Greene, Tweed Technologies, Inc.

Delsper, LP

Daikin Industries, Ltd.

University of Massachusetts

Green, Tweed Technologies

Greene, Tweed of Delaware, Inc.

Ronald R Campbell

William Franklin Burgoyne, Jr

Mookkan Periyasamy

Charles Pence Burke

Kerry Drake

Christopher Corrado

Brian Alan Ux

Carmin Quartapella

Elizabeth Sassano

Burak Bekisli

Gary Reichl

Robert Anthony Rey

Michael A Hickner

Eugene Gurevich

Joey Mead

Wojciech Jan Hajduczek

Erin E Keaney

Leeda Phaen

Stephen Burbine

ShibShankar Banerjee

Lachlan Peeke

Kerry A Drake

Charles P Burke

Charles P Bruke

Robert Rey

An apparatus suitable for extruding curable polymers for forming elastomer articles using additive manufacturing, and curable fluorine-containing polymer compositions suitable for use in such an apparatus are disclosed along with an additive manufacturing method for forming a fluorine-containing elastomer article including providing a filament formed of a curable fluoropolymer composition; providing an additive manufacturing printer having a drive mechanism and a printer nozzle; feeding the filament into an additive manufacturing printer through the drive mechanism and through a longitudinal passage defined by an interior wall of a support tube, wherein the support tube extends from a first end to a second end, and wherein the second end of the support tube is positioned near an inlet to a printer nozzle; applying heat to the filament; and printing successive layers of the heated filament exiting an outlet of the nozzle onto a substrate using the additive manufacturing printer to form the fluorine-containing elastomer article.

Articles formed from fluorine-containing elastomer compositions using an additive manufacturing method and additive manufacturing methods for thermoset elastomer compositions

A method is described for forming composite articles comprising thermoset silicon-containing polymers, that includes (a) providing a first composition comprising a first thermoset silicon-containing polymer; (b) providing a thermoplastic composition; (c) printing a first at least partial layer of the first composition comprising the first thermoset silicon-containing polymer using an additive manufacturing device; and (d) printing an at least partial reinforcing layer comprising the thermoplastic composition using an additive manufacturing device. Also described in an apparatus for preparing a composite article comprising thermoset silicon-containing polymers that includes an additive manufacturing printer having a printer drive mechanism, a first printing nozzle for forming a first layer of a first composition; and a second printing nozzle for forming a second layer of a second composition, wherein the additive manufacturing printer is capable of providing two or more layers of each of the first and the second composition to form a three-dimensional composite article of the first and the second composition according to a computer design model, and wherein at least one of the first printing nozzle and the second printing nozzle is a pressurized printing nozzle comprising a heating mechanism in operable contact therewith.

Method for forming layered thermoset silicone and thermoplastic articles using additive manufacturing, articles formed therefrom and apparatus for use therein

The invention includes a method of bonding a perfluoroelastomer material to first surface that includes: (a) contacting a first surface with a bonding agent comprising a curable perfluoropolymer and a curing agent; (b) curing the bonding agent to form a perfluoroelastomer material that is bonded to the first surface. In the practice of such method, the bonding agent may be a solution prepared by dissolving the curable perfluoroelastomer and the curing agent in a solvent. In an embodiment of the invention, the perfluoroelastomer material formed in step (b) is a coating layer or, alternatively, the first surface is a surface of a perfluoroelastomer member and the perfluoroelastomer material formed is a perfluoroelastomer weld.

Method of bonding perfluoroelastomeric materials to a surface

The invention provides a curable fluoroelastomeric composition comprising: (i) a fluoropolymer comprising at least one cure site monomer that comprises at least one cyano group; (ii) a cure system comprising a functionalized biphenyl-based compound and at least one of: a dioxime compound represented by the formula (I): HON&#x2550;R&#x2550;NOH 

Oxygen plasma-resistant composition characterized by low sticking, and related methods

The disclosure herein includes rapid gas decompression (RGD)-resistant fluoroelastomeric compositions and includes a curable fluoropolymer having a curesite monomer with at least one functional group capable of curing with a peroxide curative. The compositions include a bisphenyl-based curative and an organic peroxide curative and an organic peroxide co-curative. The fluoroelastomeric compositions have a ratio of the bisphenyl-based curative to the organic peroxide co-curative of about 0.25:1 to about 1.5:1 and a ratio of the bisphenyl-based curative to the organic peroxide of about 0.5:1 to about 1.5:1. Such compositions can be formed into seals meeting RGD industry standards in a variety of sizes, up to and/or exceeding 5 mm in thickness or cross-sectional diameter.

Rapid gas decompression-resistant fluoroelastomer compositions and molded articles

A method and compositions are described which improve extrusion-and creep-resistance of components for use in a high temperature applications including sealing elements and seal connectors among others. The method includes providing a composition having an aromatic polymer and a crosslinking compound, and subjecting the composition to a heat molding process to form the component and crosslink the aromatic polymer.

Anti-extrusion compositions for sealing and wear components

A method and compositions are described which improve extrusion- and creep-resistance of components for use in a high temperature applications including sealing elements and seal connectors among others. The method includes providing a composition having an aromatic polymer and a crosslinking compound, and subjecting the composition to a heat molding process to form the component and crosslink the aromatic polymer.

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Harleysville, PA, United States of America

Ronald R Campbell