Corning Incorporated

Ronald L Andrus

John F MacDowell

Linda Ruth Pinckney

George Halsey Beall

Stephan Lvovich Logunov

Christine Coulter Wolcott

Sabyasachi Sen

Glasses in the Ca&mdash;Al&mdash;Si system are useful in forming optical components for use in telecommunication systems. The glasses include, in mole percent: SiO present in an amount of about 6 to about 60 percent, Ga O , Al O , or a combination thereof present in an amount of about 12 to about 31 percent, and CaO present in an amount of about 20 to about 65 percent.

Ca-Al-Si oxide glasses and optical components containing the same

The present invention is directed at a glass-ceramic having high strength and toughness and containing miserite as a predominant crystal phase. The glass-ceramic has a composition calculated in terms of a weight percent on the oxide basis comprising 40-68% SiO.sub.2, 12-35% CaO, 8-20% CaF.sub.2, 4-10.5% K.sub.2 O, 0-5% Al.sub.2 O.sub.3, 0-5% B.sub.2 O.sub.3, 0-15% P.sub.2 O.sub.5, 0-4% R.sub.2 O.sub.3, wherein R represents Y.sup.3+ and rare earth metals in the lanthanide series, and 0-5% of optional constituents selected from the group consisting of MgO, SrO, BaO, Na.sub.2 O, Nb.sub.2 O.sub.5, ZrO.sub.2, and ZnO, and 0-10% of optional constituents selected from the group consisting of Nb.sub.2 O.sub.5 and TiO.sub.2 and 0-2% Li.sub.2 O as an optional constituent. The glass-ceramic may contain secondary phases of cristobalite (SiO.sub.2), fluorite (CaF.sub.2), xonotlite (Ca.sub.6 Si.sub.6 O.sub.17 F.sub.2), and fluorapatite (Ca.sub.5 (PO.sub.4).sub.3 F), and small amounts of other calcium silicate phases such as wollastonite (CaSiO.sub.3).

Strong miserite glass-ceramics

This invention is directed to the production of thermally crystallizable glasses which, upon heat treatment in contact with alumina particulates, will form a strong glass-ceramic-bonded composite body, the excellent bonding being attributed to the presence of lithium aluminoborate crystals. The glass-ceramic composition consists essentially, in weight percent, of

Lithium aluminoborate glass-ceramics

An article of manufacture comprising protectively coated titanium, titanium alloy or titanium aluminide, and a method for making it, wherein the protective coating is an adherent crystalline alkaline earth silicate glass-ceramic coating having a composition consisting essentially, in weight percent on the oxide basis, of about 20-75% total of oxides selected in amounts not exceeding the indicated proportions from the group consisting of up to about 50% BaO, 55% SrO, and 35% CaO, 25-60% of SiO.sub.2 and, as optional constituents, 0-25% MnO, 0-20% MgO, and 0-30% total of other compatible bivalent and trivalent metal oxides. The coating is applied as a continuous glassy coating and is converted to a crystalline glass-ceramic coating by heat treatment.

Glass-ceramic coatings for titanium-based metal surfaces

This invention is directed to the formation of glass bonded ceramic composite articles, with particular emphasis on forming abrasive products such as grinding wheels. The glasses consist essentially, in weight percent of 15-35% CaO, 35-55% B.sub.2 O.sub.3, and 10-35% SiO.sub.2, with alumina comprising the preferred abrasive particles being bonded into an abrasive product.

Glass bonded ceramic composites

There is disclosed a coated article composed of a metal alloy substrate, the metal alloy having a nickel, chromium, cobalt or iron base, and a coating that serves as an oxygen barrier to insulate the metal surface from oxygen attack at temperatures which may range up to 1200.degree. C. The coating comprises a glass-ceramic selected from barium silicate and strontium silicate systems characterized by additives that enable forming a continuous well flowed glass coating prior to setting of the coating by crystallization. These additives include the refractory oxides Al.sub.2 O.sub.3, ZrO.sub.2 and Y.sub.2 O.sub.3, the transition metal oxides MnO, CoO, NiO and FeO, and MgO.

Coated metal article

For protection against oxidation or other adverse chemical deterioration, substrates such as carbon, intermetallic aluminides, and refractory metal alloys are provided with barrier coatings of an aluminoborate glass-ceramic coating having a composition, in weight percent, of about 10-55% Al.sub.2 O.sub.3, 4-40% B.sub.2 O.sub.3, up to 70% total of RO, wherein RO consists of one or more alkaline earth metal oxides selected in amounts not exceeding the indicated proportions from the group consisting of up to 70% BaO, up to 60% SrO, up to 40% CaO, and up to 25% MgO, up to 35% total of R.sub.2 O, wherein R.sub.2 O consists of one or more alkali metal oxides selected in amounts not exceeding the indicated proportion from the group consisting of up to 35% Na.sub.2 O, up to 30% K.sub.2 O, and up to 15% Li.sub.2 O, up to 25% total of metal oxides selected from the group consisting of ZnO and MnO, up to 30% of SiO.sub.2, and up to 10% F.

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Painted Post, NY, United States of America

Ronald L Andrus