Range Fuels, Inc.

Albemarle Corporation

Other

Ronald C Stites

Karl C Kharas

Shakeel H Tirmizi

Jerrod Wayne Hohman

Robert E Klepper

Francis Michael Ferraro

Arie Geertsema

Otto John Schneider

Richard Ridley

Heinz Juergen Robota

Kevin T Biehle

Stephen Deutch

Optimized, heat-integrated methods and systems are provided to produce multiple, high-value products from oil shale, while minimizing overall energy and water usage. A method for producing multiple products from oil shale comprises: feeding raw oil shale into a heated retorting unit, to convert kerogen into a retorted stream; introducing the retorted stream to a distillation column to generate a high-cetane diesel stream, an &#x3b1;-olefin-containing chemical stream, an asphalt/asphalt additive stream, and an overhead gas stream, wherein heat contained in the retorted stream is harnessed as distillation energy; separating the overhead gas stream into a fuel gas stream and a purge gas stream; combusting the fuel gas stream to generate hot flue gas; heating the purge gas with hot flue gas; feeding the heated purge gas directly to the heated retorting unit; and recovering the high-cetane diesel stream, the &#x3b1;-olefin-containing chemical stream, and the asphalt/asphalt additive stream as products.

Methods and systems for retorting oil shale and upgrading the hydrocarbons obtained therefrom

Improved methods of introducing promoters to catalysts are described. The present invention provides a convenient method of uniformly distributing a catalyst promoter, to provide for intimate contact between the promoter and the active catalyst sites. This intimate contact can enhance the activity and/or product selectivity of the promoted catalyst. In some embodiments, the method includes reacting an alkali metal with an alcohol in a non-aqueous medium, contacting the resulting solution with a starting catalyst, and depositing the alkali metal onto the starting catalyst to form an alkali-promoted catalyst.

Methods for promoting syngas-to-alcohol catalysis

The present invention provides processes for selectively producing ethanol from syngas. In some variations, the process comprises converting biomass-derived syngas to dimethyl ether, carbonylating the dimethyl ether to methyl acetate, hydrogenating the methyl acetate to methanol and ethanol, and recovering the ethanol product. The methanol is preferably recycled by converting to hydrogen and carbon monoxide for introduction back into the process at distinct points. In certain variations of this invention, fresh syngas feed is introduced downstream of the first unit operation in the sequence. High yields of ethanol from biomass can be achieved according to the disclosed processes.

Selective process for conversion of syngas to ethanol

This invention features methods and apparatus for producing syngas from any carbon-containing feed material. In some embodiments, a substoichiometric amount of oxygen is used to enhance the formation of syngas. In various embodiments, both oxygen and steam are added during the conversion of the feed material into syngas. The syngas can be converted to alcohols, such as ethanol, or to other products.

Methods and apparatus for producing syngas and alcohols

The present invention provides improved methods and apparatus for producing syngas from any carbon-containing feed material. In one aspect, a multi-zone reformer system is provided. A first reaction zone can reduce the presence of refractory tars, while a second reaction zone in communication with the first reaction zone can steam-reform methane and other components from the first reaction zone, to generate high-quality syngas suitable for conversion to liquid fuels, such as ethanol. Other embodiments employ a plurality of reaction zones for added system functionality.

Multi-zone reforming methods and apparatus for conversion of devolatilized biomass to syngas

The invention provides methods and apparatus for selectively producing ethanol from syngas. As disclosed herein, syngas derived from cellulosic biomass (or other sources) can be catalytically converted into methanol, which in turn can be catalytically converted into acetic acid or acetates. Finally, the acetic acid or acetates can be reduced to ethanol according to several variations. In some embodiments, yields of ethanol from biomass can exceed 100 gallons per dry ton of biomass.

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Brighton, CO, United States of America

Ronald C Stites