Air Products and Chemicals, Inc.

Royce Associates

Ronald C Naddeo

Vincent L Magnotta

Konstantinos Hristofas

John Frederick Cirucci

Varin Ayala

Virgil G Fox, Jr

Process for bleaching pulp or paper

A method for white liquor oxidation in a kraft mill utilizes a two-stage selective oxidation system in which the first stage is operated to remove sulfide while the second stage is operated to oxidize a significant fraction of the remaining oxidizable sulfur compounds to sulfate. The resulting selectively oxidized white liquor products are used as alkali sources for various process steps in the mill. Optionally, white liquor can be oxidized in a single stage to convert a significant fraction of the oxidizable sulfur compounds to sulfate. Methods for controlling the selective oxidation process are disclosed.

Selective white liquor oxidation

A method is disclosed for the detackification of stickies in the production of recycled paper products containing secondary fibers. Oxygen is used to reduce the tackiness of stickies in secondary pulps, and optionally is used with alkali and/or detackification agents for optimum stickies control.

Oxygen detackification in secondary fiber recovery

Color is removed from secondary pulps with non-chlorine based bleaching agents in treating sequences using oxygen with combinations of peroxide, ozone, and/or hydrosulfite at/controlled pH conditions. Acid treatment prior to bleaching steps improves color removal and protects fibers from damage at more severe bleaching conditions.

Dye stripping by oxygen in secondary fiber recovery

Dye stripping by oxygen and peroxide in secondary fiber recovery

Secondary pulp is deinked and bleached by contacting the pulp simultaneously with oxygen, alkali, and a surfactant in a reaction zone followed by washing to recover a secondary fiber product. Simultaneous contacting with oxygen and surfactant yields higher pulp brightness than sequential contacting in oxygen bleaching and washing stages, and enhances bleachability in further bleaching stages.

Cleaning and bleaching of secondary fiber

A method is disclosed for the detackification of stickies in the production of recycled paper products containing secondary fibers. Oxygen is used to reduce the tackiness of stickies in secondary pulps, and optionally is used with alkali and/or detackification agents for optimum stickies control. The preferred alkali source is fully oxidized white liquor.

Oxygen alkali detackification in secondary fiber recovery

Color from dyes is removed from secondary pulps with non-chlorine based bleaching agents in treating sequences using oxygen with combinations of peroxide, ozone, and/or hydrosulfite at controlled pH conditions (less than 8 or greater than 10). Acid treatment prior to bleaching steps improves color removal and protects fibers from damage at more severe bleaching conditions.

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Kempton, PA, United States of America

Ronald C Naddeo