Bayer Aktiengesellschaft

Bergwerksverband Gmbh

Rolf Kubens

Frank Meyer

Heinrich Heine

Martin Winkelmann

Karl-Erwin Piejko

Hans-Eberhard Braese

Frank Gerald Kleiner

Herbert Gebauer

Hans E Mehesch

Otto Billinger

Christian Lindner

Karl-Heinz Ott

Joachim Wank

Eckart Reese

Wolfgang Cornely

Lothar Meier

Jurgen Heuser

Karola Brudermanns

Hans-Dieter Jakob

Fritz Ehrhard

A film-forming composition comprises from 0.1-8% by weight of an oligomeric polyglycidyl ether or ester and a polymer mixture of

Polymer mixtures of alkylmethacrylate-grafted alkylacrylate rubber with

This invention relates to flexible, soft polymer mixtures which are suitable for the production of sheets with a leather-like appearance and can be worked up by calendering and deep drawing and to a process for their preparation.

Flexible polymer mixtures

Fogging of plastics containing polymer plasticizers is reduced by treating the polymer plasticizers with water vapor in the melt.

Process for reducing fogging due to plasticizers in plastics

This invention relates to a mixture of from 60 to 95% by weight of a diglycidyl ester of hexahydrophthalic acids and from 5 to 40% by weight of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate. In combination with conventional polycarboxylic acid anhydrides as hardeners, this mixture is used for the production of molded bodies with excellent weathering resistance, good electrical properties and surprisingly good mechanical properties.

Mixtures of special cycloaliphatic 1,2-diepoxides and their use

Mixtures of (A) from 50 to 90% by weight of aromatic polycarbonate and (B) from 10 to 50% by weight of polybutylene terephthalate, the percent by weight being based on the total of (A) and (B) are used to produce novel films.

Polycarbonate/polybutylene terephthalate film

For consolidation of geological formations and artificial beds of rock, earth, and coal by means of foaming and hardening polyisocyanate/polyol blends, diols with secondary hydroxyl functions of the OH number range 150-1000 are used as diol component. Preferably a crude polyisocyanate blend (MDI) obtained by phosgenation of aniline/formaldehyde condensates which at ambient temperature assumes a liquid state, and the liquid prepolymers of said crude MDI are used as isocyanate components.

Process for consolidation and sealing of geological formations and

Waterglass solutions are mixed with polyisocyanates and these emulsions are then left to harden in the formations. Introduction of the mixture into the formations which are required to be consolidated, e.g. deposits of coal, is mainly carried out by forcing the mixture under pressure into bore-holes in the formations. According to one variation of the process, the components of the mixture are introduced into the multi-chamber cartridges which are introduced into the bore-holes and then destroyed as the components are mixed. Certain additives such as accelerators, blowing agents, polyols, stabilizers and/or thixotropic agents are advantageous for the quality of the composite masses formed by hardening of the mixture.

Process for consolidating and sealing off geological and artificially

The present invention relates to a two-compartment cartridge which is suitable for securing stay bars in bore holes by means of polyurethane resins and which is destructible by the stay bar, containing a polyisocyanate component on the one hand and a polyol component on the other hand, distinguished by the fact that the polyisocyanate component used is an aromatic polyisocyanate or a mixture of aromatic polyisocyanates, while the polyol component used is a polyol containing tertiary amine nitrogen and having a molecular weight of from about 119 to 3000 or a polyol mixture containing at least one such polyol. The present invention also relates to a process for securing stay bars in bore holes by introducing into the bore hole a two-compartment cartridge which contains components capable of forming a synthetic resin and which is destructible by driving in the stay bar and subsequently driving in the stay bar, distinguished by the fact that a cartridge of the type described above is used as the two-compartment cartridge.

Cartridge for securing stay bars in bore holes containing a

The instant invention is directed to a process for the solvent-free production of solid polyurethane moldings wherein the polyisocyanate used is a polyisocyanate mixture containing from 10 to 80% by weight of 2,4'-diisocyanatodiphenylmethane.

Process for the solvent-free production of solid plastic moldings

The instant invention is directed to a process for the production of heat-resistant synthetic resins containing isocyanurate groups by the polymerization of organic polyisocyanates in the presence of catalysts which accelerate the trimerization of isocyanate groups, wherein said polyisocyanate component is a mixture of isomers and/or homologs of polyisocyanates of the diphenylmethane series containing more than 20%, by weight, of 2,4'-diisocyanatodiphenylmethane.

Process for the production of synthetic resins containing isocyanurate

Hardenable mixtures of A. 40 to 90% by weight of at least one aromatic polyfunctional cyanic acid ester, B. 10 to 60% by weight of at least one polymerizable olefinically unsaturated monomer and, optionally, C. 0.01 to 10% by weight, based on the sum of A) and B) of at least one hardening catalyst such as amines, Mannich bases and organic metal compounds. They are suitable for use as casting resins and as pourable sealing compounds for covering materials, for producing shaped articles, coatings, bonds, electrical insulations, as binders for fibre-reinforced plastics.

Hardenable mixtures containing polyfunctional aromatic cyanic acid esters

This invention concerns a method of consolidating geological formations, heaped rock and earth masses by applying a polyurethane reaction system to the material to be consolidated. The reaction system comprises a polyisocyanate component and a polyol component wherein the polyol component contains about 5 to 50 wt.% of a special polyether with an OH number under about 100. This polyether is produced by the reaction of a compound having more than one reactive hydrogen atom per molecule and a molecular excess of a 1,2-alkylene oxide. The reaction system can also contain conventional polyurethane additives such as foaming agents, fillers, foam stabilizers and catalysts. In a preferred embodiment, the special polyether is produced from ethylene diamine or triethanol amine.

Process for the consolidation of geological formations and loosened rock

The present invention relates to a process for the reinforcement of geological formations and loose rock and earth masses by introducing, into the cavities of the geological formations or rock or earth masses which are required to be reinforced, reaction mixtures based on organic polyhydroxyl compounds and organic polyisocyanates which react to form polyurethanes, which process is characterized in that the polyisocyanate component used is a polyisocyanate mixture containing from about 10 to 80%, by weight, of 2,4'-diisocyanato-diphenylmethane. The present invention also relates to a two-chamber cartridge suitable for carrying out the process according to the present invention. This cartridge comprises two chambers separated from each other, one containing a polyisocyanate component and the second chamber containing a polyol component, the quantitative proportions of the two components being calculated so that when the cartridge is destroyed, a reaction mixture which reacts to yield a polyurethane is obtained, characterized in that the polyisocyanate component used is a polyisocyanate mixture containing from about 10 to 80%, by weight, of 2,4'-isocyanato -diphenylmethane.

Process for reinforcing geological formations

The instant invention relates to a process for the production of crosslinked plastics comprising reacting organic polyisocyanates, organic polyhydroxyl compounds and olefinically unsaturated monomers, optionally in the presence of catalysts and/or other auxiliaries and additives, wherein

Process for the production of crosslinked, urethane-containing plastics

Foundry cores and molds are produced from foundry sand and/or other inert fillers, polyhydroxyl compounds, polyisocyanates and tertiary amine catalysts. The precatalyzed mixtures can be stored for long periods of time without any adverse effects on the subsequent processing or core properties when at least 80% by weight of the polyisocyanate used is of the diphenyl alkane series in which the isocyanate groups are sterically hindered solely by substituents in at least one ortho position.

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Odenthal, Germany

Rolf Kubens