Jgc Catalysts & Chemicals Ltd.

Catalysts & Chemicals Industries Co., Ltd.

Other

Nippon Telegraph and Telephone Corporation

Dai Nippon Printing Co., Ltd.

Ryo Muraguchi

Mitsuaki Kumazawa

Miki Egami

Toshiharu Hirai

Michio Komatsu

Hirotada Arakane

Akira Nakashima

Masayuki Matsuda

Hiroyasu Nishida

Katsuyuki Machida

Tsuguo Koyanagi

Hakaru Kyuragi

Takumi Miyazaki

Kazuaki Inoue

Kazuo Imai

Atsushi Tonai

Masafumi Hirai

Kazutaka Egami

Masanobu Taniguchi

Jun Yamaguchi

Tatsuya Uehara

Toshio Yoshihara

Seiji Shinohara

Yuji Tawarazako

Ryota Sueyoshi

Takuji Miyamoto

Satoshi Yoshida

Yuji Tawarasako

Utako Mizuno

Midori Nakajo

Wataru Futagami

Shogo Hayashi

Michio Kimatsu

Yuhko Hakoshima

A silica particle dispersion liquid includes a silica particle that satisfies (i) to (iii) below: (i) an average particle diameter d is 5 to 300 nm; (ii) an occlusion amount of a basic substance per 1 g of the particle is 2 mg or more; and (iii) a Sears number Y exceeds 12.0.

Silica particle dispersion liquid and production method thereof

A porous silica particle has disintegration properties. The porous silica particle has an average particle diameter of 0.5 to 50 μm, a pore volume of 0.5 to 5.0 cm/g, a mode of a pore diameter of 2 to 50 nm, a shape factor of 0.8 to 1.0, an average compression strength of 0.1 to less than 1.0 kgf/mm, a sodium content of 10 ppm or less, and a network structure.

Porous silica particles and method for producing same

Provided are titanium oxide fine particles which are excellent in transparency and are less photocatalytically active while maintaining a high refractive index, a dispersion of such fine particles, and a method for producing such a dispersion. The method for producing a dispersion of iron-containing rutile titanium oxide fine particles including a step (1) of neutralizing an aqueous metal mineral acid salt solution containing Ti and Fe in FeO/(TiO+FeO)=0.001 to 0.010 to form an iron-containing hydrous titanic acid; a step (2) of adding an aqueous hydrogen peroxide solution to form an aqueous solution of iron-containing peroxotitanic acid having an average particle size of 15 to 50 nm; a step (3) of adding a tin compound so as to satisfy TiO/SnO=6 to 16; a step (4) of adding a sol of silica-based fine particles which contain Si and a metal element M in SiO/MO=99.9/0.1 to 80/20, the addition being made so as to satisfy SiO/(oxides of the other elements)=0.08 to 0.22; and a step (5) of hydrothermally treating the solution obtained in the step (4).

Method for producing dispersion of iron-containing rutile titanium oxide fine particles, iron-containing rutile titanium oxide fine particles, and use thereof

There is provided a production method of a chain silica particle dispersion. This production method includes a dispersion preparation step of hydrolyzing alkoxysilane in the presence of ammonia to prepare a silica particle dispersion, an ammonia removal step of removing the ammonia from the silica particle dispersion such that an ammonia amount relative to silica contained in the silica particle dispersion is 0.3% by mass or less, and a hydrothermal treatment step of hydrothermally treating the silica particle dispersion having a silica concentration of 12% by mass or more, from which the ammonia has been removed, at a temperature of not lower than 150&#xb0; C. and lower than 250&#xb0; C. An abrasive including such chain silica particles is high in polishing rate and excellent in polishing properties.

Method for producing chain-like particle dispersion, and dispersion of chain-like particles

Provided is a production method of a silica particle dispersion liquid which includes, preparing a linked silica particle by adding a liquid A containing alkoxysilane and a liquid B containing an alkali catalyst to a liquid containing water, an organic solvent, and an alkali catalyst in a container. The preparing a linked silica particle includes initially adding an alkali catalyst, the initially adding an alkali catalyst includes decreasing a molar ratio of an alkali catalyst to silica in the liquid in the container to 0.15 to 0.60 by adding the liquid A containing alkoxysilane to the liquid in the container, and increasing the molar ratio by 0.2 or more by adding the liquid B to the liquid having the decreased molar ratio in the container.

A polishing composition that can not only achieve high polishing speed, but also can improve the surface smoothness (surface quality) of a polished substrate and reduce defects is provided. That is, provided is a polishing composition comprising silica particles and a water soluble polymer, wherein the contained silica particles satisfy the following requirements (a) to (c): (a) the primary particle diameter based on the specific surface area is 5 to 300 nm; (b) the coefficient of variation in the particle diameter is 10% or less; and (c) the Sears number Y is 10.0 to 12.0.

