Massachusetts Institute of Technology

Samuel Mospens Nicaise

Karl Kimon Berggren

Caroline Anne Ross

Amir Tavakkoli Kermani Ghariehali

Kevin Willy Gotrik

A sacrificial-post templating method is presented for directing block copolymer (BCP) self-assembly to form nanostructures of monolayers and bilayers of microdomains. The topographical post template can be removed after directing self-assembly and, therefore, is not incorporated into the final microdomain pattern. The sacrificial posts can be a material removable using a selective etchant that will not remove the material of the final pattern block(s). The sacrificial posts may be removable, at least in part, using a same etchant as for removing one of the blocks of the BCP, for example, a negative tone polymethylmethacrylate (PMMA) when a non-final pattern block of polystyrene is removed and polydimethylsiloxane (PDMS) remains on the substrate.

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Cambridge, MA, United States of America

Samuel Mospens Nicaise