sheets are electrically conductive under both the discharge and recharge voltages. In a preferred form, the electrolyte and the electrochemical species are uniformly distributed within their respective films by dissolving the electrolyte and the species in a plasticizer which is incorporated within the polymer films.

A composition having utility as a plasticizer for halogen-containing resins is a mixture of (a) at least two diesters of terephthalic acid or (b) at least two triesters of trimellitic acid. The diesters of terephthalic acid are represented by the general formula ##STR1## wherein R.sub.1 is a phenyl radical or an aliphatic hydrocarbon radical of the formula C.sub.n H.sub.m, wherein n is an integer of 1 through 8 inclusive and m is equal to 2n+1; R.sub.2 is either hydrogen or an aliphatic hydrocarbon having one, two, three or four carbon atoms; x is an integer of 2 to 4 inclusive; y is an integer of 2 to 4 inclusive. The trialkyl esters of trimellitic acid are represented by the general formula ##STR2## wherein R.sub.1 is a phenyl radical or an aliphatic hydrocarbon radical of the formula C.sub.n H.sub.m wherein n is an integer of 1 through 8 inclusive and m is equal to 2n+1; R.sub.2 is either hydrogen or an aliphatic hydrocarbon radical having one, two, three or four carbon atoms; a is 2, 3 or 4; b is 2, 3 or 4; and c is 2, 3 or 4. The composition provides a unique combination of properties which includes high plasticizing efficiency, low volatility, good low temperature properties and resistance to hexane extraction.

Monomeric plasticizers for halogen-containing resins

A composition having utility as a plasticizer for halogen-containing resins is a mixture of (a) at least two diesters of terephthalic acid or (b) at least two triesters of trimellitic acid. The diesters of terephthalic acid are represented by the general formula ##STR1## wherein R.sub.1 is a phenyl radical or an aliphatic hydrocarbon radical of the formula C.sub.n H.sub.m, wherein n is an integer of 1 through 8 inclusive and m is equal to 2n+1; R.sub.2 is either hydrogen or an aliphatic hydrocarbon having one, two, three or four carbon atoms; x is an integer of 2 to 4 inclusive; y is an integer of 2 to 4 inclusive; The trialkyl esters of trimellitic acid are represented by the general formula ##STR2## wherein R.sub.1 is a phenyl radical or an aliphatic hydrocarbon radical of the formula C.sub.n H.sub.m wherein n is an integer of 1 through 8 inclusive and m is equal to 2n+1; R.sub.2 is either hydrogen or an aliphatic hydrocarbon radical having one, two, three or four carbon atoms; a is 2, 3 or 4; b is 2, 3 or 4; and c is 2, 3 or 4. The composition provides a unique combination of properties which includes high plasticizing efficiency, low volatility, good low temperature properties and resistance to hexane extraction.

A molten substituted phenol and an aqueous caustic solution are reacted at temperatures from 170.degree. C. to 190.degree. C. under superatmospheric pressure to form an aqueous solution of an alkali metal phenate. By employing a rapid drying process such as flashing the water vapor from the reactor to cool the mixture, alkali metal phenate solids are produced with low levels of toxic by-products.

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Baton Rouge, LA, United States of America

Sanford A Siegel