Nippon Shokubai Co., Ltd.

Other

Ryuichi Ishikawa

Hitoshi Yano

Norihiro Wakao

Youichi Hino

Yoshinari Yamaguchi

Yukihiro Matsumoto

Yuuji Shimasaki

Michio Ueshima

Kazumasa Kimura

Yoshihiro Arita

Kimio Ariyoshi

Kazuaki Abe

Hirokazu Ito

Teruhisa Kaziwara

Takashi Kai

Yoshitaka Arita

This invention concerns a novel organic sulfide compound obtained by the reaction of a mercapto alkanol such as 2-mercapto ethanol with an unsaturated amide such as (meth)acrylamide, maleic acid diamide, or fumaric acid diamide and a method for the production of the organic sulfide compound. The invention enables novel organic sulfide compounds of great commercial utility to be obtained with a high yield on a commercial scale.

Organic sulfide compound and method for production thereof

Method of recovering and dehydrating ethylene sulfide

Method for manufacturing thiol compounds

A process for producing an alkylene sulfide, which comprises the step of subjecting a mercaptoalkanol to an intramolecular dehydration reaction in the presence of an acidic dehydration catalyst, to produce the alkylene sulfide, in which the intramolecular dehydration reaction is conducted under at least one conditions of (1) to (3). (1) The intramolecular dehydration reaction is conducted in at least one solvent selected from the group consisting of compounds having an amide group N-substituted with a hydrocarbon group having from 1 to 6 carbon atoms, compounds having an unsubstituted amide group, compounds having a ureylene group N-substituted with a hydrocarbon group having from 1 to 6 carbon atoms, and compounds having an unsubstituted ureylene group. (2) The intramolecular dehydration reaction is conducted in a solvent under such temperature and pressure conditions that the reaction temperature T (.degree.C.) and the boiling point tb (.degree.C.) of the solvent at the reaction pressure satisfy equation (tb-30).ltoreq.T.ltoreq.tb. (3) The intramolecular dehydration reaction is conducted in a solvent in the presence of a hydrocarbon having a boiling point at ordinary pressure of from 30.degree. C. to 180.degree. C. When the hydrocarbon has from 6 to 9 carbon atoms, the above-described effects are enhanced further. When the concentration of the hydrocarbon in the reaction mixture is maintained in the range of from 0.1 to 10% by weight, the above-described effects are enhanced even more.

Process for producing alkylene sulfide

A process for producing a modified polyaminoamide with markedly increased reactivity as an epoxy resin curing agent is disclosed. The process comprises introducing amino groups and mercapto groups into a polyaminoamide by using an aziridine compound and a thiirane compound. The modified polyaminoamide is capable of curing an epoxy resin at a low temperature and at a high rate to provide a cured epoxy resin excellent in anticorrosion and chemical resistance.

Process for producing modified polyaminoamide, modified polyaminoamide

In a process for preparing alkylene sulfides through the intramolecular dehydration reaction of mercaptoalkanols in a gaseous phase, catalysts are used, which are represented by the formula: M.sub.a X.sub.b Y.sub.c O.sub.d, where M represents at least one element selected from the group of alkali metals, alkaline earth metals and thallium; X represents at least one element selected from the group of Al, B, Si and P; Y represents at least one element selected from the group consisting of lanthanides, IIIA group, IVA group, VA group, IIIB group, IVB group, VB group and VIB group, excluding an element contained in M or X; O represents oxygen; and a and b are numerical values not equal to 0; b=0.2-100 and c=0-50 when a=1; and d is a numerical value determined according to a, b and c.

Process for preparing alkylene sulfides

Growing community of inventors

Sakai, Japan

Ryuichi Ishikawa