Canadian Liquid Air Ltd - Air Liquidecanada Ltee

Canadian Liquid Air Limited

Eisenwerk-gesellschaft Maximilianshutte Mbh

Air Liquide Canada Ltee

Canadian Liquid Air Ltd./air Liquide Canada

Canadian Liquid Air Ltd/air Liquide

Robert G Lee

Guy Savard

Derek Hornsey

Jose M Dieguez

Guillermo F Garrido

Karl Brotzmann

Hans-Georg Fassbinder

Helmut Knuppel

Arthur S Perkins

Olivier Francois

A method and apparatus to prepare and deliver a gas mixture of constant composition of liquid chemical compounds soluble in liquid carbon dioxide to be used as an enhanced attractant for biting insects. The mixtures can be prepared in high pressure vessels where carbon dioxide remains liquified under its own vapor pressure or in low pressure vessels where carbon dioxide is kept liquid, at low pressure, by cooling it with a refrigeration unit. Direct vaporization of the liquid mixture from the vessels results in a gas mixture of constant composition. This mixture is to be delivered in a continuous or pulsed flow to an insect trap. These baited insect traps are an ecological alternative to chemical insecticide methods of insect control currently in use.

Method and apparatus for formation and delivery of insect attractant

A process and apparatus for leaching metal values from a particulate mineral ore containing metal values employs a fluidized bed of the particles; a leaching agent solution containing dissolved oxygen flows upwardly of the bed in a lower leaching zone, to an upper clarification zone; a velocity profile is maintained to promote settling of particles so that the particulate solids remain in the leaching zone and a clarified leachant-containing liquid low in suspended solids rises and collects in the clarification zone; the process is carried out with a minimum of undissolved gas and avoids the need for mechanical agitation, but the kinetics of the chemical leaching reaction is improved and heat loss via escaping gases is avoided.

Hydrometallurgical leaching process and apparatus

A gas, for example, oxygen which has low solubility in water is efficiently dissolved and reacted with a substance in a flowing liquid medium by injecting the gas into the flowing liquid at spaced apart points such that a bubble flow condition is maintained and the injected gas is dissolved and substantially consumed by reaction with the substance in the interval between adjacent injection points; in this way the gas is injected at a point at which the aqueous liquid has maximum dissolving capacity and the number of injection points can be minimized; in another embodiment oxygen injection is controlled to maintain a desired oxygen:liquid ratio effective for efficient dissolving of the oxygen while maintaining the bubble flow condition, however, this requires more injection points.

Pipeline reactor and method

An inert gas such as helium is employed as a tracer gas in a pulp and paper mill to determine the utilization of oxygen by an aqueous cellulosic pulp particularly, as well as other parameters, in an oxygen delignification or extraction in which oxygen is dissolved in the pulp and reacted to solubilize lignins and reduce the requirement for chlorine-based bleaching chemicals.

Apparatus and method for measuring vent gas flow rates and parameters in

Oil is recovered from an underground formation by the use of steam and a gas rich in oxygen. In a priming stage, high quality saturated steam or superheated steam is injected into the formation to raise the reservoir temperature, in the vicinity of injection, to the combustion temperature of the oil. Then, in a combustion stage, the injection of steam is continued and oxygen-containing gas is injected as well, so that local combustion of oil occurs. This results in further heating of the steam and the generation of hot combustion gases, increasing the mobility of the oil and creating pressure drive. The priming and combustion stages may be part of a cyclic steam stimulation ('huff and puff') method or a steam flooding method. Special expedients are provided for the safe use of oxygen and steam.

Process and device for oil recovery using steam and oxygen-containing gas

The invention is concerned with a substantially nitrogen-free process for chloride-route TiO.sub.2 pigment manufacture in which a TiO.sub.2 -containing feedstock is subjected to a fluidized-bed, high temperature carbochlorination in a chlorinator to produce TiCl.sub.4 which is thereafter converted to TiO.sub.2 by oxidation. The TiO.sub.2 -containing feedstock and a solid carbonaceous reducing agent are fed to the chlorinator under a CO.sub.2 blanketing atmosphere such that the carbochlorination is carried out in a substantially nitrogen-free atmosphere containing CO.sub.2 and a CO.sub.2 -rich flue gas is generated, the CO.sub.2 in the chlorinator assisting in controlling thermal balance of the carbochlorination reaction. The absence of significant concentrations of nitrogen in the flue gas results in a favorable condition enabling either or both the CO and CO.sub.2 contained in the flue gas to be readily recovered, purified and sold as by-products.

