Exxonmobil Research and Engineering Company

Exxonmobil Chemical Patents Inc.

Robert Piszczek

Brian D Albert

Michael Louis Hergenrother

Vikram Singh

Brian W Heins

Paul Hamilton

Jose X Simonetty

Terrance C Osby

Todd P Marut

David A Hokanson

Simon Y Yeung

Zhonghcheng Wang

Dion Zhang

Philippe D'Hooghe

Erik Kluwen

Zhongcheng Wang

Jason A Nichols

Many linear alpha olefin (LAO) syntheses form a range of LAO products when oligomerizing ethylene in the presence of a Ziegler-type catalyst. The range of products typically requires a plurality of distillation columns to separate the LAO products up to a desired carbon count, but such approaches may be energy- and capital-intensive. LAO product separation using at least one dividing wall column may lessen these burdens. Methods for separating LAOs may comprise: providing a pre-processed product stream comprising Cg+ linear alpha olefins (LAOs) to a first of a series of distillation columns, at least one member of the series of distillation columns comprising a dividing wall column; and separating an overhead stream comprising a first LAO from the dividing wall column and one or more side streams from the dividing wall column, each side stream comprising a different LAO that also differs from the first LAO.

Process for the separation of linear alpha-olefins using a dividing wall column

Systems and methods are provided for improving process control of separation systems that include one or more dividing walls within a single column. It has been discovered that improved process control can be achieved by controlling the dividing wall columns based on energy balance instead of mass balance. The energy balancing can be performed in part based on controlling temperature at a plurality of locations on the feed side within a first divided portion of the column. Using energy balancing based on temperature control at a plurality of locations on the feed side can facilitate maintaining the operation of the dividing wall columns within a single region of phase space that can be suitably approximated by linear models. This can allow conventional process controllers to manage the manipulated and controlled variables. In addition to controlling the temperature at a plurality of locations on the feed side, a plurality of other characteristics can be used as manipulated or controlled variables. Optionally, a multivariable controller can be used to provide further improved control of the column.

Advanced process control scheme for dividing wall column and dual-dividing wall column with multiple products

Systems and methods are provided for separating a feedstock into a plurality of separation products using dividing wall column technology that includes a plurality of dividing walls. Including a plurality of dividing walls in the column can provide reduced energy consumption and reduced equipment footprint for production of a plurality of high purity distillation products. The systems and methods can allow for separation of a large number of products from a feed while having a reduced or minimized number of liquid splits and/or vapor splits.

Dual-dividing wall column with multiple products

Vane type mist eliminator segments are arranged in a plurality of tiers at separate vertically spaced locations in a tower, typically of the upright, cylindrical type, with the eliminator at each tier covering only a portion of the cross section of the tower. The eliminator segment(s) in each tier are laterally displaced in the tower from the adjacent vertically spaced eliminator segments to form a staggered configuration for the segments. Each mist eliminator preferably extends over 50-70% of the cross-sectional area of the tower to leave an open flow passage in the tier; the staggering of the segments and the associated flow passages defines an upward tortuous or zig-zag open flow path for vapors ascending the tower through the open flow passages when the eliminator segment(s) become fouled in use.

Mist eliminator configuration for droplet removal in fouling service

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Spring, TX, United States of America

Robert Piszczek