Societe Nationale Elf Aquitaine (production)

Societe Nationale Elf Aquitaine

Elf Aquitaine Production

Robert Voirin

Andre Philippe

Georges Kvasnikoff

Rene Pornin

Andre Pepy

Jean-Henri Blanc

Pierre Mathieu

Thierry Dupin

Jacques Tellier

Jean Elgue

Claude Chambu

A single-stage low temperature catalytic process for desulphurisation of a gas which contains a mixture of H.sub.2 S and SO.sub.2 which process includes feeding the gas to be treated at a temperature below the dew point of sulphur to a Claus converter having a Claus catalyst in a reaction stage in which the catalyst includes a composite catalytic mass of alumina and one or more compounds of titanium, yttrium, lanthanum or the rare-earth elements of atomic number 58 to 71, and contacting the gas with the Claus catalyst at a temperature below the dew point of sulphur, by which sulphur deposits on the Claus catalyst and the gas is desulphurised.

Method for desulphurising a gaseous mixture containing H.sub.2 S and SO.sub

A process is provided for improving the sulphur yield of a sulphur production unit using an acid gas containing H.sub.2 S and wherein said unit is comprised of a sulphur plant with a downstream purification unit. The H.sub.2 S resulting from hydrolysis of COS and CS.sub.2 is almost entirely recovered in the form of sulphur in the purification unit resulting in an improved sulphur output of the overall installation.

Process for improving the sulphur yield of a complex for the production

The invention is a catalytic process for removing H.sub.2 S and hydrogen polysulfides from liquid sulfur. The process comprises mixing a heterocyclic compound with the liquid sulfur and removing the hydrogen sulfide from the liquid sulfur by contact with a gas which is inert to the liquid sulfur at the treating temperature.

Catalytic removal of hydrogen sulfides from liquid sulfur

A catalytic process for the production of sulphur from an acid gas containing H.sub.2 S, in which a part of H.sub.2 S is catalytically oxidized in order to form an effluent containing H.sub.2 S and SO.sub.2 in a molar ratio of 2:1 and a given quantity of sulphur, then said effluent is contacted with a CLAUS catalyst to form a further quantity of sulphur. The catalytic oxidation of H.sub.2 S is carried out in the presence of an oxidation catalyst consisting of agglomerates comprising an active alumina thermally stabilized by at least one oxide from the group consisting of SiO.sub.2, ZrO.sub.2, the rare-earth metal oxides and the alakline-earth metal oxides to which are associated one or more compounds of metals such as iron that promote the oxidation of H.sub.2 S.

Catalytic process for the production of sulphur from a gas containing

Regenerative process for removing mercaptans contained in a gas

Process of removing of COS and CS.sub.2 compounds contained in an

A catalytic process for the production of sulphur from an acid gas containing H.sub.2 S, in which a part of H.sub.2 S is catalytically oxidized in order to form an effluent containing H.sub.2 S and SO.sub.2 in a molar ratio of 2:1 and a given quantity of sulphur, then said effluent is contacted with a CLAUS catalyst to form a further quantity of sulphur. The catalytic oxidation of H.sub.2 S is carried out in the presence of an oxidation catalyst consisting of agglomerates comprising an active alumina thermally stabilized by at least one oxide from the group consisting of SiO.sub.2, ZrO.sub.2, the rare-earth metal oxides and the alkaline-earth metal oxides to which are associated one or more compounds of metals such as iron that promote the oxidation of H.sub.2 S.

Catalytic process for the production of sulfur from a gas containing

Catalytic desulfurization process of an acid gas containing H.sub.2 S

Catalytic process for the production of sulphur from an acid gas containing H.sub.2 S, in which a part of H.sub.2 S is catalytically oxidized in order to form an effluent containing H.sub.2 S and SO.sub.2 in a molar ratio of 2:1 and a given quantity of sulphur. The effluent is then contacted with a CLAUS catalyst to form a further quantity of sulphur. Said process involves:

Improved process for the production of sulphur from a gas containing H.sub.2 S, SO.sub.2, H.sub.2 and/or CO, in which the gas is caused to pass through a CLAUS catalyst in a primary catalytic stage operating at between 200.degree. and 460.degree. C. in order to form sulphur, and thereafter the sulphur contained in the reaction mixture issuing from this stage is condensed through indirect heat exchange with water to produce steam. The improved process consists in constituting at least the final eighth of the catalyst volume in this stage by a composite mass formed from a refractory oxide on which is fixed a transition metal compound, for example Co and/or Mo, and in entering into contact the gas with this composite mass at between 300.degree. and 460.degree. C. in order to oxidize H.sub.2 and CO. The energy resulting from this oxidation is recovered in the form of a supplementary quantity of steam during the sulphur condensation.

Process for the production of sulphur with increased energy recovery

A process for the catalytic incineration of residual gases containing a low content of H.sub.2 S and/or SO.sub.2, organic compounds of sulfur such as COS, CS.sub.2, mercaptans and possibly vapor and/or vesicular sulfur, comprising a hydrogenation stage which transforms all the sulfur compounds into H.sub.2 S followed by a catalytic oxidation stage to transform H.sub.2 S into SO.sub.2. The catalyst used in the oxidation stage consists in a porous support, having a surface area of at least 5 m.sup.2 /g and containing, by weight, 50 to 100% of a product selected from the group comprising titanium or zirconium oxides, silica and zeolites, and 50 to 0% alumina, to which is associated one or several compounds of metals belonging to the group formed by Cu, Ag, Zn, Cd, Y, Lanthanides, V, Cr, Mo, W, Mn, Fe, Co, Rh, Ir, Ni, Pd, Pt, Sn and Bi. The use of such an oxidation catalyst leads to a practically quantitative yield of conversion of H.sub.2 S into SO.sub.2, this yield being maintained steadily throughout the process.

Process for the catalytic incineration of residual gases containing a

In a process for desulphurizing gases containing SO.sub.2 and SO.sub.3 by absorption of the sulphur containing compounds by means of absorbents based on alumina free of alkaline substances, activated alumina or alumina carrying salts or oxides of at least one element selected from the groups IB, IIB, IVB, VB, VIB, VIIB, VIII of the Periodic Classification, the absorption takes place at temperatures comprised between 100.degree. and 400.degree. C., and the absorbent loaded with said compounds in the form of sulphates is heated with a gas containing a reducing gas, especially H.sub.2 S, to a temperature of 250.degree. C. to 450.degree. C., while the elementary sulphur thus formed is separated from said absorbent, whereafter the latter is re-used in a subsequent absorption operation.

Process and installation for desulphurizing gases containing SO.sub.2

The Claus process for the production of sulphur is improved by employing a deoxidation catalyst prior to the conventional Claus oxide catalyst.

Sulphur production

Novel hydrophilic modified acrylic polymers, which are, in particular, hydrosoluble or hydrodispersible. These novel polymers contain, expressed in molar percentages, p % of units derived from an acrylic acid or ester, q % of units derived from an alkanolamine of said acid, r % of units derived from the alkali metal, alkaline earth metal or ammonium salt of the said acid, and s % of units derived from a vinylic monomer, p, q, r and s representing integers and being so selected that 1.ltoreq.p.ltoreq.99, O.ltoreq.q.ltoreq.96, O.ltoreq.r.ltoreq.99 and O.ltoreq.s.ltoreq.40, and the sum (p+q+r+s) is equal to 100.

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Orthez, France

Robert Voirin