Hoechst Aktiengesellschaft

Cassella Aktiengesellschaft

Rolf Kleber

Lothar Jaeckel

Ulrich Cuntze

Gustav Dollinger

Frank Wehowsky

Siegfried Billenstein

Hans-Jerg Kleiner

Friedrich Engelhardt

Karl Hintermeier

Winfried Ehrl

Peter Klein

Willi Steckelberg

Rainer Kupfer

Bernhard Mees

Frank Weinelt

Wolfgang Knaup

Herbert Stuhler

Walter Fester

Ignaz Wimmer

Heinz Muller

Werner Lotz

Manfred Muller

Heinrich Bathelt

Wolfgang Wagemann

Hans Ludwig Panke

Erich Hoffmann

Reinhart Mayer

Hubert Herdt

Jan-Hilbert Mast

Sigurd Wetzel

Dieter Plabst

Fritz-Joachim Gohlke

Lothar Jackel

Wolfgang Glenz

Surfactant mixture for textile treatment

The invention relates to spin finishes comprising compounds of the formula ##STR1## in which R.sub.1 is a straight-chain or branched alkyl radical of the empirical formula C.sub.n H.sub.2n+1 or a straight-chain or branched alkenyl radical of the empirical formula C.sub.n H.sub.2n-1 where n is in each case 1 to 9 and R.sub.2 is a straight-chain or branched alkyl radical of the empirical formula C.sub.n H.sub.2n+1 where n is 2 to 16, and also to their use as spooling oils for synthetic fibers.

Biodegradable spin finishes

The invention relates to spin finishes which contain compounds of the formula

The urethanes described are synthesized from aliphatic fluoro alcohols, triisocyanate and a carboxylic acid. They are prepared by reaction of the aliphatic fluoro alcohol with the triisocyanate to give the fluoro alcohol/triisocyanate adduct and by reaction of this adduct with the carboxylic acid. The new urethanes are preferably used for the finishing of textiles for the purpose of achieving water, oil and soil repellency.

Urethanes made from aliphatic fluoro alcohols, isocyanates and

Compounds of the formula ##STR1## where R.sub.1 denotes a group of the formula ##STR2## R.sub.2 denotes C.sub.1 -C.sub.4 -alkyl, R.sub.3 denotes hydrogen or methyl, n denotes a number from 5 to 100, m denotes an integer from 0 to 4 and x denotes the number of free valences of the particular R.sub.1 radical, a process for the preparation thereof, and the use thereof as fiber spin finishes.

Poly(alkoxy ether) mixed formals

Urethanes made from aliphatic fluorinated alochols, isocyanates and substituted aromatic compounds, a process for their preparation, and their use. The novel urethanes are synthesized from an aliphatic fluorinated alcohol, an isocyanate and a specific substituted phenol or aniline compound. They are prepared by reacting an aliphatic fluorinated alcohol with a di- or triisocyanate to form a fluorinated alcohol/isocyanate adduct and reacting this adduct with a certain substituted phenol or aniline to form the urethanes intended. The novel urethanes are preferably used for oleophobic and hydrophobic finishing of textiles and leather.

Urethane made from aliphatic fluorinated alcohols, isocyanates and

Amino-containing alkenylsuccinic esters of the formulae ##STR1## where R denotes linear or branched C.sub.1 -C.sub.20 -alkyl, R.sub.1 denotes hydroxy-C.sub.2 -C.sub.6 -alkyl or C.sub.1 -C.sub.4 -alkyl, R.sub.2 denotes methyl or ethyl, R.sub.3 denotes C.sub.6 -C.sub.20 -alkyl, preferably C.sub.12 -C.sub.18 -alkyl, or C.sub.6 -C.sub.20 -alkenyl, preferably C.sub.12 -C.sub.18 -alkenyl, A denotes --C.sub.2 H.sub.4 -- or C.sub.3 H.sub.7 -- and n denotes a number from 1 to 10, preferably from 3 to 8, the preparation thereof and the use thereof as thermostable lubricants in spin finishes.

