Eni S.p.a.

Roberto Paglino

Roberta Miglio

Pietro Cesti

Giuliana Franzosi

Lino Carnelli

Daniele Fabbri

Alisar Kiwan

Cristian Torri

There is a process for the production of a liquid fuel and of a gaseous fuel from biomass. The biomass is sent to a pre-treatment section to form a homogeneous phase that can be moved and/or pumped, wherein inert parts are separated from the biomass and the biomass shredded and/or ground to reduce its size. The homogeneous phase obtained is then subjected to subcritical hydrothermal liquefaction at a temperature between 240° C. and 310° C. to form a liquefied phase. The liquefied phase is separated. After separation, the process continues in two alternative and mutually exclusive modes. In the first mode, the first aqueous phase is subjected to an anaerobic reaction with multiple stages producing biogas; the oily phase is separated into a bio-oil and a solid residue. In the second mode, the separate mixed phase is separated by density or dynamics forming a first aqueous phase, bio-oil and a gaseous phase. The first aqueous phase is subjected to a multiple-stage anaerobic reaction from which biogas, a muddy current and a second aqueous phase are produced.

Process for the production of bio-oil and biogas from biomass

Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises: &#x2014;feeding said aqueous stream containing the organic by-products of the reaction to a distillation column, obtaining two output streams: &#x2014;an aqueous stream (i) exiting from the column head, enriched with alcohols having from 1 to 20 carbon atoms, preferably from 1 to 9 carbon atoms, and other optional volatile compounds; an aqueous stream (ii) exiting from the column bottom, enriched with organic acids having from 1 to 10 carbon atoms, preferably from 2 to 6 carbon atoms; &#x2014;subjecting said aqueous stream (ii) to an anaerobic biological treatment obtaining a purified aqueous stream (iii); wherein said anaerobic biological treatment is carried out with a hydraulic retention time lower than 15 hours, preferably ranging from 4 hours to 10 hours, more preferably ranging from 5 hours to 8 hours.

Process for the purification of an aqueous stream coming from the fischer-tropsch reaction

Growing community of inventors

Trecate, Italy

Roberto Paglino