Ethyl Petroleum Additives, Inc.

Ethyl Corporation

Rolfe J Hartley

Andrew G Papay

Hiroko Ohtani

Douglas R Chrisope

Sanjay Srinivasan

Joe Leonard Hughes

Vasudevan Balasubramaniam

Donald R Bell

Gregory S Conary

The concentrates comprise specified proportions of diluent oil, an organic sulfur-containing antiwear and/or extreme pressure agent, an ashless dispersant, a dimethyl ester of an aliphatic phosphonic acid in which the aliphatic group has an average in the range of about 12 to about 24 carbon atoms, and a 3-hydrocarbyl-2,5-diketopyrrolidine in which the hydrocarbyl group is an alkyl or alkenyl group having an average in the range of about 12 to about 30 carbon atoms. By using weight ratios of diketopyrrolidine to the dimethyl phosphonate of at least 3:1, the concentrate remains homogeneous at temperatures at least as low as 12.degree. C. When utilized as a top treat in gear oils formulated with conventional GL-4 and GL-5 gear additive packages substantial improvements in limited slip axle performance can be realized.

Gear oil additive concentrates and lubricants containing them

Oleaginous compositions and additive concentrates therefor having enhanced performance characteristics comprise a) at least one oil-soluble overbased alkali or alkaline earth metal-containing detergent having a TBN of at least 200; and b) one or more oil-soluble boron-free additive compositions formed by heating (i) at least one boron-free oil-soluble ashless dispersant containing basic nitrogen and/or at least one hydroxyl group, with (ii) at least one inorganic phosphorus acid such that a liquid boron-free phosphorus-containing composition is formed.

Lubricating oil compositions and concentrates and the use thereof

Multifunctional additives having a variety of advantageous properties are described. They are formed by a process which comprises heating concurrently or in any sequence a) an oil-soluble ashless dispersant containing basic nitrogen with b) an alkoxylated alcohol of at least 8 carbon atoms c) a borating agent and optionally d) an inorganic oxyacid or anhydride of phosphorous. The reactants are in proportions on an active ingredient basis of about 0.03 to about 0.35 part by weight of b) per part by weight of a), and about 0.005 to about 0.06 part by weight of boron as c) per part by weight of a). The reaction temperature can range from about 50.degree. to about 150.degree. C. Water and/or solids present in the resultant mixture can be removed. Preferably, the optional phosphorous component is used in the formation of these additives. This phosphorous component can be an inorganic oxyacid or anhydride of phosphorous.

Lubricant additive compositions

Additives are produced by (i) reacting an O,O-dihydrocarbyl phosphorodithioic acid with a monoepoxide or mixture of monoepoxides having in the range of 20 to about 30 carbon atoms in the molecule or a vegetable oil epoxide such as epoxidized soybean oil or methyl epoxy soyate, (ii) reacting the product with phosphorus pentoxide to produce an acid phosphate intermediate, and (iii) neutralizing the intermediate with at least one amine. At least 50 mole %, and preferably all, of the hydrocarbyl groups of the O,O-dihydrocarbyl phosphorodithioic acid are secondary acyclic hydrocarbyl groups free of acetylenic unsaturation. The additives are multifunctional in that they have limited slip properties, antiwear/extreme pressure properties, and corrosion inhibiting properties.

Oil-soluble phosphorus- and nitrogen-containing additives

Gear oil compositions

Additives are produced by (i) reacting an O,O-dihydrocarbyl phosphorodithioic acid with a monoepoxide or mixture of monoepoxides having in the range of 20 to about 30 carbon atoms in the molecule, (ii) reacting the product with phosphorus pentoxide to produce an acid phosphate intermediate, and (iii) neutralizing the intermediate with at least one amine. At least 50 mole % , and preferably all, of the hydrocarbyl groups of the O,O-dihydrocarbyl phosphorodithioic acid are secondary acyclic hydrocarbyl groups free of acetylenic unsaturation. The balance, if any, of such hydrocarbyl groups are primary acyclic hydrocarbyl groups free of acetylenic unsaturation. The additives are multifunctional in that they have limited slip properties, antiwear/extreme pressure properties, and corrosion inhibiting properties.

An effective way is described for overcoming the shudder problem associated with continuous slip torque converter clutches for use in automatic transmissions, especially shudder which occurs with new friction materials before break-in. To do this, an ATF is used in which the friction modifier system consists essentially of (i) an N-aliphatic hydrocarbyl-substituted diethanolamine in which the N-aliphatic hydrocarbyl-substituent is at least one straight chain aliphatic hydrocarbyl group free of acetylenic unsaturation and having in the range of 14 to 20 carbon atoms, and (ii) an N-aliphatic hydrocarbyl-substituted trimethylenediamine in which the N-aliphatic hydrocarbyl-substituent is at least one straight chain aliphatic hydrocarbyl group free of acetylenic unsaturation and having in the range of about 14 to about 20 carbon atoms. The ATF is devoid of any tertiary amine friction modifier component and any C.sub.12-36 aliphatic hydrocarbyl succinimide or succinamide friction modifier. Specified relative proportions and concentrations of (i) to (ii) are used.

