Krupp Koppers Gmbh

Rolf Wetzel

Bernhard Firnhaber

Adolf Linke

Karl Schmid

Hubert Coenen

Gerhard Wilmer

Werner Pohl

Wolfgang Schulte

Cort Starck

Hans-Werner Gosch

Richard Wenderoth

Winfried Kreuch

In the process for gasification of municipal waste plastic waste material pieces of about a 20 mm piece size are compressed and heated at a pressure of from 40 to 80 bar until at a temperature of from 230.degree. to 300.degree. C. to produce an HCl-containing gas and a plastic waste material containing less than 3000 mg of HCl per kg and the HCl-containing gas produced is washed with water to produce a hydrochloric acid solution. The plastic waste material is then heated further until at a temperature of from 400.degree. to 500.degree. C. to form a plastic melt having a viscosity of less than 300 cSt, advantageously less than 50 cSt. This plastic melt is gasified at a pressure of 4 bar with oxygen in a flame reaction to form a crude gas containing a preponderant proportion of CO in relation to CO.sub.2 in a gasification chamber having a central temperature of about 1600.degree. C. The crude gas is withdrawn from the gasification reactor at a temperature of 1300.degree. to 1600.degree. C., quenched with a water spray to cool it until at a temperature of 700.degree. to 900.degree. C. and then further cooled by indirect heat transfer in a heat exchanger producing steam until at a temperature of from 220.degree. to 300.degree. C. The cooled crude gas is dedusted until a dust content of less than 20 mg/Nm.sup.3 of crude gas is reached and the dedusted gas is washed and desulfurized to form the product gas.

Process for working up municipal plastic waste materials by gasification

A gas with a hydrogen content of at least 85 volume percent of partial oxidation crude gas is produced in a method including cooling of the gas after waste heat boiler of a gasifier by adding converted circulating gas in a quenching zone. The resulting gas mixture after corresponding gas treatment is subjected to a CO-conversion and then separated into a circulating gas partial stream and a product gas partial stream. The circulating gas partial stream is supplied back after a corresponding compression to the quenching zone, while the product gas partial stream after a so-called acid gas washing is subjected to a further gas treatment in correspondence with a desired use.

Method of producing hydrogen-rich gas

In accordance with a method of producing of methanol synthesis gas from a partial oxidation crude gas, the gas is cooled after a waste heat boiler of a gasifier by adding a converted circulating gas in a quenching zone. The resulting gas mixture is dedusted and then separated into a product gas partial stream and a circulating gas partial stream. The product gas partial stream is supplied after corresponding gas treatment to the synthesis reactor while the circulating gas partial stream is subjected to a CO-conversion and supplied back to the quenching zone.

Method of producing methanol synthesis gas

The process removes acid components including sulfur oxides and nitrogen oxides from the exhaust gases of industrial furnaces and includes oxidizing the nitrogen oxide contained in the exhaust gases with the oxygen contained in the exhaust gases at a exhaust gases temperature between 300.degree. and 900.degree. C. before entry of the gases into a first absorption stage, with an addition to the exhaust gases of an organic compound, preferably methanol, as a radical former. After oxidation of nitrogen oxides the exhaust gases undergo a two-stage absorption using aqueous ammonium salt solutions as absorption liquid, whose pH-value is continuously adjusted to less than 5 by addition of aqueous ammonia solution. The mol ratio of NO.sub.2 to SO.sub.2 in the exhaust gases introduced to the second absorption stage is maintained between 0.01 and 0.5 by diverting a portion of the exhaust gases prior to the first absorption stage to the second absorption stage. The salt solutions obtained thereby are neutralized together and evaporated, whereby the salts so produced, after pelletization or granulation represent a useful fertilizer.

Process for the removal of acid components and nitrogen oxides from the

Decribed is a method of cooling partial oxidation gas exiting at a temperature between 1,000.degree. and 1,700.degree. C. from a conically converging outlet portion of a reactor vessel into a subsequent tubular cooling zone. To prevent deposition of sticky molten impurities entrained in the gas stream on the walls in the transition region between the reactor vessel and the cooling zone, the outlet portion of the reactor vessel is provided with a ring-shaped slot for injecting at an angle between 0.degree. to 90.degree. a frustoconical stream of cooling fluid. Another ring-shaped slot is provided in the cooling zone to inject at an angle between 70.degree. to 90.degree. another frustoconical stream of cooling fluid into the cooling zone.

Method of cooling partial oxidation gas

A process is disclosed for the working up of salvage oil, in which the salvage oil is subjected to an extraction under supercritical conditions. The halogen compounds contained in the produced extract are removed by catalytic hydrogenation. The extraction residue is eliminated by deposition or thermal treatment (gasification). In the case of a thermal treatment of the extraction residue, other residues can be simultaneously converted, so that the process is performed without yield of environmentally burdensome residues or by-products. Ethane in particular and/or propane is employed as solvent for the supercritical extraction.

Process for the working up of salvage oil

In a method of treating waste water obtained in a direct washing with water of raw gas in a plant for a gasification of gas, the waste water is first settled in a settling tank and a resultant concentrated slime-containing water is subjected to a multi-stage oxidation with air or oxygen only at the temperatures of between 20.degree. C., and 80.degree. C., and the slime-containing water obtained after the oxidation is conveyed to a filtration system or a slime-depositing container.

Method of treatment of waste water obtained in a gasification plant

A blast furnace process and plant are provided employing a gas mixture comprising coke oven gas and gasified fine grained to dusty fuels. The mixture is produced in a mixing chamber wherein the raw gas from the gasifier is chilled with purified cool coke oven gas. The gas mixture is separated from dust and desulfurized in a cyclone charged with burn lime dust. Then the gas mixture is fed to the blast furnace proper and enters at temperatures from about 750.degree. C. to 1000.degree. C.

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Heiligenhaus, Germany

Rolf Wetzel