Ionics, Inc.

General Electric Company

Bl Technologies, Inc.

Other

Ge Osmonics, Inc.

Ge Ionics, Inc.

Russell James MacDonald

Kai Zhang

Keith James Sims

John H Barber

Yongchang Zheng

Li Zhang

Yonghong Zhao

Russell B Hodgdon

Wayne A McRae

Yan Gao

Samuel S Alexander

Chakravarthy S Gudipati

William W Carson

Arthur L Goldstein

John Harold Barber

Irving D Elyanow

Oleg Grebenyuk

Li May Goh

Hai Yang

Vladimir Grebenyuk

Wojciech Gutowski

Bruce T Batchelder

Jack Peters

James A Lech

Wei Cai

Su Lu

Rihua Xiong

Liping Zheng

Zhigang Deng

Xin Gao

Chengqian Zhang

Thomas J Susa

Hilda R Zanapalidou

The present disclosure provides an electrodialysis stack that may be used for the treatment of an electrically conductive solution. The stack includes two electrodes (at least one is a recessed electrode), a plurality of ion-transport membranes and stack spacers. The membranes and spacers are arranged between the electrodes to define electrodialysis cell pairs. The stack includes an electrically insulated zone that extends substantially from a distribution manifold past the recessed edge of the electrode and substantially from the recessed electrode to the opposite electrode for a distance that is about 8% to 100% of the total distance between the electrodes. The overlap distance that the electrically insulated zone extends past the recessed edge of the electrode is calculated as:distance in cm=(0.062 cm)*(exp(−60/total cp)*(area in cmof the manifold ducts of the concentrated stream at the recessed edge)+/−10%.

Electrodialysis stack

The present disclosure provides an electrodialysis stack that may be used for the treatment of an electrically conductive solution. The stack includes two electrodes (at least one is a recessed electrode), a plurality of ion-transport membranes and stack spacers. The membranes and spacers are arranged between the electrodes to define electrodialysis cell pairs. The stack includes an electrically insulated zone that extends substantially from a distribution manifold past the recessed edge of the electrode and substantially from the recessed electrode to the opposite electrode for a distance that is about 8% to 100% of the total distance between the electrodes. The overlap distance that the electrically insulated zone extends past the recessed edge of the electrode is calculated as: distance in cm=(0.062 cm)*(exp(&#x2212;60/total cp)*(area in cmof the manifold ducts of the concentrated stream at the recessed edge) +/&#x2212;10%.

An ion exchange polymer is provided. The ion exchange polymer is a reaction product of a reaction between a crosslinker monomer and a cationic monomer. The crosslinker monomer is a reaction product of a reaction between a first crosslinking monomer and a second crosslinking monomer. Further, the cationic monomer comprises a quaternary ammonium group. A method for making an ion exchange polymer is also provided. The method comprises a step of preparing a curable solution and a step of curing the curable solution. The step of preparing the curable solution comprises mixing a pair of crosslinking monomers, a cationic monomer that comprises a quaternary ammonium group and an acid. A membrane is also provided. The membrane comprises the ion exchange polymer made by the method provided.

Ion exchange polymers and a method for making ion exchange polymers

An ion-exchange membrane is disclosed here including ion-permeable layers impregnated with an ion-exchange material and arranged in an order from one face of the membrane to the opposite face of the membrane such that opposing layers in the supporting membrane substrate provide sufficiently identical physical properties to substantially avoid irregular expansion when in a salt solution. The ion-permeable layers including at least one non-woven layer and at least one reinforcing layer.

Ion-exchange membrane with multi-layered support substrate

An ion exchange polymer composition is provided, which includes a primary crosslinker and a secondary crosslinker. The primary crosslinker includes a crosslinked ionic monomer including a quaternary ammonium group. A method for making the ion exchange polymer composition and materials prepared from the ion exchange polymer composition are also provided.

Ion exchange compositions, methods for making and materials prepared therefrom

A self-supported ion exchange membrane including a polymerized and crosslinked monomer, where the monomer includes: a least one ionic group, a polymerized group, and a silicate group; and a polymer chemically bonded to crosslinked monomer through the silicate group.

