Sabic Global Technologies B.v.

Safa Farajzadeh Bibalan

Lara Galan-Sanchez

Johan Pastwa

Nicolas Goyheneix

Anthoni Van Zijl

Christoph Roosen

Anthoni Wouter Zijl Van

The present invention relates to a process for the production of butenes and butadienes from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams of chemical products comprising ethylene, propylene, isobutene, 1-butene, 2-butene, 1,2-butadiene, 1,3-butadiene, benzene, styrene, toluene, ethylbenzene and xylenes; wherein in step (d): ⋅ the coil outlet temperature is ≥800 and ≤870° C., preferably ≥805 and ≤835° C.; and ⋅ the weight ratio of steam to feed C is >0.3 and <0.8, preferably >0.3 and <0.5. Such process allows for optimisation of the quantity of waste plastic material that finds its way back into products that are produced as outcome of the process. The higher that quantity is, i.e. the higher the quantity of chemical building blocks that are present in the waste plastic material that are converted to the produced products, the better the sustainability footprint of the process is. The process allows for circular utilisation of plastics.

Process for the preparation of chemical products from waste plastic feedstocks

Process for the production of polycarbonates comprising: providing a hydrocarbon stream A obtained by hydrotreatment of a pyrolysis oil produced from a waste plastics feedstock; supplying a feed C comprising a fraction of the hydrocarbon stream A to a thermal cracker furnace comprising cracking coil(s); thermally cracking in the presence of steam to obtain a cracked hydrocarbon stream D; separating a product stream E comprising propylene and a product stream F comprising benzene from the cracked hydrocarbon stream D; performing a reaction and one or more separation step to obtain a product stream G comprising phenol; supplying the product stream G and acetone to a reactor and performing a reaction and one or more separation step to obtain a product stream H comprising bisphenol-A; and supplying the product stream H with phosgene or diphenyl carbonate to a reactor and performing a polymerisation reaction to obtain a polycarbonate.

Process for the preparation of polycarbonates from waste plastic feedstocks

Process for the production of butenes and butadienes from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; and (f) performing a separation operation to obtain different streams comprising isobutene, 1-butene, 2-butene, 1,2-butediene and 1,3-butadiene; wherein in step (d): •the coil outlet temperature is ≥800 and ≤850° C.; and•the weight ratio of steam to feed C is >0.3 and <0.8.

Process for the preparation of butenes and butadienes from waste plastic feedstocks

A process for the production of ethylene-based polymers from waste plastics feedstocks includes the steps in this order of: providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; providing a hydrocarbon stream B; supplying a feed C including a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace having cracking coil(s); performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; supplying the cracked hydrocarbon stream D to a separation unit to obtain a product stream E containing ethylene; supplying the product stream E to a polymerisation reactor; and performing a polymerisation reaction to obtain an ethylene-based polymer; wherein in step (d): the coil outlet temperature is ≥800 and ≤870° C.; and the weight ratio of steam to feed C is >0.3 and <0.8.

Process for the preparation of polyethylenes from waste plastic feedstocks

The present invention relates to a process for the production of ethylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of a pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising ethylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an ethylene-based polymer; wherein in step (d): ⋅ · the coil outlet temperature is 2: 800 and:::; 870° C., preferably 2: 820 and:::; 870° C.; and ⋅ · the weight ratio of steam to feed C is >0.3 and <0.8.

The present invention relates to a process for the production of polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an polymer. The process of the present invention allows for optimisation of the quantity of waste plastic material that finds its way back into a polymer that is produced as outcome of the process.

Process for the preparation of polymers from waste plastic feedstocks

The present invention relates to a process for the production of propylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising propylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an propylene-based polymer; wherein in step (d): &#x2022;&#x22c5; the coil outlet temperature is 2:: 800 and:::; 850&#xb0; C., preferably 2:: 805 and:::; 835&#xb0; C.; and &#x2022;&#x22c5; the weight ratio of steam to feed C is &#x3e;0.3 and &#x3c;0.8.

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Geleen, Netherlands

Safa Farajzadeh Bibalan