3M Innovative Properties Company

Gemalto Sa

Ryan E Marx

James M Nelson

Jeffrey Jacob Cernohous

Kenneth Jason Hanley

John W Longabach

William J Schultz

Wendy L Thompson

Todd D Jones

Myles Lee Brostrom

James Robert McNerney

Audrey A Sherman

Joseph D Rule

Kevin R Schaffer

John Charles Clark

Christopher Bland Walker, Jr

Douglas Eugene Weiss

Alexander J Kugel

Steven J McMan

Charlie C Ho

Bryan C Feisel

Mark E Napierala

Vivek Krishnan

Jeffrey G Linert

Neil R Granlund

Siegmund Papp

Terri A Shefelbine

Shivshankar Venkataramani

Gerald F Fleischhacker

Toheeb B Alabi

Babu Nana Gaddam

Duane Douglas Fansler

Kui Chen-Ho

Maureen Ann Kavanagh

Daniel E Meyer

Jay M Jennen

Michael John Annen

Michael P Daniels

Christopher K Haas

Kent S Tarbutton

David Adrian Ylitalo

Steven J Rhyner

Gezahegn D Damte

Steven Dean Koecher

Jay R Lomeda

Armin Kayser

Krystal K Hunt

Jason P Pettengill

David A Ylitalo

Steven J Mcman

Kenneth J Hanley

James R Mcnerney

The provided surface protection films include a plurality of layers in the following order: a first polymeric film that is exposed at a major surface of the surface protection film; a foamed adhesive; a second polymeric film; and a pressure-sensitive adhesive. The surface protective films withstand impacts and harsh outdoor conditions, and can be easily applied and removed while minimizing or eliminating the need to use personal protective equipment and volatile organic compounds.

Surface protection film and related methods

Thermally stable microstructured layers comprising polyurethane, polyurea and/or polyurethane/urea semi-IPN materials are provided which have microstructured surfaces which are highly durable, erosion resistant, and thermally stable. The microstructured layer comprises a semi-IPN of a polymer network selected from the group consisting of urethane acrylate polymer networks, urethane/urea acrylate polymer networks and urea acrylate polymer networks and a linear or branched polymer that is a thermoplastic polymer selected from the group consisting of thermoplastic polyurethanes, thermoplastic polyurethane/polyureas, thermoplastic polyureas, and combinations thereof. The microstructures are thermally stable at temperatures above the crossover point of the thermoplastic polymer, despite comprising a majority of such thermoplastic material. In another aspect, the present disclosure provides methods of making microstructured layers according to the present disclosure.

Thermally stable microstructured semi-IPN layer

Optical adhesives that also diffuse visible light include a blend of an adhesive matrix which is an optical adhesive and a block copolymer. The adhesive may be a pressure sensitive adhesive and contains either acid or basic functionality. The block copolymer, which may be a diblock copolymer, contains a high Tg block and a functional block, the functionality of the functional block is complimentary to the functionality of the adhesive matrix to form an acid-base interaction. The adhesive may also contain a crosslinking agent.

Optical adhesive with diffusive properties

An article may include a biodata page defining a perimeter including an edge and a hinge layer attached to at least a portion of the biodata page. The hinge layer comprises a cross-linked polyurethane. In some examples, the hinge layer may include a cross-linked thermoset polyurethane.

Flexible hinge material comprising cross-linked polyurethane material

Polyurethane nanocomposites are provided which include a polyurethane and surface modified silica nanoparticles covalently bound into the polyurethane. High loadings in excess of 30% may be achieved. In some embodiments, the silica nanoparticles are covalently bound to the polyurethane polymer through a linkage derived from a surface-modifying compound comprising a silane functional group and a polyol segment. In some embodiments the polyurethane nanocomposite may be provided as a tape or film. In addition, precursors for a polyurethane nanocomposites are provided comprising: a first polyol and surface modified silica nanoparticles dispersed within the first polyol. In some embodiments, the silica nanoparticles are surface-modified by reaction with a surface-modifying compound comprising a silane functional group and a polyol segment derived from a second polyol, which may be the same or different from the first polyol.

