Toyobo Co., Ltd.

Toyobo Mc Corporation

Ryouhei Yamane

Kenji Kashihara

Takuya Akaishi

Yuki Maeda

Hirotoshi Kizumoto

[Problem] The present invention aims to provide a high-molecular-weight modified copolymerized polyester resin that has a reactive functional group at a site other than the terminals of the molecular chain thereof, has an excellent reactivity with a curing agent (such as an epoxy resin or an isocyanate compound), and can be used to form an organic-solvent-and-emulsifier-free water dispersion having excellent storage stability. [Solution] A modified copolymerized polyester resin (B) having a structure in which a copolymerized polyester resin (A) has an unsaturated polyvalent carboxylic acid added to a side chain thereof, and the copolymerized polyester resin (A) contains, as copolymerization components, at least one member selected from the group consisting of: a copolymerization component having an alicyclic structure (component x); a copolymerization component having six or more continuous methylene groups (component y); and an acyclic aliphatic copolymerization component having a tertiary carbon atom and a molecular weight of more than 100 (component z).

Modified copolymerized polyester resin and water dispersion thereof

The present invention relates to a polyester elastomer resin composition comprising: a thermoplastic polyester elastomer (A); a thickening agent (B); and a urea compound scavenger (C), wherein the thermoplastic polyester elastomer (A) is composed of a hard segment and a soft segment that are linked to each other; the hard segment being composed of a crystalline polyester formed from an aromatic dicarboxylic acid and an aliphatic and/or alicyclic diol, the soft segment being at least one member selected from aliphatic polyethers, aliphatic polyesters, or aliphatic polycarbonates; the urea compound scavenger (C) has an amine value of 50 eq/t or more; the thickening agent (B) is present in an amount of 0 to 5 parts by mass, and the urea compound scavenger (C) is present in an amount of 0.1 to 10 parts by mass, per 100 parts by mass of the thermoplastic polyester elastomer (A). The invention can decrease the deterioration of physical properties of a polyester elastomer caused by the elastomer coming into contact with grease in an environment at a temperature exceeding 140&#xb0; C.

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Shiga, Japan

Ryouhei Yamane