The Dow Chemical Company

Ross C Whiteside, Jr

George A Doorakian

Kenneth W Anderson

Adolphus V Gist

Deborah I Haynes

James L Bertram

Marvin L Dettloff

William Davis

Jody R Berman

Dennis L Steele

Deborah L Haynes

Advanced epoxy resin compositions are prepared by reacting a composition comprising (1) an aromatic hydroxyl-containing product resulting from reacting a composition comprising (a) at least one diglycidyl ether of (i) an oxyalkylated aromatic diol, or (ii) at least one compound having two hydroxyl groups per molecule in which the hydroxyl groups are attached to an aliphatic or cycloaliphatic carbon atom and which compound is free of aromatic rings; or (iii) a combination of (i) and (ii); and (iv) optionally a diglycidyl ether compound different from (i) and (ii); and (b) at least one compound containing two aromatic hydroxyl groups per molecule; (2) at least one diglycidyl ether of a compound containing two aromatic groups per molecule; (3) optionally, one or more compounds containing two aromatic hydroxyl groups per molecule; and (4) optionally, a monofunctional capping agent. The advanced resins are useful in coating compositions.

Epoxy resin advanced with polyphenol/oxyalkylated aromatic or

Cationic advanced resins are obtained by (I) reacting a composition comprising (A) an advanced epoxy resin composition comprising the product resulting from reacting a composition comprising (1) an aromatic hydroxyl-containing product resulting from reacting a composition comprising (a) at least one diglycidyl ether of (i) an oxyalkylated aromatic diol, or ii) at least one compound having two hydroxyl groups per molecule in which the hydroxyl groups are attached to an aliphatic or cycloaliphatic carbon atom and which compound is free of aromatic rings; or (iii) a combination of (i) and (ii); and (iv) optionally a diglycidyl ether compound different from (i) and (ii); and (b) at least one compound containing two aromatic hydroxyl groups per molecule; (2) at least one diglycidyl ether of a compound containing two aromatic groups per molecule; (3) optionally, one or more compounds containing two aromatic hydroxyl groups per molecule; and (4) optionally, a monofunctional capping agent; with (B) a nucleophilic compound; and (II) adding an organic acid and water at at least one point during the preparation of the cationic resin. The cationic advanced resins are useful in coating compositions.

Phenol-terminated oxyalkylated or (cyclo)aliphatic diglycidyl ethers

A composition useful as an electrodepositable coating comprises a curing agent and an advanced epoxy resin prepared by advancing a diglycidyl ether of a dihydric phenol with an aromatic hydroxyl-containing reaction product of a diglycidyl ether of an oxyalkylated dihydric phenol and/or a diglycidyl ether of a (cyclo) aliphatic diol, optionally with a dihydric phenol and/or a monofunctional capping agent, combined with a diglycidyl ether of a dihydric phenol.

Epoxy resin advanced with diphenol/diglycidyl ether adducts

Disclosed are thermosettable compositions comprising (A) an epoxy resin such as the diglycidyl ether of bisphenol A; (B) boron trifluoride complexed with a primary, secondary or tertiary amine such as monoethanolamine and (C) at least one cyclic or acyclic phosphazene having at least one pendant ##STR1## group wherein Z is an alkyl or an aryl group such as hexa(n-propylamino)cyclotriphosphazene. When cured, these compositions have an increased glass transition temperature (Tg) value as compared to a similar composition without the phosphazene compound. These compositions are useful in potting compositions, wet lay-up and pre-impregnated laminate, adhesive, molding, coating, casting, encapsulation, filament winding and transfer molding applications.

Thermosettable epoxy resin composition

Resin compositions are prepared by reacting an epoxy resin with an amine-substituted aromatic sulfonic acid amide at a temperature up to about 130.degree. C. The resultant product can be cured by heating to a temperature of at least about 150.degree. C. in the presence of suitable curing agents and in some instances in the absence of any curing agent.

Adducts of epoxy resins and amino-substituted aromatic sulfonic acid

Epoxy resins having improved properties are prepared by reacting an epoxy resin with a dihydric phenol in the presence of a sufficient quantity of a phosphonium catalyst such that the product resulting from reacting a mixture of the catalyst, epoxy resin and dihydric phenol has a % epoxide difference from the theoretical percent epoxide of from about 0.5 to about 4.0.

Process for preparing epoxy resins having improved physical properties

Epoxy resins having improved physical properties when cured

The preparation of substrates impregnated with epoxy resins and curing agents therefor is improved by employing as the epoxy resin one which has been prepared by reacting a low equivalent weight epoxy resin having an aliphatic halide content of at least about 500 ppm such as a diglycidyl ether of bisphenol A with a dihydric phenolic compound such as tetrabromo bisphenol A in the presence of an alkali metal hydroxide such as potassium hydroxide.

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Angleton, TX, United States of America

Ross C Whiteside, Jr