Uop Lcc

Roger L Peer

Michael B Russ

Chi-Chu D Low

Joseph Zmich

Frank R Whitsura

Mark D Moser

R Joe Lawson

Li Wang

Vivekanand N Parulekar

Irvin S Fisch

Charles R Hamlin

A hydrocarbon feedstock is catalytically reformed to effect dehydrocyclization of paraffins in a process combination comprising a first reforming zone, a sulfur-removal zone containing a mixed reforming catalyst and sulfur sorbent comprising a manganese component to preclude sulfur from the feed to a second reforming zone. The process combination shows substantial benefits over prior art processes in achieving reforming-catalyst stability.

Catalytic reforming process with sulfur preclusion

A hydrocarbon feedstock is catalytically reformed to effect dehydrocyclization of paraffins in a process combination comprising a first reforming zone containing a mixed reforming catalyst and sulfur sorbent and a sulfur-removal zone utilizing a manganese component to preclude sulfur from the feed to a second reforming zone. The process combination shows substantial benefits over prior art processes in achieving reforming-catalyst stability.

A hydrocarbon feedstock is catalytically reformed to effect dehydrocyclization of paraffins in a process combination comprising a first reforming zone and a sulfur-removal zone utilizing a manganese component to preclude sulfur from the feed to a second reforming zone. The process combination shows substantial benefits over prior art processes in the stability of the extremely sulfur-sensitive catalyst utilized in the second reforming zone.

A hydrocarbon feedstock is catalytically reformed in a process which comprises contacting the feedstock in an initial catalyst zone with a catalyst comprising platinum, germanium and halogen on a solid catalyst support. The product from the first catalyst zone is contacted in a terminal catalyst zone with a catalyst having the essential absence of germanium and comprising platinum, halogen and a metal promoter on a solid catalyst support.

Multizone catalytic reforming process

A sacrificial particulate bed is utilized to remove contaminants, such as sulfur, from a conversion system. Subsequently, the sacrificial particulate bed is replaced by a contaminant-sensitive catalyst, such as a reforming catalyst selective for dehydrocyclization.

Cleanup of hydrocarbon conversion system

A multiple-stage catalytic conversion system in which a hydrocarbon charge stock is countercurrently reacted in a plurality of catalytic reaction zones, in all of which the catalyst particles are downwardly movable via gravity-flow. The charge stock, in the absence of added, or recycled hydrogen, is reacted serially in the reaction zones in the order of increasing catalyst loading, the product ultimately being recovered from the effluent emanating from that reaction zone (1) into which fresh, or regenerated catalyst particles are introduced and, (2) which contains the greatest quantity of catalyst particles. Catalyst particles are transferred from one reaction zone to another in the order of decreasing catalyst loading, ultimately being withdrawn from the system through the reaction zone containing the least amount of catalyst particles.

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LaGrange, IL, United States of America

Roger L Peer