The Lion Fat and Oil Co. Ltd.

Ryozo Taniyasu

Hiroshi Isa

Toshiyuki Ukigai

Masuzo Nagayama

Anri Tominaga

Takeshi Saito

Hideo Kurokawa

Hiroshi Mandai

Anry Tominaga

Disclosed is a method for removing an aluminum halide or its complex catalyst from a polymerization product comprising the steps of adding to the polymerization product an aprotic polar solvent in an amount of 1.0 through 6.0 mol per one mol of the aluminum halide in the catalyst present in the product and sufficiently mixing them at a temperature of 70.degree. through 150.degree. C, and then, filtering the mixture at a temperature of 70.degree. through 150.degree. C. The addition of the aprotic polar solvent remarkably facilitates the separation of the catalyst from the polymerization product.

Method for removing aluminum halide catalyst from polymerization product

Disclosed is a process for preparing a catalyst for polymerizing a mono olefin having 6 through 20 carbon atoms comprising mixing (a) a fatty acid having not less than 3 carbon atoms and (b) aluminum chloride, aluminum bromide or a mixture thereof in an amount of 0.7 through 1.2 mol of the component (b) based upon 1 mol of the component (a), to effect the condensation reaction of both components and a catalyst prepared by said process. This catalyst is suitable for use in the production of an olefin polymer having low viscosity and a high viscosity index.

Process for preparing catalyst for olefin polymerization

A method of preparing a polyolefin oil in the present invention comprises polymerizing an olefin having 6 or more carbon atoms in the presence of a mixture of a polyhydric alcohol derivative and an aluminum halide, said derivative being obtained by replacing hydrogen atoms of all the hydroxyl groups of the polyhydric alcohol by alkyl groups having 1-20 carbon atoms. The thus prepared polyolefin oil scarcely contains halogen, and it has a wide range of use such as, for instance, a lubricant, a cosmetic base, a textile finishing agent, etc.

Method for preparation of polyolefin oil

A method of manufacturing granular solid catalyst, comprising the process of mixing more than 1 mole of olefin and 1.0 - 1.2 mole of ketone having 4 or more carbon atoms relative to 1 mole of aluminum halide and effecting reaction at a temperature of more than 60.degree.C.

Method of manufacturing granular solid catalyst

An olefin oligomer having a low viscosity and a high viscosity index can be prepared by polymerizing an olefin having 6 or more carbon atoms in the presence of a mixture of a polyhydric alcohol derivative and an aluminum halide, said derivative being obtained by replacing the hydrogen atoms of all the hydroxyl groups of the polyhydric alcohol by either acyl groups exclusively or by acyl group and alkyl groups both of said groups having 1 - 20 carbon atoms. The thus prepared olefin oligomer scarcely contains halogen, and it has a wide range of uses such as, for instance, a lubricant, a cosmetic base, etc.

Method for preparation of olefin oligomer

A method of effecting polymerization of olefins having 6 or more carbon atoms or mixtures of such olefins (hereinafter referred to as the feed olefin), to produce a hydrocarbon liquid polymer which comprises mixing a catalyst composed of aluminum chloride, ketone having 4 or more carbon atoms and olefin catalyst constituent with 0.01 to 0.3 mole of ester, ether or alcohol per mole of said aluminum chloride and effecting the polymerization of the feed olefin at a reaction temperature of more than 60.degree.C.

Method for preparation of hydrocarbon liquid polymers

A method for producing a liquid olefin polymer which comprises polymerizing an .alpha.-olefin having 6 - 14 carbon atoms or mixtures thereof, in the presence of a catalyst consisting of an alkali metal hydride, a halide of an element selected from boron and aluminum and a titanium halide, or a catalyst in which metallic lithium or sodium is added to those catalyst ingredients.

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Narashino, Japan

Ryozo Taniyasu