Ciba-geigy Corporation

Ciba Specialty Chemicals Corporation

Robert Langley

Arthur Stark Walls

Paul Kerwin

Ian A Lambie

Ronald Barraclough

John D Stewart

Colin D Campbell

Kenneth Grant Dykes

Michael D McFarlane

Iain Frank Fraser

Alexander M Irvine

David Keirs

Michael D McFarland

Gordon Mitchell

Paul I Yarrow

Christopher J Bridge

A process for the preparation of a paint concentrate which comprises

Production process

A process for the preparation of an ink concentrate which comprises

Process for the production of ink concentrates

The present invention provides a process for converting a crude pigment into pigmentary form which comprises kneading the crude pigment in the presence of a liquid carboxylic acid and optionally a salt.

Production of pigments

A pigment composition comprising (A) an azo pigment, (B) an azo reaction product of (i) a diazonium salt of a primary aromatic amine having a carboxyl group or sulphonic acid group meta or para to an amino group with (ii) a coupling component comprising one or more unsubstituted or substituted naphthols, at least 50 mole % of said coupling component being a naphtholsulphonic acid, or a salt of said reaction product, and, optionally, (C) an organic resin containingan acidic group or a salt thereof.

Pigment compositions

The present invention provides a process for producing beta-form pigmentary copper phthalocyanine comprising a) producing crude copper phthalocyanine by charging phthalic anhydride or phthalimide, urea, a copper compound and a catalyst, at a substantially continuous and uniform rate, into a reaction chamber containing dry, granular, pre-formed copper phthalocyanine, and removing the reaction product from the reaction chamber; and b) convening the crude copper phthalocyanine produced in step a) into pigmentary form, by milling it either in the dry state or in an aqueous medium; mixing the milled material with an aqueous emulsion comprising i) a liquid C.sub.6 -C.sub.20 amine which is insoluble in water or alkali but is soluble in acid and ii) a surfactant capable of emulsifying the liquid amine; rendering the resulting mixture acidic to thereby dissolve the amine; and finally separating the desired pigmentary copper phthalocyanine from the treatment mixture.

Production of beta form pigmentary copper phthalocyanine

A pigment composition comprising (A) a pigmentary phthalocyanine, (B) a phthalocyanine derivative of formula ##STR1## where Pc is a residue of a metal-free or metal phthalocyanine, X is --CH.sub.2 -- or --SO.sub.2 --, R.sup.1 and R.sup.2 are independently hydrogen, C.sub.1 -C.sub.20 alkyl optionally substituted by hydroxyl, C.sub.1 to C.sub.4 alkoxy, amino, C.sub.1 to C.sub.10 alkylamino or di(C.sub.1 to C.sub.10 alkyl)amino, C.sub.5 to C.sub.10 cycloalkyl, or phenyl optionally substituted by C.sub.1 to C.sub.4 alkyl, C.sub.1 to C.sub.4 alkoxy or halogen, or R.sup.1 and R.sub.2 together with the indicated nitrogen atom denote a five-, six- or seven-membered heterocyclic ring, or R.sup.1 and R.sup.2 together denote a group of formula ##STR2## R.sup.3 is an o-phenylene group optionally substituted by C.sub.1 to C.sub.4 alkyl, C.sub.1 to C.sub.4 alkoxy, nitro or halogen, and m has an average value of 1 to 5, and (C) at least one anionic surfactant selected from (i) a monovalent metal or ammonium salt of an organic sulfonic acid, (ii) a sulfate half-ester of an alcohol or a monovalent metal or ammonium salt thereof, (iii) a sulfosuccinic acid ester or a monovalent metal or ammonium salt thereof, (iv) a sulfosuccinamic acid or a monovalent metal or ammonium salt thereof or (v) an aminosulfonic acid or a monovalent metal or ammonium salt thereof.

Phthalocyanine pigment compositions

A pigment composition comprising a) a pigment; and b) a phthalocyanine compound having the formula I:

A heat-stable, pigmented thermoplastic resin composition comprising A) a thermoplastic resin; B) a metal phthalocyanine pigment; and C) 0.5 to 30% by weight of, based on the weight of component B), as agent for imparting heat stability to component B), a phthalocyanine compound having the formula (I):

Stabilized phthalocyanine pigment compositions

A pigmented thermoplastic resin composition comprising:

Resin compositions

The present invention provides a process for the production of dimethylaminomethyl copper phthalocyanine having an average of 1 to 4 dimethylaminomethyl groups per molecule which comprises reacting aminomethyl copper phthalocyanine having an average of 1 to 4 aminomethyl groups per molecule with formaldehyde and aqueous formic acid at a concentration of 2 to 60%, at atmospheric pressure, and at an elevated temperature.

Production of dimethylaminomethyl copper phthalocyanine

Pigmentary copper phthalocyanine is prepared by converting crude copper phthalocyanine by methods known per se in the presence of trichlorophenoxy copper phthalocyanine. The resulting pigment is heat resistant and solvent resistant.

Production of pigmentary copper phthalocyanine

A process for the production of a pigment composition useful in pigmenting surface coating comprising:

Process for the production of a pigment composition

A copper phthalocyanine derivative having the formula: ##STR1## or a mixture thereof wherein CuPc represents the residue of a copper phthalocyanine molecule, Y is an alkyl or alkenyl residue each having from 8 to 22 carbon atoms, and each being unsubstituted or substituted by one or more hydroxy groups or being interrupted by one or more nitrogen atoms, or Y is an alkoxyaryl- or aralkyloxyaryl, or an alkyl-aralkyloxyaryl residue wherein the alkoxy-, aralkyloxy- or alkyl-aralkyloxy moiety contains from 7 to 22 carbon atoms, and n is an integer from 1 to 8, provides, when incorporated into a phthalocyanine pigment, a phthalocyanine pigment composition having excellent flocculation resistance, when incorporated into paint and printing media, which moreover exhibit improved flow.

Growing community of inventors

Glasgow, United Kingdom

Robert Langley