E.i. Dupont De Nemours and Company

Hewlett-packard Development Company, L.P.

Rolf Dessauer

Jonathan V Caspar

Graciela Beatriz Blanchet-Fincher

Gregory Charles Weed

Catharine E Looney

William Bindloss, Jr

Curtis R Fincher

Jeffrey Jude Patricia

Richard J Kempf

Alan S Dubin

Randall Orson Willard

Steven C Freilich

James Riesenfeld

Raymond A Firmani

Graciella Blanchet

Lawrence K-f Cheung

Compositions and systems for labeling substrates, such as optical disks, using leuco dye-containing coating compositions are described. The composition can comprise a color forming composition, an electromagnetic radiation absorber, and a stabilizing agent. The color forming composition can include a leuco dye, a hexaarylbiimidazole activator, and an acid-generating source. The absorber can be admixed with or in thermal contact with the color forming composition. The stabilizing agent can be configured for protecting the leuco dye upon exposure to ambient light, wherein the stabilizing agent comprises a diarylguanidine dye salt. The coating composition can be optimized for development using electromagnetic radiation having a frequency from about 760 nm and 800 nm.

Leuco dye-containing coating compositions

A thermally imageable element having a thermally imageable layer, wherein the thermally imageable layer has a thermal amplification additive and a stabilizer selected from the group consisting of phenolic type compounds and amine type compounds. These stabilizers present in thermally imageable layers maintain NIR stability during manufacture, and when the thermally imageable elements containing them are used in thermal imaging processes.

Thermal imaging elements having improved stability

Novel thermally imageable monochrome product compositions, elements, and processes are disclosed herein. These compositions and elements characteristically have high contrast and fast imaging speeds. The thermally imageable compositions of this invention contain at least one polymeric binder, a specified leuco dye and a specified hydroxylamine compound. These compositions have the propensity for affording, upon thermal imaging, highly colored images having high optical density values. At the same time, background color is low in preferred compositions even after extensive exposure to ambient light. These compositions can be imagewise heated to effect color formation (i.e., generation of an image) or, in case of compositions containing at least one near IR-absorbing dye, can be imagewise exposed to near IR radiation from a laser or other device to effect color formation (i.e., generation of an image).

Non-photosensitive, thermally imageable element having improved room light stability

Novel thermally imageable monochrome product compositions, elements, and processes are disclosed herein. These compositions and elements characteristically have high contrast and fast imaging speeds. The thermally imageable compositions of this invention comprise (a) at least one hexaarylbiimidazole (HABI) compound, (b) at least one leuco dye, (c) at least one acid-generating compound, (d) a polymeric binder, (e) optionally at least one UV stabilizer and/or at least one inhibitor of color formation, and, in certain embodiments, (f) at least one near IR-absorbing dye. These compositions have the propensity for affording, upon thermal imaging, highly colored images having high optical density values. At the same time, background color is low in preferred compositions even after extensive exposure to ambient light. These compositions can be imagewise heated to effect color formation (i.e., generation of an image) or, in case of compositions containing at least one near IR-absorbing dye, can be imagewise exposed to near IR radiation from a laser or other device to effect color formation (i.e., generation of an image).

Thermally imageable monochrome digital proofing product with high

High resolution, photosensitive electrostatic master which is positive-working with a single imagewise exposure comprising a conductive support bearing a layer of a photosensitive composition consisting essentially of (A) at least one polymeric binder, (B) a hexaarylbiimidazole photooxidant, (C) leuco dye, preferably stabilized, oxidized by (B), (D) a nonionic halogenated compound, preferably a hydrocarbon, and (E) compatible plasticizer. A process of making positive images by a single imagewise exposure is described. The master is useful in making proofs that duplicate the image achieved by printing, etc.

Photosensitive leuco dye containing electrostatic master with printout

Photohardenable electrostatic master comprising an electrically conductive substrate, e.g., aluminized polyethylene terephthalate, bearing a layer of a photopolymer comprising an organic polymeric binder, compound having at least one ethylenically unsaturated group, photoinitiator, an aromatic amino compound, as defined, and an acid, e.g., p-toluene sulfonic acid, or an oxidized substituted aromatic amino compound. The photohardenable electrostatic master having improved charge decay and backtransfer is used for electrostatic proofing, etc.

Photohardenable electrostatic master having improved backtransfer and

Xeroprinting process involving imagewise exposing a photopolymer master, charging on a conductive support, toning with dry or liquid electrostatic toner, and transferring to another surface. Photopolymer systems comprising preferred combinations of polymeric binders, ethylenically unsaturated monomers. HABI initiators and chain transfer agents.

Xeroprinting with photopolymer master

Photoimaging compositions comprising (A) 2,4,5-triphenylimidazolyl dimer having selected substituents on the 2,4 and 5 phenyl rings and an extinction coefficient determined in methylene chloride at 10.sup.-5 to 10.sup.-3 mol/liter at 350 nm of at least 4000 liters/mol-cm and at 400 nm of at least 250 liters/mol-cm; and at least one of (B1) leuco dye or (B2) addition polymerizable ethylenically unsaturated monomeric compound. The new imaging compositions are useful in preparing dual response photoimaging products such as proofing papers, printout paper, overlay films and photopolymerizable elements. Improved imaging speed is achieved at equal concentration levels when compared with conventional 2,4,5-triphenylimidazolyl dimers.

Dimers derived from unsymmetrical 2,4,5,-triphenylimidazole compounds as

Dimers derived from unsymmetrical 2,4,5-triphenylimidazole compounds as

A photosensitive system comprising in intimate admixture (1) a dye in its leuco form, (2) a photooxidant taken from the group of hexaarylbiimidazole compounds, benzophenone, para-aminophenyl ketones, polynuclear quinones and thioxanthenones, and mixtures thereof and in the presence of the admixture is a 5-member-heterocyclic phenylhydrazide compound. The cyclic phenylhydrazide can be present in the admixture, or a dry coating of the admixture, after imagewise exposure, is treated with a solution of the heterocyclic compound. The system is useful in formation of colored images.

Photoimaging systems with cyclic hydrazides

A marking transfer sheet comprising an imaging layer of pigment, binder and a color-forming, radiation-sensitive component on a carrier film and a process for its use comprising exposing the imaging layer to a pattern of radiation to form a mark, heating the imaging layer until adhesive, and contacting the imaging layer with a support more adherent to the imaging layer than the carrier film; and optionally separating the carrier film from the imaging layer.

Marking transfer sheets

Marking transfer sheets and process

Described are a marking composition of a color-forming, radiation-sensitive component, a diffusely reflecting pigment and a binder, and a process for the use of the same comprising coating a product surface with the marking composition; exposing the coating to a pattern of radiation to form a marking; and then reading the marking with a diffuse reflectance scanning means.

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Greenville, DE, United States of America

Rolf Dessauer