Polyurethane nanocomposites

The present disclosure provides a tape comprising: a) a single layer comprising a crosslinked polymer, selected from the group consisting of crosslinked polyurethane, crosslinked polyurea, and crosslinked mixed polyurethane/polyurea polymer, and b) an adhesive layer. In another embodiment, the tape comprises at least one layer comprising a semi-interpenetrating polymer network of a crosslinked acrylate and an uncrosslinked polymer selected from the group consisting of polyurethane, polyurea, and mixed polyurethane/polyurea polymer.

Erosion resistant films for use on heated aerodynamic surfaces

There is provided an article comprising at least a first surface having a first binder layer selected from at least one of linear resins and resins having low cross link densities, where the first binder layer has a first major surface opposite a second major surface; and a plurality of microspheres at least partially embedded in the first major surface of the first binder layer. There is also provided an article comprising a first surface having a first binder layer selected from at least one of linear resins and resins having low cross link densities; and a plurality of microspheres at least partially embedded a the first major surface of the first binder layer, where for at least a portion of the first major surface the plurality of microspheres covers 30% to 50% of that portion, and the microspheres are substantially uniformly spaced.

Thermoformable microsphere articles

Multilayer polymeric films which may be useful for protecting the leading edges of aircraft from rain and sand erosion are presented. Typical surface protection films comprising two or more layers of a first material alternating with one or more layers of a second material, wherein the first and second materials are different materials, wherein the first and second materials comprise first and second polymers, wherein the first and second materials have a first and second Shore hardness, and wherein the first Shore hardness is greater than the second Shore hardness by more than 5 A or more typically more than 10 A.

Multilayer erosion resistant protective films

There is provided an article comprising at least a first surface having a first binder layer selected from at least one of linear resins and resins having low cross link densities, where the first binder layer has a first major surface opposite a second major surface; and a plurality of microspheres at least partially embedded in the first major surface of the first binder layer. For at least a portion of the first major surface, the plurality of micro spheres may cover 30% to 50% of that portion, and the microspheres may be substantially uniformly spaced.

Briefly, the present disclosure provides a film, tape or outer layer of a composite part comprising: a) at least one layer comprising a crosslinked polymer selected from the group consisting of crosslinked polyurethane, crosslinked polyurea, and crosslinked mixed polyurethane/polyurea polymer; and in some embodiments b) an adhesive layer. In some embodiments the layer additionally comprises a non-crosslinked polymer forming a semi-IPN with the crosslinked polymer. In some embodiments the non-crosslinked polymer may be selected from the group consisting of polyurethane, polyurea, and mixed polyurethane/polyurea polymer. In some embodiments the crosslinked polymer may additionally comprise an acrylate-containing component.

Semi-IPN polyurethane/polyurea protective films

Compositions comprising a plurality of carbon nanotubes, a host polymer, and A block copolymer comprising a first block and a second block, wherein no block is compatible with the host polymer. In one aspect, the block copolymer is amphiphilic. In another aspect, the block copolymer may comprise a first block and a second block, wherein at least one of the first and second blocks comprises repeating units derived from a monomer having the general formula:(R)C&#x2550;C(R)(R)wherein Ris selected from fluorine, a Cto Cfluorinated or perfluorinated alkyl group, and a Cto Cfluorinated or perfluorinated alkoxy group; each R is independently selected from F, H, Cl, R, a Cto Calkyl group, and RA, wherein Ris a Cto Calkylene group and A is selected from COM and SOM, wherein M is selected from H, an ammonium and organo onium group.

Polymer composites

A composition that employs a coupling agent with a fluoropolymer processing aid to address melt-processing issues related to the use of interfering components in melt-processable polymeric binders.

Compositions and method for improving the processing of polymer composites

A deprotectable polymer, activating agent, and layered silicate are combined and the deprotectable polymer is at least partially deprotected to form a composite. The composite may be combined with a polymeric resin to form a nanocomposite.

Method of making composites and nanocomposites

Growing community of inventors

Rosemount, MN, United States of America

Ryan E Marx