Minnesota Mining and Manufacturing Company

3m Innovative Properties Company

Rosa Uy

Timothy M Dietz

Chung I Young

Ying-Yuh Lu

Robert A Asmus

Olester Benson, Jr

Daniel C Duan

Arlene J Mencke

Carol E Hendrickson

Steven S Kantner

Rafael M Yasis

Steven K Itoh

Barbara J Marcus

A method for making a bicontinuous, conductive, pressure sensitive adhesive (PSA), such that the starting microemulsion has a convenient viscosity for coating, and such that only a single polmerization step is needed. This has been accomplished by the discovery of a class of thickening agents having a carboxylic acid functionality that are compatible with the microemulsion and yet do not damage the properties of the final adhesive.

Microemulsion compositions and methods of making and using same

A polymerized microemulsion pressure sensitive adhesive composition is described. The composition has peel adhesion of at least 3 Newtons/100 mm as measured according to a PSTC-1 Test. The composition preferably has a bicontinuous structure of a continuous phase of a hydrophobic pressure sensitive adhesive polymer and a continuous phase of a hydrophilic polymer. The bulk properties of both polymers are retained in the bicontinuous structure. The composition is prepared from a microemulsion comprising a free-radically ethylenically unsaturated polar amphiphilic or hydrophilic monomer or oligomer in the aqueous phase, a free-radically ethylenically unsaturated hydrophobic monomer, having a glass transition temperature suitable for forming a pressure sensitive adhesive, in the oil phase, water, and surfactant. Uses for the pressure sensitive adhesive composition include biomedical articles, such as biomedical electrodes, medical skin coverings, and pharmaceutical delivery devices, and industrial articles, such as zinc/adhesive tapes used for cathodic protection of rebars embedded in concrete.

Polymerized microemulsion pressure sensitive adhesive compositions and

Biomedical electrode comprising polymerized microemulsion pressure

A method of making and using diagnostic electrodes is disclosed. The method of making involves the coating of both conductive adhesive and biocompatible pressure sensitive adhesive on to a flexible non-conductive backing material on a side that has at least a portion thereof covered with an electrically conductive surface. The method of coating the electrodes is very cost efficient and economical. The use of the electrode enjoys the advantage of controlled coating thicknesses such that both types of adhesive in their final thicknesses have contact with skin of a patient.

Method of manufacturing a diagnostic electrode

A polymerized microemulsion pressure sensitive adhesive composition is described. The composition preferably has a biocontinuous structure of a continuous phase of a hydrophobic pressure sensitive adhesive polymer and a continuous phase of a hydrophilic polymer. The bulk properties of both polymers are retained in the bicontinuous structure. The composition is prepared from a microemulsion comprising a free-radically ethylenically unsaturated polar amphiphilic or hydrophilic monomer or oligomer in the aqueous phase, a free-radically ethylenically unsaturated hydrophobic monomer, having a glass transition temperature suitable for forming a pressure sensitive adhesive, in the oil phase, water, and surfactant. Uses for the pressure sensitive adhesive composition include biomedical articles, such as biomedical electrodes, medical skin coverings, and pharmaceutical delivery devices, and industrial articles, such as zinc/adhesive tapes used for cathodic protection of rebars embedded in concrete.

A polymerized microemulsion pressure sensitive adhesive composition is described. The composition has peel adhesion of at least 3 Newtons/ 100 mm as measured according to a PSTC-1 Test. The composition preferably has a bicontinuous structure of a continuous phase of a hydrophobic pressure sensitive adhesive polymer and a continuous phase of a hydrophilic polymer. The bulk properties of both polymers are retained in the bicontinuous structure. The composition is prepared from a microemulsion comprising a free-radically ethylenically unsaturated polar amphiphilic or hydrophilic monomer or oligomer in the aqueous phase, a free-radically ethylenically unsaturated hydrophobic monomer, having a glass transition temperature suitable for forming a pressure sensitive adhesive, in the oil phase, water, and surfactant. Uses for the pressure sensitive adhesive composition include biomedical articles, such as biomedical electrodes, medical skin coverings, and pharmaceutical delivery devices, and industrial articles, such as zinc/adhesive tapes used for cathodic protection of rebars embedded in concrete.

