Japan Exlan Company Limited

Ryuichi Kasahara

Ryosuke Nishida

Noriyuki Kohara

Hirotaka Shiota

Yoshihiro Watanabe

Takahisa Kida

Disclosed are a hot-melting acrylonitrile (AN) polymer composition comprising a non-volatile component modified from AN alone or a AN monomer composition through chemical reaction, an AN polymer and water, a method for producing the composition, and a method for producing a shaped article of AN polymer by melting the composition under heat followed by shaping the melt. The composition and the shaped article do not contain toxic AN and AN monomer mixture.

Acrylonitrile polymer compositions, method for producing the

A process for producing a homogeneous phase melt of polyacrylonitrile suitable for extrusion molding and melt spinning, by the steps of preparing polymer/water crumb containing 30-60 wt % of polyacrylonitrile and dewatering the crumb in a molten state with stirring at temperatures above 140.degree. C. and at pressures above autogenous pressure until the concentration of the polymer in the crumb exceeds 70% by weight.

Process for producing homogeneous phase melt of polyacrylonitrile

Saturated or superheated steam, or an inert gas, or a combination thereof is introduced into a gas phase above a molten acrylonitrile polymer in a vessel having a stirrer, while the polymer has a temperature of at least 120.degree. C. and a pressure at least equal to its autogenous pressure. Any unreacted acrylonitrile monomer, or both any such monomer and any acrylonitrile monomer or water used as a plasticizer are removed by evaporation from the vessel.

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Okayama, Japan

Ryuichi Kasahara