Nippon Shokubai Co., Ltd.

Ryuji Aizawa

Yoshinobu Asako

Satoru Ono

Izuho Okada

Minoru Kobayashi

Shoji Ito

Minoru Aoki

Kiyomi Arimatsu

Kazuhiko Murata

Jinxing Pan

Polymer and macromolecular solid electrolyte containing the same

The sulfonation of a polyaniline or a derivative thereof by the use of a sulfonating agent, characterized by dispersing the polyaniline or the derivative thereof in a reaction solvent thereby inhibiting the formation of lumps of grains due to substantial aggregation. Preferably, the solvent for the reaction is an organic solvent incapable of reacting with the sulfonating agent. The initial stirring power for the reaction of sulfonation is preferred to be not less than 0.03 kW/m,and the polyaniline or the derivative thereof is preferred to have a water content of not more than 8 wt. %. Further, this invention is characterized by subjecting a polyaniline having introduced a sulfonic acid group therein or a derivative thereof to hydrolysis in a mixed solution of water with a hydrophilic organic solvent. The hydrophilic organic solvent is preferred to be an alcohol. The aqueous solution of the water-soluble conducting polyaniline obtained by the method of production mentioned above can be made to form a thin film by a simple technique such as spin coat, dip coat, or bar coat and utilized for various antistatic applications and non-linear optical materials.

Method for production of water-soluble conducting polyaniline

An electrorheological fluid composition is composed of a dispersed phase of dielectric solid particles and a dispersion medium of an electrically insulating solution, wherein the solution is composed of 99-75% by weight of silicone oil and 1-25% by weight of an organic compound having at least one unsaturated bond. The composition generates a large shear stress even under an electric field of relatively low intensity, and the concurrent current density is small. The composition shows excellent performances also in terms of its withstanding dielectric breakdown strength under an electric field of high intensity and the fluidity and re-dispersibility in the absence of an electric field. In the meantime, the composition has high durability of the generated shear stress and the current density.

Electrorheological fluid composition including hydrocarbon compound

An electrorheological fluid comprising dielectric particles and an insulating liquid and characterized by exhibiting a viscosity of not more than 0.2 Pa.cndot.s at a shear rate of 33/s when measured at 25.degree. C. in the absence of supply of an electric field and a structural viscosity satisfying the condition of the formula (1):

Electrorheological fluid with improved properties comprising composite

An electrorheological fluid comprising a dielectric particle as the dispersed phase, an insulating oil as the dispersing medium, and an additive, the additive being substantially insoluble in the dispersing medium, and being a composite containing a polysiloxane-containing structural unit (A), and at least one dispersed phase absorbing chain-containing structural unit (B) selected from the group consisting of an alkylene oxide chain-containing structural unit (B-1), a nitrogen atom chain-containing structural unit (B-2), and a long hydrocarbon chain-containing structural unit (B-3).

Electrorhelogical fluid

An electrorheological fluid composition comprising a dispersion of disperse-phase particles formed of a sulfonated polymer possessing aromatic rings substituted with sulfonic acid groups in an electrically non-conducting oil which electrorheological fluid is characterized by the fact that the number of sulfonic acid groups in said sulfonated polymer forming said disperse-phase particles exceeds the number of aromatic rings present in said sulfonated polymer.

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Ibaraki, Japan

Ryuji Aizawa