Dispersion liquid of silica particles, polishing composition, and method for producing dispersion liquid of silica particles

Provided is a dispersion liquid of silica particles, comprising silica particles having an average particle diameter of 5 to 300 nm determined from an electron micrograph and a density of 1.20 g/cmor more determined from a specific surface area determined by a BET method using nitrogen adsorption, wherein the dispersion liquid has a pH of less than 8, a silica concentration of 12 to 40% by mass, and a viscosity in terms of a silica concentration of 20% by mass of 40 mPa&#xb7;s or less. When this silica particle is used as an abrasive, it is possible to realize a sufficient polishing speed and a smooth polished surface on which occurrence of scratches is suppressed.

Dispersion liquid of silica particles and production method therefor

A method for producing a dispersion liquid of silica particles, by simultaneously adding a liquid A containing silane alkoxide and a liquid B containing an alkali catalyst and water to a liquid I containing silica seed particles to cause the particles to grow, so as to produce silica particles; wherein the variation rate of the mole ratio of the alkali catalyst to silica components in the reaction system during a period from the start to the end of the addition relative to the initial mole ratio is 0.90 to 1.10; and the variation rate of the mole ratio of water to the silica components in the reaction system during a period from the start to the end of the addition relative to the initial mole ratio is 0.90 to 1.10.

Production method for dispersion liquid of silica particle

A method for producing a liquid dispersion containing irregular-shaped silica particles in which two or more primary particles are linked together, by simultaneously adding a liquid A containing silane alkoxide and a liquid B containing an alkali catalyst and water to a liquid I consisting substantially of an organic solvent to cause hydrolysis and polycondensation of the silane alkoxide, wherein the period from the start of the addition until the silica concentration of the reaction system at the end of the addition reaches 70% is 20% or less of the full reaction time period.

Silica particle liquid dispersion and production method therefor

Silica particles calcined in a calcination step are supplied in a swirling flow generated by a gas introduced in a disintegration container and disintegrated therein, whereby the silica particles can be easily disintegrated and there can be obtained disintegrated silica particles having both low hygroscopicity and high dispersibility in resin. In addition, the introduction of dehumidified air (gas) during the disintegration reduces hygroscopicity and greatly improves dispersibility in resin. Furthermore, performing heating treatment (calcination) again after the disintegration causes the surface modification of the disintegrated silica particles, greatly improving hygroscopicity and dispersibility in resin. The resin composition obtained in this manner including silica particles provides good injectability and filterability when used for an underfill material for semiconductors and an in-plane spacer or sealing spacer of liquid crystal displays.

Method for producing disintegrated silica particles

Producing a silica particle by inhibiting the generation of incompletely reacted materials such as oligomers which have not been grown to the silica particles having the intended particle size. A dispersion liquid of a silica particle is produced by simultaneously adding, to a liquid substantially consisting of an organic solvent, a liquid containing silane alkoxide and a liquid containing an alkali catalyst and water to cause hydrolysis and polycondensations to produce a silica particle. The variation rate of the mole ratio of the alkali catalyst to silane alkoxide in the reaction system for a period from the start to the end of the reaction relative to the initial mole ratio is 0.90 to 1.10; and the variation rate of the mole ratio of water to silane alkoxide for a period from the start to the end of the reaction relative to the initial mole ratio is 0.90 to 1.10.

Silica particle dispersion and production method of the same

A method of producing silica-based particles includes, when a dispersion liquid of composite oxide particles is prepared by simultaneously adding an aqueous silicate solution and/or an acidic silicic acid solution and an aqueous solution of an alkali-soluble inorganic compound in an alkali aqueous solution or in an alkali aqueous solution with seed particles dispersed therein, if required, the aqueous silicate solution and/or the acidic silicic acid solution and the aqueous solution of alkali-soluble inorganic compound are added so that the molar ratio of MO/SiOare in a range from 0.01 to 2, herein MOdenoting an inorganic oxide other than silica and SiOdenoting silica to prepare the dispersion liquid of composite oxide particles with an average diameter (D) in a range from 3 to 300 nm.

Method of producing silica-based particles

Provided is a silica-based polishing particle which can polish and flatten the surface of a substrate at a sufficient polishing rate with generation of scratches prevented, and successfully prevents generation of particle residues on a substrate after polishing. A silica-based polishing particle with a three-dimensional polycondensation structure containing an alkoxy group, wherein the particle has an average particle diameter (d) of 5 to 300 nm, an aspect ratio of 1.00 or more and 1.20 or less, and a carbon content of 0.005% by mass or more and less than 0.50% by mass.

Silica-based polishing particle and abrasive

Provided is a silica-based polishing particle, particularly suitable for primary polishing, which provides a high polishing rate on the surface of a substrate and which prevents particle residues on the substrate after polishing, and an abrasive including the silica-based polishing particle. A silica-based polishing particle with a three-dimensional polycondensation structure containing an alkoxy group, wherein the particle has an average particle diameter (d) of 5 to 300 nm, an aspect ratio of more than 1.20 and 5.00 or less, and a carbon content of 0.005% by mass or more and less than 0.50% by mass.

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Kitakyushu, Japan

Ryo Muraguchi