Ion exchange membranes prepared from crosslinked ion exchange polymer compositions

This specification describes an ion exchange membrane and a method of making it. The membrane may be used, for example, in an electrodialysis module or electrochemical cell. The membrane comprises an ion exchange polymer and inorganic particles preferably linked to the ion exchange polymer. To make a membrane, inorganic particles are mixed into an ion exchange membrane pre-cursor. A polymerization initiator or catalyst is then added and the resulting mixture is placed in a form and cured. The inorganic particles may comprise, for example, an oxidized form of graphite such as graphite oxide. The ion exchange polymer may comprise an ionic monomer, containing a quaternary ammonium group for anion exchange or a sulfonate group for cation exchange, along with a crosslinking co-monomer containing polymerizable diacrylic functionalities. The membrane is self-supporting and can be made without a supporting fabric.

Ion exchange membranes containing inorganic particles

An ion exchange membrane and a method of making it. The membrane may be used, for example, in an electrodialysis module or electrochemical cell. The membrane comprises an ion exchange polymer and inorganic particles preferably linked to the ion exchange polymer. To make a membrane, inorganic particles are mixed into an ion exchange membrane pre-cursor. A polymerization initiator or catalyst is then added and the resulting mixture is placed in a form and cured. The inorganic particles may comprise, for example, an oxidized form of graphite such as graphite oxide. The ion exchange polymer may comprise an ionic monomer, containing a quaternary ammonium group for anion exchange or a sulfonate group for cation exchange, along with a crosslinking co-monomer containing polymerizable diacrylic functionalities. The membrane is self-supporting and can be made without a supporting fabric.

A supercapacitor desalination cell comprises a first electrode, a second electrode, a spacer disposed between the first and second electrodes, and a monovalent ion selective layer disposed on at least one of the first and second electrodes. A supercapacitor desalination device and a method for desalination of a liquid are further presented.

Supercapacitor desalination cells, devices and methods

The application describes a method of preparing a polymer that includes: mixing in an aqueous solution comprising water and a water-soluble alcohol: a vinyl-based monomer having a sulfonic acid functional group, a bifunctional vinyl-based cross-linking agent, and a polymerization initiator, to form a reaction solution, where the monomer and the cross-linking agent are soluble in the reaction solution; and polymerizing the monomer and cross-linking agent to form the polymer. The application further describes a polymer that includes a polymer backbone comprising sulfonic acid functional groups; and crosslinks comprising alcohol functional groups.

Cation exchange materials prepared in aqueous media

A bi-polar electrode having ion exchange polymers on opposite faces of a porous substrate is formed using a method that includes providing an electrode substrate with activated carbon layers on opposite faces of the electrode substrate, wherein said faces have an outer perimeter band void of the activated carbon layers. Gaskets are placed against the outer perimeter band of the electrode substrate void of activated carbon and the electrode substrate is clamped between two rigid plates to form a first airtight chamber on one side of the electrode substrate and a second airtight chamber on the opposite side of the electrode substrate. A first polymerizable monomer mixture having an anion exchange group is added into the first chamber and a second polymerizable monomer mixture having a cation exchange group is added into the second chamber. The first and second polymerizable monomer mixtures are then polymerized in an oven.

Vacuum chamber method to form polymer coatings on porous support

A bi-polar electrode having ion exchange polymers on opposite faces of a porous substrate is formed using a method that includes providing an electrode substrate with activated carbon layers on opposite faces of the electrode substrate, wherein said faces have an outer perimeter band void of the activated carbon layers. The electrode substrate is placed in a thermoplastic envelope formed by a pair of polyethylene films. A Mylar sheet is placed in each side of the envelope against the electrode substrate, and the envelope is thermally sealed to the outer perimeter band of the electrode substrate void of activated carbon to form a first pocket on one side of the electrode substrate and a second pocket on the opposite side of the electrode substrate. The method also includes inserting a first polymerizable monomer mixture having an anion exchange group into the first pocket of the envelope and inserting a second polymerizable monomer mixture having a cation exchange group into the second pocket of the envelope. The first and second polymerizable monomers mixtures are then polymerized in an oven.

Simultaneous polymerization of two vinyl monomer mixtures to opposite faces of a flat porous substrate

A novel anion exchange polymer is provided. A method of making the anion exchange polymer includes reacting a tertiary amine, an acid inhibitor and a polyepoxide to form a quaternary ammonium monomer and polymerizing the quaternary ammonium monomer in the presence of a catalyst. The exchange polymer is prepared without using alkyl halides and can be used to make improved ion exchange materials that are chemically resistant and non-fouling.

Growing community of inventors

Wilmington, MA, United States of America

Russell James MacDonald