Basf Aktiengesellschaft

Badische Anilin- & Soda-fabrik Aktiengesellschaft

Rudolf Kropp

Eckhard Hickmann

Harald Schwahn

Klaus Ebel

Hans Peter Rath

Martin Fischer

Wolfgang Gunther

August Amann

Franz Reicheneder

Hubert Giertz

Jochen Schroeder

Norbert Goetz

Wolfgang Siegel

Bernd Wolf

Hans Theobald

Klaus Halbritter

Beate Trentmann

Franz Merger

Rainer Becker

Wolfgang Hoelderich

Wolfgang Harder

Boris Breitscheidel

Heinrich Adolphi

Karl Kiehs

Walter Himmele

Leopold Hupfer

Josef Gries

Marco Thyes

Albrecht Franke

Hans-Juergen Teschendorf

Adolf Fischer, Deceased

Wolfgang Reif

Rainer Buerstinghaus

Rainer Schlecker

Axel Nuerrenbach

Hartwig Fuchs

Frank Thoemel

Rolf Kretzschmar

Martin Traut

Werner Hoffman

Joerg Schuster

Franz Reicheneder, Deceased

Franz Wenisch

Dora I Reicheneder

Process for producing organic nitrogen compounds, special organic

Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.

Reaction products of polyisobutenes and oxides of nitrogen or mixtures

Use of reaction products of polyolefins and oxides of nitrogen or

The preparation of .alpha.-carbonylphosphine oxides by oxidizing an .alpha.-hydroxyalkyl phosphine oxide with an organic hydroperoxide or of an organic peroxy acid in the presence of a compound of a Group IV to Group VIII metal in the periodic table, and novel .alpha.-hydroxybenzyl phosphine oxides. .alpha.-Carbonylphosphine oxides are used as photoinitiators for polymerizable compositions.

Preparation of carbonylphosphine oxides

Preparation of .alpha.-carbonylphosphine oxides

A process for the preparation of 2,4,6-trimethylbenzoic acid of the formula I ##STR1## in which .alpha.-chloro-2,4,6-trimethylacetophenone is reacted with an alkali hydroxide solution and chlorine in the presence of a phase-transfer catalyst at a temperature ranging from 0.degree. to 150.degree. C. and a pressure ranging from 0.01 to 50 bar, and a process for the preparation of 2,4,6-trimethylbenzoic acid I, in which .alpha.-chloro-2.4.6-trimethylacetophenone of the formula II ##STR2## is reacted with 1,3,5-trimethylbenzene and chloroacetyl chloride in the presence of a catalyst at a temperature ranging from 0.degree. to 150.degree. C. and a pressure ranging from 0.01 to 50 bar, the catalyst used being an iron oxide.

Preparation of 2,4,6-trimethylbenzoic acid

Phenylacetaldehydes of the structure (I) ##STR1## where the substituents X are 2,4-dichloro, difluoro, trifluoro, tetrafluoro, p-trifluoromethyl, 2-methyl-4-fluoro, haloalkoxy or haloalkylthio radicals or are adjacent Cl, F, CF.sub.3, alkyl, alkoxy, haloalkoxy and/or haloalkylthio radicals.

Phenylacetaldehydes and the preparation of phenylacetaldehydes

2-benzylfuryl compounds of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different substituents and are each hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, haloalkylthio, alkenyl or haloalkenyl, each of not more than 6 carbon atoms, n being 1, 2 or 3 where R.sup.3 is not hydrogen, and R.sup.4 and R.sup.5 are each hydrogen or alkyl of not more than 6 carbon atoms, R is --CHO or CHR.sup.6 OA, R.sup.6 is hydrogen, cyano, alkyl, alkenyl, haloalkenyl or alkynyl, each of not more than 6 carbon atoms, or carboxamide, and A is either hydrogen or a radical of an acid typical for pyrethroids, with the proviso that R.sup.2 is not hydrogen, chlorine, bromine, methyl or methoxy when R.sup.1 is hydrogen or methyl and R.sup.3 and A are each hydrogen, and furthermore with the proviso that R.sup.1 and R.sup.2 are not methyl when A is a radical of tetramethylcyclopropanecarboxylic acid, and finally with the proviso that R.sup.2 is not methyl, chlorine, bromine or methoxy and R.sup.1 and R.sup.3 are not hydrogen when A is a radical of chrysanthemumic acid, their preparation and their use as intermediates for crop protection agents or as crop protection agents.

Pyrethroids and their use for controlling pests

Novel 1-phenyl-4(1H)-pyridazinone-imines of the formula (I) ##STR1## which are substituted at the imine nitrogen, and their addition salts with a physiologically tolerated acid, processes for their preparation, pharmaceutical formulations containing these compounds, and their use as drugs, in particular as antidepressants, antiparkinson drugs and antihypotonic agents.

Novel pyridazinone-imines and their physiologically tolerated addition

Oximinophosphoric acid derivatives of the formula ##STR1## where R.sup.1 is a straight-chain or branched alkyl of not more than 4 carbon atoms, R.sup.2 is a straight-chain or branched alkoxy or alkylthio group of not more than 4 carbon atoms, straight-chain or branched alkyl of not more than 3 carbon atoms, phenyl, amino or a straight-chain or branched alkylamino or dialkylamino radical, where alkyl in each case is of not more than 4 carbon atoms, and X is oxygen or sulfur, a process for the manufacture of these oximinophosphoric acid derivatives, and their use for controlling pests.

Oximinophosphoric acid derivatives, and their use for controlling pests

Salts of 1,2,3,4-tetrahydro-.beta.-carbolines of the formula I ##STR1## where R is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or trifluoromethyl, x is halogen and n is an integer from 2 to 5, and their preparation are described. The compounds are intermediates for the preparation of pharmacologically active substances.

Process for the preparation of a salt of

Preparation of 5-(2,2-dihalovinyl)-4,4-dialkyl-tetrahydro-furan-2-ones of the formula I ##STR1## where R.sup.1 and R.sup.2 are each alkyl of 1 to 4 carbon atoms and X is halogen, by reacting a carboxylic acid amide of the formula II ##STR2## where R.sup.3 and R.sup.4 are each alkyl of 1 to 4 carbon atoms, aralkyl of 7 to 9 carbon atoms or aryl of 6 to 10 carbon atoms, or together with the nitrogen form a 5-membered or 6-membered saturated ring which may contain a second hetero-atom, with a carbon tetrahalide of the formula III

Preparation of 5-(2,2-dihalovinyl)-4,4-dialkyl-tetrahydro-furan-2-ones

Preparation of 5-(2,2,2-trihaloethyl)-4,4-dialkyl-tetrahydro-furan-2-ones of the formula I ##STR1## where R.sup.1 and R.sup.2 are each alkyl of 1 to 4 carbon atoms and X is halogen, by reacting a carboxylic acid amide of the formula II ##STR2## where R.sup.3 and R.sup.4 are each alkyl of 1 to 4 carbon atoms, aralkyl of 7 to 9 carbon atoms or aryl of 6 to 10 carbon atoms or together with the nitrogen on which they are present as substituents form a 5-membered or 6-membered saturated ring which may contain a second hetero-atom, with a carbon tetrahalide of the formula III

Preparation of 5-(2,2,2-trihaloethyl)-dialkyl-tetrahydrofuran-2-ones

Growing community of inventors

Limburgerhof, Germany

Rudolf Kropp