Other

Robert R Dean

Jean-Louis Mauleon

Robert W Pfeiffer

Jean L Mauleon

Robert J Newman

Warren S Letzsch

The invention described is directed to the fluid catalytic conversion of hydrocarbons and is concerned particularly with the method and means for obtaining atomized-vaporized contact of residual oils and reduced crudes with high temperature dispersed phase fluid catalyst particles. More particularly, one embodiment of the invention is directed to atomizing an oil-water emulsion thereafter discharged into up-flowing dispersed phase catalyst particles at velocities up to sonic velocities to form a suspension under hydrocarbon conversion conditions.

Residual oil feed process for fluid catalyst cracking

The invention described is concerned with atomizing an oil fraction of crude oil to provide a fog of oil droplets in diluent gaseous material which is sprayed into an upwardly flowing annular dense mass of catalyst particles to form a high temperature suspension therewith and conveyed through a riser conversion zone under selected hydrocarbon conversion conditions suitable for cracking the oil droplets to gasoline and light cycle oil boiling range products. The oil feed preparation and distribution arrangement to form a suspension with catalyst particles of desired elevated temperature is employed in combination with a two-stage catalyst regeneration operation designed and operated to achieve catalyst temperatures at least equal to the pseudo-critical temperature of the oil feed and at least above the end boiling point of gas oil boiling range material and resid product of vacuum distillation.

Method and means for preparing and dispersing atomed hydrocarbon with

An integrated combination of fluid catalytic cracking and hydrocracking select fractions of crude oil and FCC cycle oils to conserve hydrogen process requirements in the production of gasoline is discussed. Liquid products of hydrocracking are separated into low boiling components and a high boiling fraction is recycled to the FCC operation. Select fractions obtained from hydrocracking, FCC and crude oil distillation are upgraded by reforming and alkylation.

Combined fluid catalytic cracking and hydrocracking process

A process for converting residual oil comprising vacuum bottoms in the presence of a cracking catalyst of high surface area and comprising an ultrastable zeolite is described. More particularly, a conversion process particularly contributing to producing cycle oil and gasoline boiling range products with reduced carbon deposition in combination with a relatively high regeneration temperature operation of at least 1350.degree. F. and above, and a short contact time riser hydrocarbon conversion operation contributing to reducing slurry oil product in favor of lower boiling products is described. A fluid cracking catalyst comprising a special ultrastable crystalline zeolite of high silica to alumina ratio provides hydrothermal stability of acceptable tolerance in the environment employed.

Method for catalytically converting residual oils

A side by side hydrocarbon conversion-two staged stacked catalyst regeneration arrangement is provided wherein the first stage of catalyst regeneration is temperature restricted to achieve incomplete removal of carbon deposits and a second higher temperature regeneration is accomplished in an upflowing catalyst contact system under conditions to accomplish removal of residual carbon on the catalyst and produce a CO.sub.2 -rich flue gas. A special external cyclone separator arrangement may be attached to either of the second stage regeneration operation or the riser hydrocarbon conversion operation to effect separation of catalyst particles from gasiform material.

Method and apparatus for cracking residual oils

A hydrocarbon conversion-catalyst regeneration process and apparatus is described for converting residual oils and regeneration of catalyst in two separate low and higher temperature regeneration stages stacked one above the other on the same or different vertical axis to provide catalyst at a temperature above the residual feed psuedo-critical temperature. A CO rich flue gas is recovered from the low temperature regeneration stage and a CO.sub.2 rich flue gas is recovered from the higher temperature regeneration stage. The temperature of the catalyst mixed with the residual oil feed is sufficient to obtain substantially complete vaporization of the residual oil charge. A special arrangement of apparatus is provided in the lower portion of a riser conversion zone to obtain the intimate vaporization contact between residual oil feed and the high temperature catalyst charged to the riser.

A hydrocarbon conversion-catalyst regeneration process and apparatus is described for converting residual oils and regeneration of catalyst in two separate low and higher temperature regeneration stages stacked one above the other on the same or different vertical axis to provide catalyst at a temperature above the residual feed pseudo-critical temperature. A CO rich flue gas is recovered from the low temperature regeneration stage and a CO.sub.2 rich flue gas is recovered from the higher temperature regeneration stage. The temperature of the catalyst mixed with the residual oil feed is sufficient to obtain substantially complete vaporization of the residual oil charge. A special arrangement of apparatus is provided in the lower portion of a riser conversion zone to obtain the intimate vaporization contact between residual oil feed and the high temperature catalyst charged to the riser.

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Littleton, CO, United States of America

Robert R Dean