Taiyo Yuden Co., Ltd.

Sachie Tomizawa

Daigo Ito

Chie Kawamura

Takato Satoh

Masashi Sekiguchi

Kotaro Mizuno

Takato Sato

An all solid battery includes: an oxide-based solid electrolyte layer; a first electrode provided on a first main face of the solid electrolyte layer; a second electrode provided on a second main face of the solid electrolyte layer, wherein the solid electrolyte layer is a sintered structure of solid electrolyte powder, wherein the solid electrolyte powder has D10% diameter of 0.05 μm or more and 0.6 μm or less, D50% diameter of 0.08 μm or more and 1.5 μm or less, D90% diameter of 4 μm or less, and a BET value of 3 m/g or more and 20 m/g or less.

All solid battery, manufacturing method of all solid battery and solid electrolyte powder

An all solid battery includes: a solid electrolyte layer of which a main component is oxide-based solid electrolyte; a first electrode layer that is provided on a first main face of the solid electrolyte layer and includes an active material; and a second electrode layer that is provided on a second main face of the solid electrolyte layer and includes an active material, wherein at least one of the first electrode layer and the second electrode layer includes an aggregate of carbon particles and a cavity, wherein the aggregate demarcates at least a part of the cavity.

All solid battery

An all-solid battery includes: a multilayer structure that includes a plurality of first electrodes and a plurality of second electrodes, and has a first side face and a second side face adjacent to each other, the plurality of first electrodes and the plurality of second electrodes being alternately stacked with solid electrolyte layers interposed between the plurality of first electrodes and the plurality of second electrodes; a first extraction part exposed on the first side face, the first extraction part being a part of the first electrode; a second extraction part exposed on the second side face, the second extraction part being a part of the second electrode; a first external electrode coupled to the first extraction part on the first side face; and a second external electrode coupled to the second extraction part on the second side face.

All-solid battery and battery module

An all solid battery includes a multilayer chip in which plurality of internal electrodes are alternately exposed to two side faces. A thickness SE of a solid electrolyte layer is 1 μm or more and 50 μm or less in an intersection portion in which two internal electrodes next to each other connected to different external electrodes overlap with each other. Thicknesses EL1 and EL2 of the two internal electrodes are 1 μm or more and 200 μm or less. In one of two non-intersection portions, a length EM from one of the pair of external electrodes contacting the one of the two non-intersection portions to an internal electrode spaced from the one of the pair of external electrodes in a distance direction is 50 μm or more and 800 μm or less. EM/(SE+EL1/4+EL2/4) is 20 or less.

An all-solid battery includes: a solid electrolyte layer mainly composed of oxide-based solid electrolyte; a first electrode layer formed on a first principal face of the solid electrolyte layer, the first electrode layer containing an active material; a second electrode layer formed on a second principal face of the solid electrolyte layer, the second electrode layer containing another active material, wherein no collector layer that is in contact with the second electrode layer is provided in a direction in which the solid electrolyte layer, the first electrode layer, and the second electrode layer are stacked, and the second electrode layer includes board-shaped carbon.

All-solid battery and manufacturing method of the same

An all solid battery includes: a solid electrolyte layer including a glass component, a main component of the solid electrolyte layer being phosphoric acid salt-based solid electrolyte; and electrode layers that are provided on both main faces of the solid electrolyte layer, wherein the electrode layers include a carbon material having an average particle diameter of 40 nm or more and 120 nm or less, wherein a DBP oil absorption of the carbon material is 200 mL/100 g or less.

All solid battery and manufacturing method of the same

An all solid battery includes: a solid electrolyte layer; a positive electrode layer provided on a first face of the solid electrolyte layer, a part of the positive electrode layer extending to a first edge portion of the solid electrolyte layer; a first margin layer that is provided on an area of the solid electrolyte layer where the positive electrode is not provided; a negative electrolyte layer provided on a second face of the solid electrolyte layer, a part of the negative electrolyte layer extending to a second edge portion of the solid electrolyte layer; a second margin layer that is provided on an area of the second face of the solid electrolyte layer where the negative electrolyte layer is not provided; wherein a main component of the first margin layer and the second margin layer is solid electrolyte of which ionic conductivity is lower than that of the solid electrolyte layer.

An all solid battery includes: a multilayer chip in which each of solid electrolyte layers and each of electrodes are alternately stacked, a main component of the solid electrolyte layers being phosphoric acid salt-based solid electrolyte, the plurality of electrodes being alternately exposed to a first end face and a second end face of the multilayer chip, a first external electrode provided on the first end face; a second external electrode provided on the second end face; and wherein L/W is 0.2 or more and 1.1 or less, when a length of the multilayer chip in a first direction in which the first end face faces with the second end face is L, and a width of the multilayer chip in a second direction that is vertical to the first direction and a stacking direction of the multilayer chip is W.

An all solid battery includes a solid electrolyte layer of which a main component is a Li&#x2014;Al-M-PO-based phosphoric acid salt, a first electrode layer that is provided on a first main face of the solid electrolyte layer and includes an active material, and a second electrode layer that is provided on a second main face of the solid electrolyte layer and includes an active material. 'M' is at least one of Ge, Ti, and Zr. A region in which a ratio of MOwith respect to Li&#x2014;Al-M-POis 5% or more is unevenly distributed from a center in a thickness of the solid electrolyte layer to 0.4 A downward and to 0.4 A upward, when the thickness of the solid electrolyte layer is expressed by 'A'.

An all solid battery includes: a solid electrolyte layer; a first electrode layer that is formed on a first main face of the solid electrolyte layer; a first electric collector layer that is formed on a face of the first electrode layer, the face being opposite to the first main face; a second electrode layer that is formed on a second main face of the solid electrolyte layer; and a second electric collector layer that is formed on a face of the second electrolyte layer, the face being opposite to the second main face, wherein at least one of the first electric collector layer and the second electric collector layer includes Pd and board-shaped graphite carbon, wherein a volume ratio of Pd and the board-shaped graphite carbon in the at least one of the first electric collector layer and the second electric collector layer is 20:80 to 80:20.

An all solid battery includes: a solid electrolyte layer including phosphoric acid salt-based solid electrolyte; a first electrode that is formed on a first main face of the solid electrolyte layer; and a second electrode that is formed on a second main face of the solid electrolyte layer, wherein a D50% grain diameter of crystal grains of the phosphoric acid salt-based solid electrolyte is 0.5 &#x3bc;m or less, wherein a D90% grain diameter of the crystal grains is 3 &#x3bc;m or less.

All solid battery, manufacturing method of the same and solid electrolyte paste

An all solid battery includes: a solid electrolyte layer including solid electrolyte; a first electrode layer that is formed on a first main face of the solid electrolyte layer and includes an active material; and a second electrode layer that is formed on a second main face of the solid electrolyte layer and includes an active material, wherein the solid electrolyte layer includes polymer solid electrolyte including lithium salt, in a clearance of a sintered compact of phosphoric acid salt-based solid electrolyte.

An all solid battery includes: a solid electrolyte layer including an oxide-based electrolyte; a first electrode layer that is formed on a first face of the solid electrolyte layer and includes a ceramic grain; and a second electrode layer that is formed on a second face of the solid electrolyte layer and includes a ceramic grain, wherein at least one of the first electrode layer and the second electrode layer includes a micro particle carbon and a board-shaped carbon.

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Takasaki, Japan

Sachie Tomizawa