The Dow Chemical Company

Ronald W Diesen

Kenneth A Burdett

Stanley S King

Ravi S Dixit

Michael M Olken

John R Moyer

A composition comprising a copper(I) impregnated aluminosilicate zeolite wherein the zeolite is selected from faujasites, L and .OMEGA., and wherein the zeolite has a silica to bulk alumina molar ratio between about 12 and about 50 and a silica to framework alumina molar ratio of at least about 15. The catalyst preparation involves in the following order: drying the selected zeolite, impregnating the dried zeolite with a copper(II) salt, calcining the copper(II)-impregnated zeolite, and reducing the copper(II) to copper(I). The composition is useful as a catalyst for the cyclodimerization of 1,3-butadiene to 4-vinylcyclohexene.

Copper-impregnated zeolite composition

A process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes. The process involves contacting butadiene with a copper (I)-aluminosilicate zeolite prepared by (a) an impregnation method, or (b) heating a solid mixture of a copper salt and the zeolite, or (c) contacting vapors of a copper salt with the zeolite. The catalysts exhibit long life and good activity in the claimed process. The impregnated Cu(I)-catalyst is claimed.

Process for the cyclodimerization of 1,3-butadienes to

Aromatic compounds such as ethylbenzene and styrene are produced by contacting butadiene or 4-vinylcyclohexene in a flow reactor with a magnesium oxide, zinc oxide, calcium oxide, strontium oxide, or barium oxide. The products of the process contain low levels of xylene.

Dehydrocyclization of unsaturated hydrocarbons to aromatic products

Butadiene is converted to ethylbenzene or styrene or both by contacting butadiene with a catalyst containing molybdenum.

Process for converting butadiene to styrene or ethylbenzene or both

A process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes comprising contacting a butadiene in the presence of a promoting amount of a hydroxylic solvent with a catalyst containing copper(I) ions supported on a carrier. A second process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes comprising contacting a butadiene with a catalytic amount of a copper(I)-impregnated aluminosilicate zeolite characterized by a bulk SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio in the range from about 5 to about 50 and a framework SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least about 15. A catalyst composition comprising a copper(I)-impregnated zeolite of specified bulk and framework silica to alumina molar ratios and specified water content. The catalyst exhibits high activity and long lifetime in the aforementioned dimerization processes and is easily regenerated.

Monosubstituted saturated lower hydrocarbons are oxyhalogenated selectively to saturated dihalohydrocarbons at 180.degree.-350.degree. C. in the presence of a catalyst which is formed by depositing a variable valence metal compound on a zeolitic support in such a manner that the catalyst can be employed to selectively produce ethylene dichloride and ethylene from ethyl chloride.

Catalytic process for ethylene dichloride

Saturated C.sub.1-6 hydrochlorocarbons are dehydrochlorinated by contacting with ZSM-5 or silicalite zeolites at 200.degree. C.-400.degree. C.

Catalytic dehydrohalogenation process

An anionic co-catalyst system is provided for the oxidation of organic compounds in aqueous solutions. After the solution is acidified, a nitrate ion source and at least one of either a bromide or an iodide ion source are introduced into the solution which is heated in the presence of an oxidizing agent.

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Midland, MI, United States of America

Ronald W Diesen