Akzo N.v.

Akzona Incorporated

Ronald E Hutton

Joseph W Burley

Vincent Oakes

Dieter Frank

William J Parr

Paul Y Moy

Cornelis J Groenenboom

Willem G Huysmans

Brian Rodney Iles

Michael R Jolley

David Frederic Cross

Conductive metal-filled composites via developing agents

Organotin compounds having the formula R.sub.3 SnX or R.sub.4 Sn are prepared by reacting metallic zinc with organotin compounds having the formula RSnX.sub.3 or R.sub.2 SnX.sub.2, wherein X stands for chlorine, bromine, iodine or an alkyl carboxylate group having the formula C.sub.p H.sub.2p+l COO, wherein p=1-18, and R represents an organic group. Satisfactory yields are obtained under mild reaction conditions and without any catalyst being needed if both in the reacting organotin compounds and in the organotin compounds obtained the group R has the structure ##STR1## with A being selected from the group consisting of alkyl having 1-18 carbon atoms, O-alkyl having 1-18 carbon atoms and optionally carrying an alkoxy group having 1-18 carbon atoms, polyoxyalkylene consisting of oxyalkylene groups having 1-4 carbon atoms and carrying as terminal group alkyl or a hydrogen atom, O-cycloalkyl, O-alkenyl having 2-4 carbon atoms, O-phenyl, NH.sub.2 and alkyl substituted amino, and Cl.

Process for the preparation of organotin compounds

A stabilizer composition for a polymer is described, said composition comprising a chemically combined structure of the formula ##STR1## wherein R is a group having the formula ##STR2## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently a hydrogen atom, or an alkyl or substituted alkyl group having 1 to 18 carbon atoms, with the proviso that at least one of R.sup.1 and R.sup.2 contains adjacent to the group HC- a carbonyl group which forms a part of an acid group, ester group, acid halide group, ketone group or aldehyde group; and X is --S(CH.sub.2).sub.y --COOR.sup.5 or --S(CH.sub.2).sub.y --OCOR.sup.5, wherein y is 1 or 2, or --SR.sup.5, --OCOR.sup.5 or --OCOCH.dbd.CHCOOR.sup.5, R.sup.5 being an alkyl or substituted alkyl group having 1 to 18 carbon atoms.

Novel organotin stabilizer compositions

A stabilizer composition for polyvinyl polymers contains

Novel organotin stabilizer compositions and polyvinyl resins stabilized

An organotin dihalide having the formula ##STR1## OR A MIXTURE OF THE DIHALIDE AND AN ORGANOTIN TRIHALIDE IS PREPARED BY REACTING METALLIC TIN WITH AN OLEFIN HAVING THE FORMULA ##STR2## wherein R.sub.1, R.sub.2, and R.sub.4 are hydrogen or a hydrocarbon radical and at least one of R.sub.1 or R.sub.2 contains an oxygen-containing group with a carbonyl group adjacent to the olefinic double bond and Hal is a halogen. The organotin dihalide or mixture thereof with a trihalide is reacted with an acid or mercaptan to produce a stabilizer for polyvinyl chloride polymers and the like.

Process for making organotin dihalides and trihalides

Organotin trihalides are prepared by reacting in a polar solvent a stannous halide, hydrogen halide and an olefin of the formula ##STR1## where R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are an alkyl group, an oxygen-containing hydrocarbon group or a hydrogen atom and at least one of the groups contains a carbonyl group adjacent to the carbon-carbon double bond. The resulting product may be converted into organotin stabilizers for polyvinyl chloride and other polymers.

Process for the preparation of organotin trihalides

A hydrolytically stable composition contains as its essential components at least about 85% by weight of an organic triphosphite and from about 0.1% to 5% by weight of a salt of a metal from Group I or Group II of the Periodic System and an organic acid having at least 8 carbon atoms. An organic triphosphite can be stabilized against hydrolytic degradation in accordance with the invention by mixing from about 0.1% to 5% by weight of the said salt therewith.

Organic triphosphites having improved hydrolytic stability and a process

Organotin stabilizers

An organotin dihalide having the formula ##STR1## OR A MIXTURE OF THE DIHALIDE AND AN ORGANOTIN TRIHALIDE IS PREPARED BY REACTING METALLIC TIN WITH AN OLEFIN HAVING THE FORMULA ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen or a hydrocarbon radical and at least one of R.sub.1 or R.sub.2 contains an oxygen-containing group with a carbonyl group adjacent to the olefinic double bond and Hal is a halogen. The organotin dihalide or mixture thereof with a trihalide is reacted with an acid or mercaptan to produce a stabilizer for polyvinyl chloride polymers and the like.

Process for making organotin dihalides and trihalides and stabilizers

Improved heat stability of halogen containing polymers is obtained by applying as stabilizer a synergistic mixture of

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Southport, United Kingdom

Ronald E Hutton