Cities Service Oil and Gas Corporation

Ecolab Inc.

Roger C Zillmer

Burton B Sandiford

Rhonda Kay Schulz

Helen B Bailly

The invention provides a process for preparing a homogeneous, urea-based, solid cleaning composition, without the application of heat from an external source to melt the urea. Cleaning compositions for use in warewashing and cleaning hard surfaces, rinsing, sanitizing, deodorizing, and the like, made by the method are also provided. Preferably, the ingredients are processed in an extruder, and the mixture is extruded directly into a mold or other packaging system for dispensing the detergent. The consistency of the composition ranges from that of a fused solid block to a malleable article.

Urea-based solid cleaning compositions free from or containing minor

Method of making urea-based solid cleaning compositions

A gel-forming composition is provided comprising a first substance selected from the group consisting of a polyvinyl alcohol, a polyvinyl alcohol copolymer, and mixtures thereof, glutaraldehyde, and water, and which does not require a separately provided acidic catalyst to crosslink and form a gel. The gel-forming composition is useful for retarding the flow of fluids in subterranean formations. For example, a method is provided for retarding the flow of water in high permeability channels in an oil reservoir. Such method is particularly useful in waterflood operations to increase the sweep efficiency of the oil recovery process. Since these gels have very good stability at elevated temperature they can be used in reservoirs having an average in situ temperature of 80.degree. C. or higher.

Process for retarding fluid flow

A gel-forming composition is provided comprising a first substance selected from the group consisting of a polyvinyl alcohols, polyvinyl alcohol copolymers, and mixtures thereof, a second substance selected from the group consisting of aldehydes, aldehyde generating substances, acetals, acetal generating substances, and mixtures thereof capable of crosslinking with the first substance through the formation of acetal crosslinkages, and water, and which requires contacting with a sorbed substance or brine which has sorbed substantial amounts of carbon dioxide before the gel-forming composition will form a gel. The gel-forming composition is useful for retarding the flow of carbon dioxide and other fluids in subterranean formations. For example, a method is provided for preventing the loss of carbon dioxide to nonproductive parts of an oil reservoir. Such method is particularly useful in carbon dioxide flood operations to increase the sweep efficiency of the oil recovery process and in cyclic carbon dioxide injection operations for increasing the fluidity of the reservoir oil.

Gel and process for preventing carbon dioxide break through

A rapid setting gel-forming composition is provided comprising a first substance selected from the group consisting of a polyvinyl alcohol, a polyvinyl alcohol copolymer, and mixtures thereof, and aldehyde, and water, which is useful in preventing the loss of circulation fluids in well drilling, completion of workover operations. A combination process is also provided using a slower setting gel-forming composition for retarding the flow of waters or brines in high permeable non-productive channels in combination with a subsequent acidizing step for increasing the permeability of low porous structure in subterranean formations. The combination process is particularly useful in waterflood operations to increase the sweep efficiency of the oil recovery process while improving the flow oil and drive water in the productive parts of the reservoir.

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Apple Valley, MN, United States of America

Roger C Zillmer