W. R. Grace Co.-conn.

W. R. Grace Co.

Robert M Spotnitz

Robert P Kreh

Wu-Cheng Cheng

Christian B Lundsager

Chia-Chih Ou

Semyon D Friedman

Howard J Troffkin

Richard T Giovannoni

Yihong Guo

Robert W McKinney

Shaohai Wu

Burton M Rein

Charles G Carter

Awdhoot V Kerkar

Roy W Rice

Rasto Brezny

Vincent R Kuhn

Vladimir Jovancicevic

John Richardson

Douglas S McFarland

Porous monolithic ceramic bodies containing reticulated macropores are produced by:

Method of making microcellular ceramic bodies

A vermiculite composition capable of exhibiting a high degree of volume increase upon subjection to thermal exfoliation composed of vermiculite mineralogical species having specific gravity of from 2.5 g/cm.sup.3 to 2.9 g/cm.sup.3. Further, intumescent sheets formed with said vermiculite composition exhibit low initial expansion temperature and very high maximum expansion properties.

Vermiculite composition with improved thermal expansion properties

A vermiculite composition composed of particulate vermiculite mineral species having a density of 2.3 g/cm.sup.3 to 2.7 g/cm.sup.3 which has intercalated cations of lithium or organo ammonium and to dispersions obtained therefrom.

Vermiculite composition with improved chemical exfoliation

The present invention is directed to a multi-ply unfilled microporous sheet product composed of at least one first ply and at least one second ply which are, respectively, formed from polymeric compositions having different rheological properties and to a method of forming said sheet product.

Battery separator

A process of having a microporous multiply sheet product which is capable of becoming non-porous at a predetermined elevated transformation temperature is formed by first forming a non-porous, multiply initial sheet product having at least one first ply and at least one second ply, each with its own viscosity profile. The initial sheet product is then stretched and annealed to impart porosity to the sheet product.

Process of making a battery separator

The invention encompasses a method of forming a densified ceramic part comprising the steps:

Manufacture of optical ferrules by electrophoretic deposition

A method of inhibiting corrosion of a metal surface in an aqueous system having a pH of at least 6, comprising maintaining in the aqueous system, in an amount effective to inhibit corrosion, a water-soluble, organic-rare earth metal chelate which is derived from a rare earth metal having an atomic number from 57 to 71 and an organic chelant. The organic chelant provides not only water solubility but surprisingly enhanced corrosion inhibiting activity. The water-soluble, organic-rare earth chelates may be advantageously combined with other corrosion inhibitors such as zinc chelates, organophosphonates, phosphates, chromates, molybdates, and the like.

Corrosion inhibition with water-soluble rare earth chelates

A process for forming halogen of chlorine and/or bromine by subjecting aqueous hydrohalic acid electrolyte solution to an electrical current while providing a continuous flow of inert gas through the solution and maintaining the solution at a substantially invariant level and composition.

Halogen generation

Catalysts made by the Raney process (e.g., Raney process nickel) pelletized in matrix of polymer and plasticizer are activated by either (a) removal of plasticizer (e.g., by solvent extraction) followed by leaching out Al with caustic solution, leaving an active catalyst made by the Raney process in a polymer matrix; or (b) removal of plasticizer, then calcining to remove polymer, followed by leaching with caustic. The activated catalyst pellets have sufficient strength and attrition resistance for efficient use in fixed beds and packed columns for superior hydrogenation of toluene, heptene, butyraldehyde, and other conventional feedstockers used with catalysts made by the Raney process.

Shaped catalysts and processes

Shaped catalyst and process for making it

Aqueous acidic solutions of certain thallium(III) organosulfonate having at least 0.1 molar thallium ion concentration are contacted with an organic compound to form a related oxidized organic compound. The oxidized compound is separated and recovered from the solution and the resultant thallium(I) rich solution is electrochemically treated to regenerate thallium(III) which, in turn, can be reused in a cyclical process. The present invention provides a highly effective means of oxidizing organic substrates.

Oxidation of organic compounds using thallium ions

A process for oxidizing aromatic and alkyl substituted aromatic compounds to carbonyl containing compounds by contacting an aromatic or alkyl aromatic compound with ceric methanesulfonate in an aqueous, weakly acidic solution containing an organic cosolvent which has at least 2 percent solubility in water under reaction conditions and is substantially inert with respect to the acidic, oxidizing conditions.

Oxidation of organic compounds using ceric methanesulfonate in an

A process for oxidizing aromatic and alkyl substituted aromatic compounds to carbonyl containing compounds by contacting an aromatic and alkyl aromatic compound with an aqueous solution of ceric trifluoromethanesulfonate having from at least 0.75 to 7 molar concentration of free acid of trifluoromethanesulfonic acid and at least 0.2 molar cerium ion concentration. The present process provides a highly effective means of forming the desired carbonyl containing product in good yields and high selectivity.

Oxidation of organic compounds using ceric ions in aqueous

A process for oxidizing aromatic and alkyl substituted aromatic compounds to carbonyl containing compounds by contacting an aromatic and alkyl aromatic compound with an aqueous solution of ceric methanesulfonate having from at least 1.5 to 9 molar concentration of free acid of methanesulfonic acid and at least 0.2 molar cerium ion concentration. The present process provides a highly effective means of forming the desired carbonyl containing product in good yields and high selectivity.

Growing community of inventors

Baltimore, MD, United States of America

Robert M Spotnitz