Automatic transmission fluids and additives therefor

A lubricant composition especially adapted for use as an automatic transmission fluid, which composition consists essentially of: a) from 50 to 85 weight percent of a mineral oil having a viscosity at 100.degree. C. in the range of 3 to 5 centistokes; b) from 5 to 35 weight percent of a poly-.alpha.-olefin lubricating oil having a viscosity at 100.degree. C. in the range of 1 to 8 centistokes; and c) from 8 to 15 weight percent of a combination of alkenyl succinimide dispersant, viscosity index improver and antioxidant; said composition being further characterized in that it contains less than 7.0 weight percent of viscosity index improver and in that the composition has a Brookfield viscosity at -40.degree. C. of no more than 20,000 cP.

An ashless or low-ash oleaginous liquid composition comprising a major amount of hydrogenated poly-.alpha.-olefin oligomer fluid having a viscosity in the range of about 2 to about 10 cSt at 100.degree. C., and minor amounts of at least the following: A) hydrogenated poly-.alpha.-olefin oligomer fluid having a viscosity in the range of about 40 to about 120 cSt at 100.degree. C.; and B) antiwear/extreme pressure agent selected from phosphorus-containing ashless dispersant, boron-containing ashless dispersant, and phosphorus- and boron-containing ashless dispersant. Compositions of this type can be formed having excellent high and low temperature viscosity characteristics and excellent shear stability. To this end, the preferred compositions are devoid or substantially devoid of conventional polymeric high molecular weight viscosity index improvers.

Ashless or low-ash synthetic base compositions and additives therefor

A 'cold-clash' gear problem associated with vehicular manual transmissions exposed to the cold is overcome by use of a special all-synthetic gear oil composition. The composition is composed of base oil and specified additive components. The base oil is a blend of di-(2-ethylhexyl)sebacate and three hydrogenated poly-.alpha.-olefin oligomers having kinematic viscosities at 100.degree. C. of about 40, about 8 cSt and about 2 cSt in specified proportions. The additive components comprise an organic sulfur-containing antiwear and/or extreme pressure agent, an organic phosphorus-containing antiwear and/or extreme pressure agent, a copper corrosion inhibitor, a rust inhibitor, a foam inhibitor, and an ashless dispersant. The gear oil has a boron content of about 0.0025 to about 0.07 wt %.

A new friction modifier system is described. It has the capability of establishing and maintaining a substantially constant static breakaway coefficient of friction between a pair of friction surfaces that are periodically frictionally engaged with each other. Also this system is capable of maintaining a substantially constant ratio between (i) the low speed dynamic coefficient of friction of such friction surfaces, and (ii) the (midpoint) dynamic coefficient of friction of such friction surfaces. The additive composition yielding these results comprises at least the following components: a) a hydroxyalkyl aliphatic imidazoline in which the hydroxyalkyl group contains from 2 to about 4 carbon atoms, and in which the aliphatic group is an acyclic hydrocarbyl group containing from about 10 to about 25 carbon atoms; and b) a di(hydroxyalkyl) aliphatic tertiary amine in which the hydroxyalkyl groups, being the same or different, each contain from 2 to about 4 carbon atoms, and in which the aliphatic group is an acyclic hydrocarbyl group containing from about 10 to about 25 carbon atoms.

Friction modifier compositions and their use

An ashless or low-ash oleaginous liquid composition comprising a major amount of hydrogenated poly-.alpha.-olefin oligomer fluid having a viscosity in the range of about 2 to about 10 cSt at 100.degree.C., and minor amounts of at least the following: A) hydrogenated poly-.alpha.-olefin oligomer fluid having a viscosity in the range of about 40 to about 120 cSt at 100.degree.C.; and B) antiwear/extreme pressure agent selected from phosphorus-containing ashless dispersant, boron-containing ashless dispersant, and phosphorus- and boron-containing ashless dispersant. Compositions of this type can be formed having excellent high and low temperature viscosity characteristics and excellent shear stability. To this end, the preferred compositions are devoid or substantially devoid of conventional polymeric high molecular weight viscosity index improvers.

Oil-soluble reaction products of inorganic phosphorus containing acids or anhydrides with a boron compound and ashless dispersants such as alkenyl succinimides are useful as antiwear/EP additives in lubricants.

Growing community of inventors

St. Louis, MO, United States of America

Rolfe J Hartley