Commissariat &#xc0; L'&#xc9;nergie Atomique Et Aux &#xc9;nergies Alternatives

Orano Cycle

Sandra Lopes Moreira

Pascal Baron

Manuel Miguirditchian

Cécile Marie

Gaëlle Milanole

Novel dissymmetric N,N-dialkylamides which meet the following formula (I): where R represents a linear or branched alkyl group at Cto C. A method for synthesizing these N,N-dialkylamides, and to the uses of same as extractants, alone or in admixture, in order to extract uranium and/or plutonium from an aqueous acid solution, or to totally or separate uranium from plutonium from an aqueous acid solution and, in particular, an aqueous solution resulting from dissolving spent nuclear fuel in nitric acid. Further, a method for processing an aqueous solution resulting from the dissolution of a spent nuclear fuel in nitric acid, allowing the uranium and plutonium contained in the solution to be extracted, separated and decontaminated in a single cycle, without requiring any plutonium reduction operation, and in which one of the aforementioned N,N-dialkylamides or a mixture of same is used as extractant. Applications for the method include the processing of spent nuclear fuels, in particular comprising uranium (e.g. UOX) or uranium and plutonium (e.g. MOX).

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Nantes, France

Sandra Lopes Moreira