E.i. Dupont De Nemours and Company

San C Yuan

Jeffery W Johnson

Peter William Uhlianuk

Delson Jayme Trindade

Mitchell Scott Chinn

Mary Ann Haslett

This invention relates to a method for forming a multi-layer coating, comprising sequentially applying a primer surfacer, a basecoat, and a clear coat composition on an automotive substrate in a wet-on-wet-on-wet manner, and simultaneously curing the applied three layers together in a single baking step, wherein the primer surfacer comprises: a film forming binder, a volatile organic liquid carrier, and pigment(s); and the binder contains about: The resulting multi-layered coating film has excellent aesthetic appearance, chipping resistance, sag resistance, and film build even when formed in a three wet layered application method.

Method of forming multi-layer coating films on automobile bodies without a primer bake

This invention relates to a method for forming a multi-layer coating on a vehicle body, comprised of applying primer coating, base coating, and clear coat layers in a wet-on-wet-on-wet manner, and simultaneously curing the applied three layers together in a single baking step. The primer layer comprises a film-forming binder The resulting multi-layered coating film has excellent aesthetic appearance, strike-in resistance, chipping resistance, sag resistance, and film build even when formed in a three wet layered application method.

Method of forming multi-layer coatings on automobile bodies without a primer bake

This invention relates to a primer composition having a low VOC content useful in the manufacture of automobiles and trucks in which the film forming binder contains: These primers are characterized in that the curing or crosslinking reaction is presumably based, at least in part, on a ring opening polymerization reaction between the epoxy structures of (a) and silanol groups formed on (b) in the presence of atmospheric moisture and acid. Curing chiefly utilizing a ring opening reaction of the forgoing epoxy structures with the forgoing reactive diluents not only avoids volatile compounds from being generated and released into the atmosphere during the curing process, but also keeps the viscosity low enough for practical application such as by spraying. These primers are especially useful in reducing emissions, while also meeting today's performance requirements, such as ease of application and excellent physical properties such as corrosion resistance, a high level of adhesion to primed and unprimed substrates, and provide a surface to which conventional automotive topcoats will adhere.

High solids primer composition based on epoxy ring opening curing reaction

A non-yellowing coating composition particularly useful as primer that has a low VOC and excellent adhesion and chip resistance and comprises an aqueous coating composition having a VOC of less than 0.12 kg/L (1.0 pounds/gallon) comprising 25-70% by weight of a film forming binder and correspondingly, 75-30% by weight of an aqueous carrier for the binder and the composition contains pigment in a pigment to binder weight ratio of 5/100 to 150/100 and has a pH of 7-10; wherein the binder comprises

Non-yellowing polyester coating composition

A curable coating composition with holdout capability, and methods of use thereof, useful in providing a chip resistant two-tone finish in a reduced number of coating steps and curing cycles, which contains a hydroxyl-functional polyester resin, or a plurality of hydroxyl-functional polyester resins, with an average hydroxyl functionality of at least 2.1, a hydroxyl number of 75 to 400 mg KOH/g, a number average molecular weight of 1,000 to 10,000, an acid number of 1 to 30; a curing agent; and, a barium sulfate pigment This invention is also directed to method for coating a substrate with the above coating composition. In one embodiment, the method comprises (1) applying a holdout capable chip resistant primer coating composition of the forgoing character to an accent area of a electrodeposition primed substrate, (2) applying a primer surfacer coating composition to an adjacent non-accent area of the substrate, (3) applying an accent color basecoating composition wet-on-wet to the chip resistant primer coating composition in the accent area, (4) curing the composite coated substrate in a first bake, (5) covering the accent area with a protective membrane, (6) applying a main color basecoating composition over the unmasked area, (7) removing the protective membrane from the accent area, (8) applying a clear coating composition wet-on-wet to all faces of the substrate, and then (9) curing the composite two-toned coated substrate in a second bake, is also claimed. Further claimed is a substrate coated by the aforementioned coating and methods.

Chip resistant primer composition useful for producing two-tone finishes

An improved solvent borne primer composition containing as the binder a polyester, polyester urethane or an epoxy polyester and a monomeric or polymeric alkylated melamine formaldehyde crosslinking agent and containing pigments in a pigment to binder weight ratio of about 10/100 to 200/100; where the improvement is the use of about 0.1-10% by weight, based on the weight of the binder, of a zircoaluminate coupling agent of the formula ##STR1## where R is an organo functional group; wherein the primer provides excellent adhesion to waterborne basecoats that are applied over the primer.

Primers containing zircoaluminate coupling agents for improved adhesion

A method for improving the properties of a coated reinforced thermoplastic substrate which forms surface irregularities when cooled after being heated to elevated temperatures is disclosed. The method comprises coating the substrate with primer coating compositions, wet-on-wet, comprising first applying a rigid primer composition followed by applying a flexible primer composition, curing the composite primer coating and thereafter applying a topcoating. The coated substrates exhibit improved properties, especially distinctness of image (DOI).

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Commerce Township, MI, United States of America

San C Yuan