Amino-containing alkenylsuccinic esters

Novel alkanephosphonic monoester salts, preparation thereof and use thereof as spin finishes for textile fibers Alkylphosphonic monoester salts of the formula ##STR1## where R, if p=1, is alkyl, and, if p=4, a carbon atom, R.sup.1 denotes C.sub.1 -C.sub.4 -alkyl, A denotes C.sub.2 H.sub.4 and/or C.sub.3 H.sub.7, m denotes a number from 15 to 35, R.sup.2 denotes C.sub.6 -C.sub.24 -alkyl, n denotes a number from 0 to 15, and p denotes 1 or 4 . These compounds are suitable for use as spin finishes for textile fibers and are distinguished by very good thermostability.

Novel alkanephosphonic monoester salts, preparation thereof and use

The molecule of the new urethanes contains an aliphatic fluoroalcohol, an isocyanate and an aromatic dihydroxy, diamino, aminohydroxy, aminocarboxy or hydroxycarboxy compound. They are prepared by reacting an aliphatic fluoroalcohol with a diisocyanate or triisocyanate to give the fluoroalcohol/isocyanate adduct and by reacting this adduct with said aromatic compound to give the desired urethanes composed of an aliphatic fluoroalcohol, an isocyanate and the bifunctional aromatic compound mentioned, and also be reacting a urethane of this type which also carries an active hydrogen atom on the bifunctional aromatic compound, with an isocyanate compound containing one or more isocyanate groups. The new urethanes are preferably used for imparting an oleophobic and hydrophobic finish to textiles and leather.

Urethanes composed of aliphatic fluoroalcohols, isocyanates and aromatic

The novel urethanes, in addition to at least one perfluoroalkyl group, also contain epichlorohydrin groups and dialcohol radicals in the molecule. They are prepared by reacting a fluorine-containing alcohol with epichlorohydrin to give the perfluoroalkyl-epichlorohydrin adduct, reacting this adduct with a di- or triisocyanate to give the perfluoroalkyl-epichlorohydrin-isocyanate adduct and by reacting this adduct with a dialcohol or a monoetherified dialcohol to give the desired urethanes having a perfluoroalkyl group and having epichlorohydrin groups and dialcohol radicals, and by reacting a suitable urethane compound of this type with a perfluoroalkyl-containing di- or triisocyanate to give the desired urethanes having a plurality of perfluoroalkyl groups and having epichlorohydrin groups and dialcoholradicals. The novel urethanes are preferably used for the oleophobic and hydrophobic finishing of textiles.

Urethanes which contain perfluoroalkyl groups, epichlorohydrin groups

Water-soluble polycoesters, process for their preparation, and their use

The novel urethanes correspond to the formula I below ##STR1## in which a denotes a number from 5 to 17 and b denotes a number from 1 to 7. These urethanes are prepared by reacting the corresponding perfluoroalkylethanol/epichlorohydrin adducts with toluelene diisocyanates. The novel aqueous dispersions are essentially composed of the novel urethanes, cationic or betaine emulsifiers and non-ionic emulsifiers, water-insoluble carboxylic and/or dicarboxylic acid esters and alkanediols or polyalkanediols which can be etherified on one or both sides, in water. The novel urethanes and the novel aqueous dispersions are used to impart an oleophobic and hydrophobic finish to textiles, leather and furs. They are also suitable for the treatment of unpainted timber, for example unpainted furniture.

Urethanes containing perfluoroalkyl and epichlorohydrin groups

Dressing agents for synthetic fibers, which contain an amine oxide of the formula ##STR1## in which R.sub.1 denotes C.sub.5 -C.sub.22 alkyl or C.sub.5 -C.sub.22 alkenyl, R.sub.2 denotes a group of the formula ##STR2## R.sub.3 denotes C.sub.5 -C.sub.22 alkyl, C.sub.5 -C.sub.22 alkenyl or a group of the formula 2, either X denotes methyl and Y denotes hydrogen or X denotes hydrogen and Y denotes methyl, and n and m denote numbers from 2 to 8, it being necessary that the total of n and m does not exceed 10.

Dressing agents for synthetic fibers and their use

Polyvinyl alcohol modified by reaction with formaldehyde and amidosulfonic acid at a pH value of 4 to 7, which value is established by the addition of an organic amine. This modified polyvinyl alcohol is suitable for use as a sizing agent for yarns.

Modified polyvinyl alcohol and its use as a sizing agent

A sizing agent consisting substantially of polyvinyl alcohol and polyglycerol.

Growing community of inventors

Neu-Isenburg, Germany

Rolf Kleber