Eastman Chemical Company

Grupo Petrotemex S.a. De C.v.

Ronald Buford Sheppard

Alan George Wonders

Raymond Elbert Fogle, Iii

Thomas Earl Woodruff

Timothy Alan Upshaw

Kenny Randolph Parker

Philip Edward Gibson

Brent Alan Tennant

Martin De Boer

Robert Lin

Iii Fogle Raymond Elbert

Wayne Scott Strasser

Charles Edwan Sumner, Jr

Ruairi Seosamh O'Meadhra

Lee R Partin

Marcel De Vreede

Nick Allen Collins

Steven Anthony Wilson

William Lewis Trapp

Brian Douglas Seiler

S M Bedarul Islam

Lee Reynolds Partin

Charles Edwan Sumner

Brent Alain Tennant

Raymond Elbert Iii Fogle

A process for preparing a recycle cellulose ester and a recycle cellulose ester composition and articles made with such recycle cellulose esters comprising at least one cellulose ester having at least one substituent on an anhydroglucose unit (AU) derived from recycled plastic content syngas are provided. The recycled plastic content syngas can be obtained by gasifying feedstocks containing a solid fossil fuel such as coal, a plastic, and water. The plastic can be post-consumer or postindustrial plastic.

Cellulose ester compositions derived from recycled plastic content syngas

A fiber delivery system capable of providing cut fiber segments for use in treating an oil and/or gas well. The fiber delivery system can utilize bales of a continuous filamentary tow that are transported to the well site from a remote manufacturing location. At the well site, a multifilament strand can be pulled off the bale, opened, and cut to provide cut fiber segments. The cut fiber segments can be mixed with other well treatment components to create a well treatment medium that is introduced into the well as part of a drilling, stimulation, or cementing process.

Well treatment fiber delivery system

The invention provides improved energy content in and shaft power recovery from off-gas from xylene oxidation reactions while at the same time minimizing wastewater treatment cost. More shaft power is produced using off-gas than is required to drive the main air compressor, even with preferred, relatively low oxidation temperatures. Simultaneously, an amount of wastewater greater than byproduct water from oxidation of xylene is kept in vapor form and treated along with off-gas pollutants in a self-sustaining (self-fueling) gas-phase thermal oxidative destruction unit. Optionally, off-gas is combined from multiple xylene oxidation reactors, comprising primary and/or secondary oxidation reactors and forming TPA and/or IPA. Optionally, air compressor condensate and caustic scrubber blowdown are used in a TPA process or as utility water, effectively eliminating normal flow of liquid wastewater effluent from a TPA plant. Optionally, PET off-gas containing the water of PET formation is treated in a shared thermal oxidative destruction unit, effectively eliminating normal flow of liquid wastewater effluent from a combined pX-to-TPA-to-PET plant.

Dicarboxylic acid production with self-fuel oxidative destruction

Dicarboxylic acid production with direct fired off-gas heating

Dicarboxylic acid production with enhanced energy recovery

Dicarboxylic acid production with minimal wastewater generation

The invention provides improved energy content in and shaft power recovery from off-gas from xylene oxidation reactions while at the same time minimizing wastewater treatment cost. More shaft power is produced using off-gas than is required to drive the main air compressor, even with preferred, relatively low oxidation temperatures. Simultaneously, an amount of wastewater greater than byproduct water from oxidation of xylene is kept in vapor form and treated along with off-gas pollutants in a self-sustaining (self-fueling) gas-phase thermal oxidative destruction unit. Optionally, off-gas is combined from multiple xylene oxidation reactors, comprising primary and/or secondary oxidation reactors and forming TPA and/or IPA.

Integrated co-production of dicarboxylic acids

A process is provided for producing an enriched carboxylic acid compositions produced by contacting composition comprising a carboxylic acid with an enrichment feed in an enrichment zone to form an enriched carboxylic acid composition. This invention also relates to a process and the resulting compositions for removing catalyst from a carboxylic acid composition to produce a post catalyst removal composition.

Enriched terephthalic acid composition

Disclosed is an optimized system for more efficiently and economically producing terephthalic acid. The system includes a multi-stage oxidative digestion system for processing an improved initial slurry from primary oxidation. The multi-stage digestion system is capable of adequately purifying the improved initial slurry without requiring significant liquor exchange between primary oxidation and oxidative digestion.

Polycarboxylic acid production system employing enhanced multistage oxidative digestion

Disclosed is an optimized system for more efficiently and economically producing terephthalic acid. The system employs an evaporative removal step downstream of oxidative digestion. The evaporative removal step removes a portion of the liquid phase and promotes precipitation of certain aromatic impurities. By promoting precipitation of certain aromatic impurities, the amount of the precipitated impurities in the recycled solvent is advantageously reduced.

Polycarboxylic acid production system employing enhanced evaporative concentration downstream of oxidative digestion

Disclosed are modified PET polymer compositions and process for making modified PET polymer compositions by reacting purified terephthalic acid and non-hydrogenated isophthalic acid with ethylene glycol. Compositions with acceptable visual appearance, such as clarity and color, can be made at typical modification levels for many packaging application. Disclosed are also shaped articles and the process for making shaped articles of the modified PET polymer composition.

Simplified isophthalic acid process for modifying PET

This invention relates to a process for the manufacture of aromatic carboxylic acids by exothermic liquid phase oxidation of an aromatic feedstock. More particularly, this invention relates to the efficient energy recovery of the exotherm produced by the liquid phase oxidation of an aromatic feedstock. Also, this invention relates to the efficient energy recovery of the exotherm produced by the liquid phase oxidation of an aromatic feedstock while also utilizing the heat from the energy of oxidation to efficiently remove water resulting from the exothermic oxidation reaction.

Process for energy recovery and water removal in the preparation of aromatic carboxylic acids

Disclosed is an optimized system for more efficiently and economically producing terephthalic acid. The system minimizes or eliminates the need for liquor exchange upstream of oxidative digestion and/or upstream of substantial cooling of the TPA-containing slurry.

Polycarboxylic acid production system employing oxidative digestion with reduced or eliminated upstream liquor exchange

Growing community of inventors

Kingsport, TN, United States of America

Ronald Buford Sheppard