Betz Laboratories, Inc.

Betzdearborn, Inc.

General Electric Company

Ge Betz, Inc.

Roger C May

David W Reichgott

Michael A Cady

Sydia B Anderson

Gary E Geiger

Anita G Monino

Stephen M Kessler

Frank C Sessa

Fu Chen

Alan E Goliaszewski

David Birenbaum Engel

William S Carey

Rosa Crovetto

Ping Lue

Kristin E Buentello

Natalie A Kolson

Suzanne M Zefferi

Julie A Kaechelin

Kristof Kimpe

Methods for reducing calcium deposition along surfaces in contact with the water phase of a resolved water/oil emulsion are disclosed. High calcium crude oil and the like are contacted with a sequestrant to form a sequestered calcium containing complex that partitions to the water phase in the resolved emulsion. A specifically formulated polymeric deposit control agent is added to the water phase to inhibit calcium deposit formation therein and along surfaces in contact with the water phase.

Method for removing calcium from crude oil

The present invention provides an effective method of inhibiting corrosion on metallic surfaces in contact with a fluid contained in a closed loop industrial fluid system, which comprises adding to such fluid an effective corrosion controlling amount of a combination of an organic diacid, a triamine and a phosphonate compound.

Corrosion inhibitor treatment for closed loop systems

Method for controlling scale formation and deposition in aqueous systems

The use of halo-benzotriazoles as corrosion inhibitors in aqueous systems is disclosed. Halo-benzotriazoles such as chloro-tolyltriazole and bromo-tolyltriazole were found to be more effective corrosion inhibitors than tolyltriazole in the presence of chlorine.

Methods of inhibiting corrosion using halo-benzotriazoles

A method and composition for controlling corrosion of metals in contact with an aqueous system is disclosed, which method includes introducing into the aqueous system a sufficient amount of a substantially zinc-free treatment comprising a phosphate compound, and glucoheptonic acid or a water soluble salt thereof.

Inhibition of corrosion in aqueous systems

A method of inhibiting corrosion of metals such as low carbon steel in contact with calcium chloride brine comprising adding to the brine or to the salt prior to dissolution 2-hydroxyphosphono-acetic acid.

Corrosion inhibition of calcium chloride brine

A method for inhibiting corrosion and controlling deposition in an iron containing aqueous medium is disclosed. The method is capable of providing for the formation of a protective passive oxide film on the metallic surfaces in contact with the aqueous medium without resulting in unacceptable iron based deposition or fouling. Surprisingly, the method does not call for the addition of an organic-phosphonic acid compound or derivative to the aqueous medium as would be normally expected due to the known iron dispersing characteristics of these type compounds. The invention comprises maintaining the pH level at 5.5 or above, assuring that a certain minimal calcium or other ion level is maintained, and adding to the system an orthophosphate compound, a water soluble acrylic acid/hydroxyalkylacrylate copolymer, and a topping agent selected from the group consisting of effective water soluble aminocarboxylic acids, lignosulfonates, citric acid, and tannic acid, and water soluble salt forms and mixtures thereof.

Control of iron induced fouling in water systems

A method for reducing corrosion of metal surfaces is disclosed according to which a specific corrosion inhibitor is utilized. The inhibitor comprises water-soluble zinc compound, water-soluble chromate compound and copolymer of acrylic acid and hydroxylated lower alkyl acrylate. Water-soluble orthophosphate can also be used.

Method of corrosion inhibition in aqueous mediums

A method for inhibiting corrosion and controlling deposition in an iron containing aqueous medium is disclosed. The method is capable of providing for the formation of a protective passive oxide film on the metallic surfaces in contact with the aqueous medium without resulting in unacceptable iron based deposition or fouling. Surprisingly, the method does not call for the addition of an organic-phosphonic acid compound or derivative to the aqueous medium as would be normally expected due to the known iron dispersing characteristics of these type compounds. The invention comprises maintaining the pH level at 5.5 or above, assuring that a certain minimal calcium or other ion level is maintained, and adding to the system an orthophosphate compound and a water soluble acrylic acid/hydroxyalkylacrylate copolymer.

A composition is disclosed comprising a stable aqueous solution of (i) water-soluble zinc compound, (ii) water-soluble chromate compound and (iii) a particular type of water-soluble polymer composed essentially of moieties derived from acrylic acid and hydroxylated lower alkyl acrylates. The composition could additionally comprise (iiii) orthophosphate.

Stable compositions for use as corrosion inhibitors

The invention deals with a method and composition(s) for use in inhibiting corrosion of metallic parts in contact with aqueous systems. It has been discovered that protective oxide films can be formed on the metallic surface if such is allowed to contact an aqueous system containing a sufficient amount for the purpose of a polymer composed primarily of acrylic moieties and hydroxylated lower alkyl acrylate moieties and a water-soluble orthophosphate. Optionally but desirably, polyphosphates, organo-phosphonates, and copper corrosion inhibitors may be included.

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Glenside, PA, United States of America

Roger C May