University of California

The United States of America As Represented by the United States

The United States of America As Represented by the Department of Energy

Robert K Sander

Steven Forrest Son

Blaine W Asay

Jeanne M Robinson

Bryan Henson

Peter M Dickson

Stephen D Rockwood

Jeffrey Pietryga

Richard D Schaller

Kirill K Zhuravlev

James H Glownia

Jerry H Atencio

Edward I McCreary

Michael Whitehead

Xin Luo

Emma T Seegmiller

George Balog

A fiber-based optical pressure-sensor, made using semiconductor nanocrystal quantum dots (NQDs) as the active transducing material, provides response time fast enough for shock wave measurements. For NQDs, the shift in band gap as a result of applied pressure can be observed as a shift of the photoluminescence (PL) peak. Further, the shift of the principal absorbance feature allows pressure measurements faster than those obtainable by following the PL peak.

Real time measurement of shock pressure

Method for monitoring the crystallization of at least one organic material from a liquid. According to the method, a liquid having at least one organic material capable of existing in at least one non-centrosymmetric phase is prepared. The liquid is interrogated with a laser beam at a chosen wavelength. As at least a portion of the at least one organic material crystallizes from the liquid, the intensity of any light scattered by the crystallized material at a wavelength equal to one-half the chosen wavelength of the interrogating laser beam is monitored. If the intensity of this scattered light, increases, then the crystals that form include at least one non-cetrosymmetric phase.

Method for monitoring the crystallization of an organic material from a liquid

The present invention includes a method for identifying and probing phase transitions in materials. A polymorphic material capable of existing in at least one non-centrosymmetric phase is interrogated with a beam of laser light at a chosen wavelength and frequency. A phase transition is induced in the material while it is interrogated. The intensity of light scattered by the material and having a wavelength equal to one half the wavelength of the interrogating laser light is detected. If the phase transition results in the production of a non-centrosymmetric phase, the intensity of this scattered light increases; if the phase transition results in the disappearance of a non-centrosymmetric phase, the intensity of this scattered light decreases.

Method for identifying and probing phase transitions in materials

A bubble chamber spectrometer provides a new method for the sensitive detection of an analyte in a solvent. A bubble chamber receives a solution containing an analyte to be detected. A laser is adapted to direct an output laser beam through the bubble chamber, where the laser is selected to be absorbed by the analyte and to be transmitted by the solvent. A video camera is adapted to display passage of said laser beam through said bubble chamber so that bubbles in the solvent arising from energy deposition in the analyte can be counted to characterize the analyte both quantitatively and qualitatively.

Method and apparatus for bubble chamber spectroscopy

Carbon Monoxide vapor is used to generate coherent, tunable vacuum ultraviolet radiation by third-harmonic generation using a single tunable dye laser. The presence of a nearby electronic level resonantly enhances the nonlinear susceptibility of this molecule allowing efficient generation of the vuv light at modest pump laser intensities, thereby reducing the importance of a six-photon multiple-photon ionization process which is also resonantly enhanced by the same electronic level but to higher order. By choosing the pump radiation wavelength to be of shorter wavelength than individual vibronic levels used to extend tunability stepwise from 154.4 to 124.6 nm, and the intensity to be low enough, multiple-photon ionization can be eliminated. Excitation spectra of the third-harmonic emission output exhibit shifts to shorter wavelength and broadening with increasing CO pressure due to phase matching effects. Increasing the carbon monoxide pressure, therefore, allows the substantial filling in of gaps arising from the stepwise tuning thereby providing almost continuous tunability over the quoted range of wavelength emitted.

Resonantly enhanced method for generation of tunable, coherent vacuum

A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

Device and method for separating oxygen isotopes

In XeBr lasers which make use of HBr as the source of bromine, it has been found that the working life of the laser is limited because of dissociation of the HBr in the lasing region to form H.sub.2 and Br.sub.2. Accordingly, apparatus is disclosed for substantially improving the working time of the XeBr laser wherein means are provided for recombining H.sub.2 and Br.sub.2 into HBr and for continuously circulating the gaseous working medium from the lasing region through the recombination region.

Growing community of inventors

Los Alamos, NM, United States of America

Robert K Sander