Solid state conductive polymer compositions which are ionically-conductive regardless of the amount of water present in the composition are disclosed. The compositions have solvating polymer, ionic salt, and optionally if the composition is not cohesive and pliable, essentially non-volatile plasticizer in an amount sufficient to render the composition cohesive and pliable. Biomedical electrodes having means for electrical communication contacting the compositions are also disclosed. Methods of making the compositions and electrodes are also disclosed.

Solid state conductive polymer compositions

Biomedical electrodes containing solid state conductive polymer

A hydrophilic, pressure-sensitive adhesive composition prepared by irradiating solid poly(N-vinyl lactam) with ionizing radiation to crosslink the poly(N-vinyl lactam) and thereafter mixing the radiation-crosslinked poly(N-vinyl lactam) with essentially unirradiated plasticizer in an amount sufficient to form a cohesive, pressure-sensitive adhesive composition. The composition is useful as a biomedical adhesive for transmitting or receiving electrical signals as a component of a biomedical electrode. The composition is also useful as a drug delivery device to deliver pharmaceuticals or other active ingredients to or through mammalian skin. The composition is also useful as a component in a skin covering for protecting mammalian skin or mammalian skin openings with antimicrobial agents. A method of preparation of the composition is also disclosed.

Pressure-sensitive poly(N-vinyl lactam) adhesive composition and

A hydrophilic, pressure-sensitive adhesive composition prepared by irradiating solid poly(N-vinyl lactam) with ionizing radiation to crosslink the poly(N-vinyl lactam) and thereafter mixing the radiation-crosslinked poly(N-vinyl lactam) with essentially unirradiated plasticizer in an amount sufficient to form a cohesive, pressure-sensitive adhesive composition. The composition is useful as a biomedical adhesive for transmitting or receiving electrical signals as a component of a biomedical electrode. The composition is also useful as a drug delivery device to deliver pharmaceuticals or other active ingredients to or through mammalian skin. The composition is also useful as a component in a skin covering for protecting mammalian skin Or mammalian skin openings with antimicrobial agents. A method of preparation of the composition is also disclosed.

Method for producing pressure sensitive poly (N-vinyl lactam)

Pressure-sensitive poly(n-vinyl lactam) adhesive composition and skin

Solid state conductive polymer compositions, biomedical electrodes

The present invention discloses a low impedance, water-absorbing, ionically-conductive, hydrophilic pressure sensitive adhesive composition comprising an ionically-conductive, hydrophilic, pressure sensitive adhesive hydrogel and crosslinked poly(N-vinyl lactam) in an amount sufficient to retain low electrical impedance and maintain hydrogel adhesion and cohesion during use of the composition in the presence of water and other moisture tending to plasticize the hydrogel. Crosslinked homopolymers and copolymers of poly(N-vinyl pyrrolidone) having Swelling Capacity of at least 15 milliliters of water per gram of poly(N-vinyl pyrrolidone) are preferred. Adhesion values upon removal from mammalian skin after about four hours of adhesion are not greater than initial adhesion removal values, demonstrating ease of removal of electrodes of the present invention from skin.

Low impedance pressure sensitive adhesive composition and biomedical

A two-phase composite of ionically-conductive pressure-sensitive adhesive, biomedical electrodes using the composite and methods of preparing the composite and the electrode are disclosed. The continuous phase is a hydrophilic, solid state pressure-sensitive adhesive composition ionically-conductive regardless of an amount of water present in the composition. The discontinuous phase are domains of a hydrophobic pressure-sensitive adhesive which enhances adhesion of the composite to mammalian skin while maintaining acceptable alternating current impedance of the composite.

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Saint Paul, MN, United States of America

Rosa Uy