Lexmark International, Inc.

International Business Machines Corporation

Robert L Vollmer

Vernon M Balthis

Bradley Leonard Beach

Donald Leo Elbert

James F Feeman

Terence E Franey

John Melvin Olson

Robert B Champ

Rodney O Aulick

David Berhard Sclove

Dean S Ehn

Allen C Sanders

Ronald A Merten

Thomas Richard Gadek

Ralph F Fox

Jacob Pacansky

Robert J Waltman

James M Adley

Robert J Rumery

A photoconductor for use in electrophotographic reproduction devices is disclosed. This photoconductor exhibits improved oil resistance when used with liquid toners and excellent cycling stability. The photoconductors of the present invention utilize a phthalocyanine dye, particularly an X-form metal-free phthalocyanine, dispersed in a medium molecular weight polyvinyl chloride binder in the charge generating layer, and a charge transport molecule, particularly a hydrazone such as DEH, in a polyestercarbonate binder in the charge transport layer.

Electrophotographic photoconductor having improved cycling stability and

A alkali-soluble dye for a waterfast ink having structural formula as follows: ##STR1## and an ink containing the dye dissolved in water. Printing from the ink is insoluble below pH 6.0; is an intense black at low concentration; and remains black on acid papers. The aqueous inks are stable and exhibit good printhead nozzle maintenance.

Waterfast dye and aqueous ink

A layered electrophotographic photoconductor is disclosed having a ground plane layer, a charge generating layer carried by the ground plane layer, and a charge transport layer carried by the charge generating layer. The polymeric binder material of the charge transport layer and the charge generation layer comprises an ordered copolyestercarbonate whose ester content is in the range of about 35 wt. % to about 70 wt. %, of which about 60 wt. % to about 70 wt. % is preferred, and of which about 70 wt. % is the most preferred. The charge generating molecule is a squarylium, and more specifically 2,4-bis-(4-dimethylamino-2-hydroxyphenyl) cyclobutene diylium-1,3-diolate (OHSQ), or an operative phthalocyanine compound, and preferably oxytitanium phthalocyanine. The charge transporting molecule is a hydrazone, and more specifically 4-diethylaminobenzaldehyde-1,1-diphenylhydrazone (DEH), or 4-diphenylaminobenzaldehyde-1,1-diphenylhydrazone (TPH).

Electrophotographic photoconductor contains ordered copolyester

A squarylium dye molecule is synthesized from a phenolic precursor. The resulting hydroxy pyrrolidino squarylium (OHPYRRSQ) dye does not have to be purified in order to provide the dye with a negative response in the Ames test for mutagenicity. A xerographic photoconductor using the molecule shows superior electrophotographic performance.

Squarylium charge generating dye and electrophotographic photoconductor

Squaric acid is prepared by reacting hexachlorobutadiene with an excess of morpholine in the presence of an aromatic hydrocarbon solvent while maintaining the temperature between 110.degree. C and 120.degree. C, and then converting the resulting 1,1,3-trichloro-2,4,4-trimorpholino-butadiene to 3-morpholinotrichloro-2-cyclobuten-1-one, which in turn is hydrolyzed in the presence of strong acid to produce the desired squaric acid.

Synthesis of squaric acid

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Boulder, CO, United States of America

Robert L Vollmer