Breed Automotive Technology, Inc.

Key Safety Systems, Inc.

Robert K Walsh

J B Canterberry

John Herman Adams

Samuel Steven Schlueter

Edward Otis Hosey

Mark A Schmidt

Dennis A Trevillyan

A non azide gas generant composition of nitroguanidine and an oxidizer such as phase stabilized ammonium nitrate is provided. A gas generant having nitroguanidine and phase stabilized ammonium nitrate has many desirable characteristics such as little production of ash and the production of essentially toxic free exhaust gas. When nitroguanidine is compressed into a pellet it has needle shaped crystals that bend or distort. When the gas generant pellets are subjected to thermal cycling some nitroguanidine crystals will return to their native conformation resulting in pellet growth. To eliminate this pellet growth, nitroguanidine is passed through a vibrating ball mill. The media in the vibrating ball mill pulverizes the nitroguanidine into an amorphous crumb.

Method of stabilizing the density of gas generant pellets containing nitroguanidine

A non azide gas generant composition of nitroguanidine and phase stabilized ammonium nitrate is provided. This gas generant composition has many desirable characteristics such as little production of ash and the production of essentially toxic free exhaust gas. When nitroguanidine is compressed into a pellet it has needle shaped crystals that bend or distort. When the gas generant pellets are subjected to thermal cycling some nitroguanidine crystals will return to their native conformation resulting in pellet growth. To eliminate this pellet growth, nitroguanidine is passed through a VBM mill. The media in the VBM mill pulverizes the nitroguanidine into an amorphous crumb.

An ignition enhancer and gas heater composition for vehicle occupant restraint systems (commonly known as &ldquo;airbags&rdquo;) contains a non-azide fuel, an oxidizer and a metal. The ignition enhancer composition provides reliable and consistent ignition of a main propellant composition to produce a sufficient amount of gas to inflate an attached airbag within ten to eighty milliseconds or successfully heat the stored gas in a hybrid system. In a preferred embodiment, the enhancer composition contains 5-aminotetrazole, strontium nitrate, boron nitride, mica or clay and aluminum.

Inflator

Ignition enhancer composition for an airbag inflator

Gas generating compositions are formed from a fuel, one or more oxidizers and mica. The gas generant composition of this invention yields solid combustion products and inflating gases having a reduced content of undesirable gases such as NO.sub.x and CO.

Gas generating compositions containing mica

Gas generating compositions contain a non-azide fuel, phase stabilized ammonium nitrate (PSAN) and silicon. These gas generant compositions yield inflation gases having a reduced content of undesirable gases such as NO.sub.x and CO. The gas generanting compositions preferably contain 5-aminotetrazole at a concentration of 15-30 wt. % as the fuel, an oxidizer system at a concentration of 35-80 wt. % which comprises phase stabilized ammonium nitrate, at least 0.5 wt. % silicon, about 1 wt. % iron oxide and at least one material selected from binders and processing aids. The gas generating compositions are useful for inflating vehicle occupant restraint devices and for pyrotechnically operated fire suppression devices. The high level of gases produced by the compositions of the invention allow for smaller inflators which reduce the costs of production and the saving of weight.

Gas generating compositions containing phase stabilized ammonium nitrate

An airbag inflators employ gas generating compositions formed from a fuel, one or more oxidizers and mica. The gas generant composition employed in the airbag inflators yields solid combustion products and inflating gases having a reduced content of undesirable gases such as NO.sub.x and CO.

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Lakeland, FL, United States of America

Robert K Walsh