Toyota Motor Engineering & Manufacturing North America, Inc.

Toyota Jidosha Kabushiki Kaisha

The State University of New York

Toyota Motor Entineering & Manufactirung North America Inc.

Ruigang Zhang

Fuminori Mizuno

Chen Ling

Timothy Sean Arthur

Rana Mohtadi

Nikhilendra Singh

Oscar Tutusaus

Kensuke Takechi

Ruidong Yang

Debasish Banerjee

Hongfei Jia

John Muldoon

Masaki Matsui

M Stanley Whittingham

Claudiu Bogdan Bucur

Gaohua Zhu

Koji Suto

Wei Song

Zehua Chen

Jason Germain

Keiko Kato

Ruibo Zhang

3-D magnesium voltaic cells have a magnesium anode coated on multiple opposing surfaces with a continuous protective/electrolyte layer that is ionically conductive and electronically insulating. The resulting protected 3-D magnesium anode is coated on multiple opposing surfaces with a continuous cathode layer that is electronically and ionically conductive, and includes a magnesium storage medium. Suitable magnesium anodes, in particular, magnesium foam anodes, can be made by pulsed galvanostatic deposition of magnesium on a copper substrate. The protective layer can be formed by electropolymerization of a suitable methylacrylate ester. The continuous cathode layer can be a slurry cathode having powders of an electronic conductor and a reversible magnesium storage component suspended in a magnesium electrolyte solution.

3D magnesium battery and method of making the same

An electrochemical cell includes a metal containing anode M' capturing and releasing cations, a metal containing cathode M&#x2033; and an electrolyte including an anion Xand a cation M&#x2032;. During the charge process, the electrolyte allows reversible reactions wherein the anion dissociates from the electrolyte and reacts with the metal cathode forming M&#x2033;X. At the same time, cations M&#x2032;from the electrolyte deposit on the anode side. The reverse process happens during the discharge process.

Metal-metal battery

A high voltage rechargeable magnesium cell includes an anode and cathode housing. A magnesium metal anode is positioned within the housing. A high voltage electrolyte is positioned proximate the anode. A metal oxide cathode is positioned proximate the high voltage electrolyte. The magnesium cell includes a multi-cycle charge voltage up to at least 3.0 volts and includes a reversible discharge capacity.

High voltage rechargeable magnesium cell

An electrode active material comprising an amorphous or crystalline composite of phosphorous sulfide having the general formula MPs, wherein M is a metal and x, y, and z are positive whole numbers. Electrochemical cells and a reversible battery having a cathode containing one of the electrode active materials are also provided. In specific embodiments, the battery is a magnesium battery. In addition, methods of forming the composites and electrodes via ball milling and in situ electrochemical reactions are provided.

High capacity phosphorous sulfide based cathode materials for magnesium batteries

A magnesium-ion battery containing an anode of magnesium metal, a cathode, capable of absorption and release of Na ions; and a nonaqueous electrolyte containing a sodium ion salt selected from NaHMDS, NaPFand a sodium carborane and a magnesium ion salt selected from PhMgCl&#x2014;AlCl(APC), a Mg carborane, and MgHMDS&#x2014;Cl is provided.

Magnesium battery having an electrolyte containing cations of magnesium and sodium

A method for tuning the thermal conductivity of a nanolayered material is presented. The method includes a step of intercalating the nanolayered material with cations, based on a correlation between cation loading density and thermal conductivity. A bond coat of a thermal barrier system is also disclosed. The bond coat includes a nanolayered material intercalated with cations at a specified loading density based on a correlation between cation loading density and thermal conductivity.

Method for tuning the thermal conductivity of a nanolayered material and thermal insulators prepared thereby

A magnesium electrochemical cell having a positive electrode containing as an active ingredient, a material of formula [VO][MO]and/or a material of formula [VO][MO][MgX]in a metastable structural and morphological phase is provided. In the formulas M is an element selected from the group consisting of P, B, Si, Ge and Mo; and X is O or a halide.

Metastable vanadium oxide cathode materials for rechargeable magnesium battery

An all-solid-state metal-metal battery with both high energy density and high power density is provided. The battery has an anolyte including at least one active anode metal ion conducting ceramic solid and a catholyte including at least one active cathode metal ion conducting ceramic solid sandwiched between an anode including an alkali metal or an alkaline earth metal as the active anode metal and an cathode including a transition metal as the active cathode metal. Prior to the initial charge, the battery may have an anode current collector devoid of the active anode metal or a cathode current collector devoid of the active cathode metal.

All-solid-state metal-metal battery comprising ion conducting ceramic as electrolyte

A positive electrode comprising &#x3b5;-VOPOand/or Na(&#x3b5;-VOPO) wherein x is a value from 0.1 to 1.0 as an active ingredient, wherein the electrode is capable of insertion and release of sodium ions and a reversible sodium battery containing the positive electrode are provided.

Vanadyl phosphates as high energy density cathode materials for rechargeable sodium battery

An oxygen storage material including a compound of the formula: CaMnAlOwherein 0&#x2266;&#x3b4;&#x2266;0.5 wherein the compound includes at least one dopant said dopant selected from alkaline earth ions at the Ca site, trivalent ions at the Al site, and 3transition metal ions at the Mn site wherein the an oxygen release temperature or an oxygen storage temperature is modified in comparison to an un-doped CaMnAlOmaterial.

[object Object]

A magnesium electrochemical cell having a positive electrode containing as an active ingredient, an amorphous material of formula [VO][MgX][MO]is provided. In the formula M is an element selected from the group consisting of P, B, Si, Ge and Mo, and X is O, F, Cl, Br or I.

Vanadium oxide based amorphous cathode materials for rechargeable magnesium battery

An anode active material for a magnesium battery includes a Metal M which electrochemically alloys with magnesium, magnesium, and carbon that are ball milled forming an active material mixture. The mixture may be of the formula: MgM(0&#x2266;a&#x3c;1)+Carbon wherein the mixture is ball milled and has a stoichiometric amount of M and Mg and carbon of from 0.1-50 weight percent of the total mixture.

Preparation of high energy-density electrode materials for rechargeable magnesium batteries

A MnOelectrode active material of high capacity is provided. The high capacity MnOhas a surface area which is greater than 60 m/g and the MnOis obtained by a process comprising a redox reaction of a Mn (II) salt and permanganate at a reaction temperature less than 30&#xb0; C. and a pH of 2 to 4. Also provided are a magnesium electrochemical cell having a cathode containing the MnOand a rechargeable magnesium battery having a cathode containing the MnO.

Magnesium battery having a cathode containing manganese dioxide nanoparticles as active material

A process of forming two dimensional nano-materials that includes the steps of: providing a bulk two dimensional material; providing lithium iodide; suspending the lithium iodide and bulk two dimensional material in a solvent forming a solution; initiating a solvent thermal reaction forming a lithiated bulk two dimensional material. The resulting lithiated bulk two dimensional material may be exfoliated after the solvent thermal reaction forming a two dimensional layered material.

Growing community of inventors

Ann Arbor, MI, United States of America

Ruigang Zhang