Toyobo Mc Corporation

Toyobo Co., Ltd.

Ryo Umeki

Nobuhiro Yoshimura

Yoshitaka Ayuzawa

Yoshitaka Tanaka

Shigeyuki Watanabe

Takafumi Masuda

Daiki Funaoka

Kensaku Maeda

The invention provides a thermal adhesive laminated oriented film containing a substrate layer comprising a resin composition containing 99.9 to 60% by mass of a polyamide resin or a polymethylpentene resin and 0.1 to 40% by mass of a modified polyolefin resin; and a thermal adhesive layer containing a thermal adhesive polyolefin resin and provided on each of both surfaces of the substrate layer so as to be in direct contact therewith by coextrusion. When a machine direction is defined as an X axis, a transverse direction is defined as a Y axis, and a thickness direction is defined as a Z axis, the film is stretched and oriented in at least one direction of the X axis or the Y axis, and has a thermal deformation rate at 150° C. of 4% or less in both directions of the X axis and the Y axis.

Thermal adhesive laminated oriented film

A method for producing a polyamide resin composition containing a crystalline polyamide resin (A) containing a polycaproamide resin as a main component, a semi-aromatic amorphous polyamide resin (B), an inorganic reinforcing material (C), a master batch of carbon black (D), and a copper compound (E); a dispersion liquid of the copper compound (E) has a concentration of 0.04% by mass to 1.0% by mass; and the crystalline polyamide resin (A) containing a polycaproamide resin as a main component, the semi-aromatic amorphous polyamide resin (B), the master batch of carbon black (D), and the dispersion liquid of the copper compound (E) are mixed in advance, followed by charging the mixture is into a hopper part of an extruder, and charging the inorganic reinforcing material (C) into the extruder by a side feed method.

Method for producing polyamide resin composition

A pellet production method comprising: an operation in which a strand comprising a composition containing thermoplastic resin and reinforcing material is extruded from an orifice at a die; an operation in which the strand is drawn into water within a tank and is cooled; and an operation in which the cooled strand is cut to obtain a pellet; wherein at least one first guide roller for guiding the strand within the tank is provided within the tank, and an angle made by portions of the strand that are ahead of and behind that first guide roller which is in an upstreammost location is not less than 90° but is less than 180°; and wherein a ratio of a diameter of the pellet to a diameter of the orifice (diameter of the pellet/diameter of the orifice) is 0.45 to 0.80.

Pellet production method

The present invention aims to provide a glass-fiber-reinforced polyamide resin composition, characterized in that, the composition contains a crystalline aliphatic polyamide resin (A), an amorphous polyamide resin (B), an acrylic resin (C), mica (D), glass fiber (E) and a master batch of carbon black (F) in a ratio by mass of (17 to 30):(10 to 16):(3 to 8):(10 to 25):(20 to 50):(1 to 8), respectively, in that, a mass ratio of (A) and (B) ((B)/(A)) satisfies 0.50 to 0.61, and in that, the composition further contains a copper compound (G) in a rate of 0.005 to 1.0 part by mass when a total amount of the ingredients (A) to (F) is taken as 100 parts by mass. From the glass-fiber-reinforced polyamide resin composition, it is possible to obtain a molded product that is highly excellent in a surface appearance (textured surface uniformity) and has a weather resistance in a level being enough for maintaining an excellent surface appearance even after the weathering test.

Glass-fiber-reinforced polyamide resin composition and molded product for vehicle interior or vehicle exterior made therefrom

The present invention provides a polyamide resin composition containing (A) a crystalline polyamide resin containing a polycapramide resin as a main component, (B) a semi-aromatic amorphous polyamide resin, and (C) an inorganic reinforcing material, wherein the polyamide resin composition contains, as the (C), (C-1) a glass fiber, (C-2) a wollastonite having a needle shape, and (C-3) an inorganic reinforcing material of a plate-like crystal; a mass ratio of the (B) to (A) satisfies 0.35≤(B)/(A)≤0.80; when a total content of the (A), (B), and (C) is 100 parts by mass, a content (parts) of each component satisfies 30≤(A)+(B)≤55; 10≤(B)≤23; 20≤(C-1)≤40; 8≤(C-2)≤25; 8≤(C-3)≤25; 45≤(C-1)+(C-2)+(C-3)≤70; and an amount of a carboxyl group in the polyamide resin composition is less than 120 meq/kg. The resin composition provides a molded article having excellent strength and rigidity, excellent surface appearance of the molded article, and further excellent weather resistance, even in continuous molding of the composition over a long period of time at a high cylinder temperature.

Polyamide resin composition and method for producing same

A polyamide resin composition containing a polyimide resin (A), a modified styrene-based copolymer (B), a modified high-density polyethylene (C), and an aliphatic metal salt (D), and having a melt mass flow rate (MFR) of 20 g/10 minutes or more and less than 60 g/10 minutes and a 65% RH equilibrium water absorption rate of less than 3%. The polyamide resin composition can form a molded article having a sufficiently high limit of fatigue against continuous load, achieve high mechanical characteristics and high fluidity to prevent the occurrence of a short shot or decrease in the strength of a welded part even in a large and/or thick molded article, and has excellent mold releasability and more excellent abrasion resistance than ever before.

Growing community of inventors

Shiga, Japan

Ryo Umeki