The Upjohn Co.

Robert J Lockwood

Harold E Reymore, Jr

Louis M Alberino

Alexander McLaughlin

Edward J Thompson

Richard H Roess

Polyurethanes having a two phase morphology and characterized by high impact strength and, optionally, high modulus are obtained by reaction of 4,4'-methylenebis(phenyl isocyanate) and modified forms thereof with an aliphatic glycol extender and a blend of at least two polyoxypropylene-polyoxyethylene polyols both of which have average functionalities in the range of 2 to 4, one of which has a molecular weight in the range of about 3000 to 10,000 and contains at least 23 percent by weight of ethylene oxide residues and the other has a molecular weight in the range of about 750 to about 2000 and contains at least 45 percent by weight of ethylene oxide. The two or more such polyols are employed in proportions such that the aliphatic glycol extender is completely miscible with said polyols if blended together.

Novel compositions and process

Polyurethane polymers comprising the reaction product of an organic polyisocyanate (A), an organic polyol (B), & a difunctional extender (C) wherein the improvement comprises employing as the polyisocyanate (A) a composition comprising a bond of, (a) a prepolymer comprising the reaction product of methylenebis (phenyl isocyanate) with a polyol mixture comprising:

Polyurethane prepared from polyisocyanate blend

A novel cocatalyst combination for the trimerization of polyisocyanates to polyisocyanurates is disclosed. The catalyst combination comprises: (a) alkali metal glycine salts, (b) hydroxyalkyltrialkylammonium carboxylate salts, and (c) alkali metal salts selected from the group consisting of (i) alkali metal salts of N-phenyl aliphatic amides, and (ii) alkali metal salts of aliphatic carboxylic acids. The use of the cocatalyst combination provides for the facile formation of polyisocyanurate foam laminate boardstock which is characterized by good fire resistance and good physical properties.

A cocatalyst system for trimerizing isocyanates

A novel catalyst combination for the trimerization of polyisocyanates to polyisocyanurates is disclosed. The catalyst combination comprises (i) an alkali metal salt of an N-substituted amide, (ii) an alkali metal salt of an N-(2-hydroxyphenyl)methyl glycine, and optionally a tertiary amine trimerization catalyst. The use of these catalyst combinations in the preparation of polyisocyanurate foams results in the facile continuous formation of laminate board stock. The polyisocyanurate foams produced using the novel catalyst combinations of the invention are characterized by having high resistance to heat distortion and volume change.

Novel cocatalyst system for trimerizing polyisocyanates

A novel process for the preparation of polyisocyanurate spray foams is disclosed. The catalyst combination comprises (i) N,N-dimethylcyclohexylamine, and (ii) a tetra (lower-alkyl) quaternary ammonium salt of an alkanoic acid. The use of this catalyst combination in the preparation of polyisocyanurate spray foams enables the systems to be sprayed under conditions of low ambient temperature upon cold substrates and to achieve good adhesion between the foam and substrate under such conditions. The polyisocyanurate foams produced using the novel catalyst combination of the invention are characterized by having high resistance to flame and heat distortion.

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East Haven, CT, United States of America

Robert J Lockwood