Bisco Inc.

Rui Yin

Byoung I Suh

Michelle Schiltz-Taing

Louis J Sharp

Amer Tiba

Adriana Pigozzo Manso

The present application relates to a dental primer adhesive system that is capable of being used as either a one-step or two-step self-etch dental primer and is compatible with self-cure composites and dual-cure composites with reduced permeability.

Dual application mode self-etch dental adhesives compatible with self-cured and dual-cured composites

The present application relates to a polymerizable dental primer/adhesive system comprising a primer component having a relatively hydrophilic monomer component in an amount that renders the system relatively hydrophilic before polymerization of the system and capable of penetrating a prepared dental surface such as etched tooth dentin or enamel, and a multi-functional cross-linking agent in an amount that renders the system relatively hydrophobic after polymerization. A polymerizable hydrophobic monomer component is also included in the primer. The inclusion of said hydrophobic polymerizable monomer and said multi-functional cross-linking agent improves the long term stability or durability of the polymerized primer system to the dental restoration and to the tooth, dentin, enamel and other dental surfaces. An additional hydrophobic resin can also be employed with the primer adhesive system. The dental primer adhesive system exhibits greater stability and durability over time when compared to other dental adhesive systems.

Dental primer adhesive system and optional hydrophobic resin

Dental composite compositions, restorative compositions, and methods for their use are provided. The compositions can contain (a) from about 1 to about 35 weight percent of a monomer portion containing at least one monomer having a functional group capable of undergoing polymerization; (b) from about 75 to about 95 weight percent of a filler portion, the filler portion containing at least a spherical filler portion having at least one spherical filler particle component; and (c) from about 0.01 to about 10 weight percent of a polymerization catalyst portion containing at least one catalyst capable of assisting in the polymerization of the functional group of the monomer portion and hardening of the composite after application of the composite to a tooth surface or other dental surface. The spherical filler portion is present in an amount sufficient to reduce shrinkage of the composite after polymerization to about 1.8 percent or less. Compositions according to the invention are useful in Class I, II, IV, V, Core build-ups, and other types of dental restorations where maximum strength and polishability are desired. Methods for using such compositions in such restorative procedures are also provided.

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Buffalo Grove, IL, United States of America

Rui Yin