Engelhard Corporation

Basf Corporation

Basf Catalysts LLC

Motorola Corporation

Basf Mobile Emissions Catalysts LLC

Sanath V Kumar

Kenneth Edwin Voss

Kevin A Hallstrom

Susanne Stiebels

Marius Vaarkamp

Harold N Rabinowitz

Michel Deeba

Martin Dieterle

Stanley Allen Roth

Ronald Marshall Heck

Patrick L Burk

John Joseph Steger

R Samuel Boorse

Matthew Tyler Caudle

Jeffrey D Naber

Alan J Chewter

Weiyong Tang

Frank C Briden

David M Youngren

David Richard Price

James Rogalo

Samuel R Boorse

Provided are catalyst articles, methods and systems for treating lean burn engine exhaust. Catalyst articles include selective catalytic reduction catalyst on a particulate filter. The SCR catalyst on the particulate filter provides limited NOx conversion so that unconverted NOis available to facilitate passive oxidation of soot trapped on the particulate filter by reaction with NO. Systems and methods utilize such catalytic articles, and further include, e.g., a downstream selective catalytic reduction catalyst on a flow through substrate.

Filter catalyzed with SCR catalyst, systems and methods

Zoned diesel oxidation catalysts containing a higher precious metal loading in the inlet zone that the outlet zone and an equal or shorter length inlet zone are described. Emission treatment systems and methods of remediating nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons using zoned diesel oxidation catalysts are also described.

Emission treatment catalysts, systems and methods

An emission treatment system and method for remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams are described. The emission treatment system has an oxidation catalyst upstream of a soot filter upstream from a NOx reducing catalyst.

Emission treatment system

Systems and methods for abating NOx in an exhaust stream are provided. System using a lean NOx trap, an air injector and optional catalysts and filters are described. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.

Emissions treatment system with lean NOx trap

Catalysts and catalytic articles for treating exhaust gas streams are described. In one or more embodiments, a catalyst system includes a first zone to abate nitrogen oxides by selective catalytic reduction, a second zone to oxidize ammonia and a third zone to oxidize carbon monoxide and hydrocarbons. Methods for treating the exhaust gas stream are also provided. Methods of making and using such catalysts and catalytic articles are also described.

Integrated SCR and AMOx catalyst systems

Provided is an exhaust article (catalyst) coated on a single substrate, such as a monolithic honeycomb having a plurality of channels along the axial length of the catalyst. Different washcoat compositions are deposited along the length the channel walls of the substrate beginning from either the inlet or outlet axial end of the substrate to form inlet and outlet catalyst layers, respectively. In the coating process, the channel walls are coated with catalyst washcoat compositions to lengths that are less than the substrates' axial length. The architecture of the resulting catalyst layers defines a plurality of zones along the length of the substrate. The properties of each zone of the catalyst can be optimized to address specific catalyst functions by manipulation of both the coating lengths and the catalyst washcoat compositions.

Multi-zone catalytic converter

The present invention is directed to an emission treatment system for the treatment and/or conversion of engine emissions and particulate matter from diesel engines. The emission treatment system of the present invention comprises an upstream oxidation catalyst, a particulate filter or soot filter section and optionally a downstream catalytic element or clean-up catalyst for the treatment and/or conversion of any remaining emission gas stream contaminants.

DOC and particulate control system for diesel engines

Provided are coated, multi-zoned catalyst substrates that trap and combust hydrocarbon and nitrogen oxides pollutants in a single monolith substrate. In some embodiments, the multi-zoned catalysts contain both radial and axial zones. The zones can be formed by deposition of segregated coating compositions (or washcoats) containing platinum group metals and pollutant adsorbent materials to form layers along the length and radius of the honeycomb substrate. The invention also relates to exhaust gas treating systems that incorporate the multi-zoned catalysts.

Multi-zoned catalyst and trap

An article, apparatus and method for simulating poisoning and deactivating catalysts with catalyst poison compounds at least one catalyst poison compound selected from the group consisting of a compound comprising phosphorous, a compound comprising zinc compound and a compound comprising phosphorous and zinc.

Method and apparatus for accelerated catalyst poisoning and deactivation

A method and apparatus that converts time-resolved sensor signals into frequency domain signals using Fast Fourier Transforms and power spectral densities. A signal, as a means to assess catalyst performance such as a signal based on sensing oxygen concentration in motor vehicle exhaust in accordance with the present invention is in the time domain and has multiple components at different frequencies. The use of Fast Fourier Transforms isolates the various spectral density which arise from different frequency components of the complex time domain signal. The analysis has been found to be substantially independent of operating conditions. The power spectral density has found to be a precise indication of oxygen storage and release of the catalyst and catalyst performance. The catalyst performance can be signaled to the vehicle operator for on board diagnostics (OBD) of the catalyst.

Apparatus and method for diagnosis of catalyst performance

A system for interfacing with the ECU of an automotive vehicle for optimizing engine control to meet emission requirements or engineering targets for catalytic converter systems includes a secondary controller and an emission analyzer. The secondary controller monitors sensor input to the ECU and actuator output from the ECU so as to mimic an ECU actuator control function by generation of an operating parameter control map(s) functionally identical to that used by the ECU. The emission analyzer receives vehicle sensor input and additional emission data from a bench gas analyzer to similarly produce not only the parameter control map but also emission maps correlated to the operating parameter control map which are systemically changed to optimize emission conversion by the vehicle's catalytic converter system and modify the operating parameter control map. The modified control map is inputted to the secondary controller which bypasses the ECU to control the actuator function in accordance with the modified control map. Emission maps are subsequently generated and the modified control map further modified until conversion of emissions by the vehicle's catalytic converter system is optimized. The system permits engine control to assure emission regulation compliance without knowledge of the ECU's code while also providing design optimization of the catalytic converter.

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Hillsborough, NJ, United States of America

Sanath V Kumar