Dubois Chemicals, Inc.

Diversey, Inc.

Chemed Corporation

Ronald J Christensen

Gary L Baker

Lyle H Steimel

Water in a process water system, such as a cooling tower or pulp and paper processing plant, is treated to destroy biological microorganisms by diverting the portion of the water flowing through the system to a side stream. In the side stream, chemicals are added such as halide ions or sodium chlorite. The water is then passed through an electrolysis unit or a UV radiation unit to oxidize the precursor to form an active oxidant. Advantageously, the pH of the side stream can be lowered to significantly improve the oxidization of the halide ions. When a very small portion of the flow rate is passing through the side stream, the acid added does not significantly alter the pH of the entire system. In a preferred embodiment, the acid added is phosphonic acid which acts as an antiscalant. Also included in the present invention is a method to inject oxidant precursors into a process water system through an oxidant generation station.

Method and apparatus for controlling microorganisms

An inert water soluble dye is added to a concentrated water treatment composition. This mixture is added to the water in a circulating water system such as a cooling tower. The concentration of the dye and the concentration of the actives in the treatment composition are proportionate to each other. The concentration of the treatment composition in the water system can be determined by measuring the percentage of light absorbed by the dye in the water. This can be determined by use of a colorimeter. Fluorescein is the preferred dye.

Method for detection and quantitative analysis for water treatment

An oxygen scavenger for boiler water includes ascorbic acid neutralized with diethylaminoethanol. The diethylaminoethanol provides condensate treatment for the long and short steam lines and improves the scavenging of the ascorbic acid.

Oxygen scavenger for boiler water and method of use

An all in one boiler water treatment composition includes an oxygen scavenging system, an alkalinity control agent such as sodium carbonate, diethylaminoethanol as a condensate treatment, a polymer system including polymethacrylate or polyacrylate and polymaleic acid along with an oxygen scavenging system. The oxygen scavenging system includes the diethylaminoethanol, a polyhydroxy acid and a sulfite.

All-in-one boiler water treatment composition

Algae growth in an open water system such as a water cooling tower is controlled by reducing the amount of light available for the algae to photosynthesize. The light available for photosynthesis is reduced by incorporating a dye into the water in the water cooling system. Thus the dye absorbs the light necessary for photosynthesis and in turn prevents algae growth. Preferably fluorescein at a concentration of 0.2 to 800 parts per million is incorporated into the water in the water cooling system. Other dyes can be selected depending on the particular algae.

Chemical treatment for algae control in open water systems

An all-in-one treatment composition for a water cooling tower includes a water soluble aromatic azole corrosion inhibitor such as benzotriazole, an organophosphorous antiscalant and a polymeric quaternary ammonium compound. The polymeric quaternary ammonium compound has the following general formula: ##STR1## The composition is suitable for use at low level continuous applications rates. The polymeric quaternary ammonium compound is also suitable for use at low concentration as a continuous biocide/biostat. This compound does not suffer from the acclimatization typically encountered when one biocide is used on a continuous low level basis.

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Montgomery, OH, United States of America

Ronald J Christensen