Nitrogen-free process for chloride-route TiO.sub.2 pigment manufacture

In a steam generating boiler having a bottom wall supporting a char bed and sidewalls with ports through which air is admitted for combustion of combustible species in the char bed and emanating therefrom, combustion is improved by introducing an oxygen-containing gas into a lower central zone of the boiler, from at least one point remote from the sidewalls to thereby cause intimate mixing of the oxygen contained in the gas with the combustible species.

Non-peripheral blowing of oxygen-containing gas in steam generating

Molten steel, normally exposed to an atmosphere of air, is protected against impurities by placing a gas containing a major amount of carbon dioxide gas in such quantities and in such proximity to the surface to cause dissociation of the carbon dioxide at a rate which provides a gas barrier or shroud isolating the steel from the surrounding atmosphere. This method may be applied to protecting certain molten steels being transferred from a ladle to a mold, or from a ladle to a tundish and from the tundish to a mold in continuous casting. In a method where a number of shrouding operations are carried out in series, gas under pressure is bled, in increments, from a storage vessel containing a body of liquid carbon dioxide in an overlying ullage space containing vapor. Each increment is ultimately expanded and dispersed at ambient temperature to form the shroud. As each increment of vapor is removed from the vessel, it is replace by withdrawing liquid carbon dioxide, vaporizing it and returning it to the ullage space.

Molten metal casting

Molten steel, normally exposed to an atmosphere of air, is protected against pick-up of impurities by placing carbon dioxide gas in such quantities and in such proximity to the surface to cause dissociation of the carbon dioxide at a rate which furnishes an atmosphere of carbon monoxide and gives off a negligible amount of oxygen to the steel, thus providing a gas barrier or shroud isolating the steel from the surrounding atmosphere and preventing pick-up therefrom of oxygen, nitrogen or hydrogen. This method may be applied to protecting steel being transferred from a ladle to a mold, or from a ladle to a tundish and from the tundish to a mold in continuous casting. In a method where a number of shrouding operations are carried out in series, carbon dioxide vapor, under pressure, is bled, in increments, from a storage vessel containing a body of liquid carbon dioxide in overlying ullage space containing vapor. Each increment is superheated, after it leaves the vessel, and is ultimately expanded and dispersed at ambient temperature to form the shroud. As each increment of vapor is removed from the vessel, it is replaced by withdrawing liquid carbon dioxide, vaporizing it and returning it to the ullage space.

Method of and apparatus for casting metal using carbon dioxide to form

Enhanced recovery of oil from subterranean sedimentary formations by an in-situ combustion method employing a pattern of an injection well and several production wells, spaced-apart by a treatment zone. Combustion is controlled by placing at least one fluid conduit in a treatment zone and introducing a control fluid through it to modify the flame front. Oxygen may be introduced to take over from combustion air initially introduced through the injection well, to sustain combustion and advance the flame front. Water may be injected through the injection well, alternating with the oxygen through the control conduit to continue a wet combustion method started with air. The strategic placing of control conduits and the introduction of appropriate fluids may be employed to improve the sweep geometry by advancing the flame front or retarding it, or invading areas behind it. Safety means is provided for introducing the oxygen at a velocity greater than the maximum flame velocity encountered in the flame front.

Oil recovery by in-situ combustion

An oil recovery installation made up of an inner conduit for an oxidant gas and a surrounding outer conduit forming therebetween a water jacket for cooling liquid leading from an upper end at the surface through a sealing well casing to a lower end within the underground oil recovery formation. Terminal means closes the lower end of the outer conduit and provides a restricted passage in communication with the inner conduit for injecting oxygen into the formation. There is means for supplying oxidant gas under pressure to the upper end of the inner conduit and means for supplying water to circulate within the cooling jacket. There is means for controlling the supply rate of oxidant gas and means for controlling the water supply rate.

In situ combustion for oil recovery

In the injection of oxygen through a refractory lined wall into a molten metal, for example, pig iron, the injected oxygen is surrounded by a stream of a protective fluid to diminish erosion of the refractory lining; the velocities of the oxygen and protective fluid are selected to minimize eddying of the oxygen into the protective fluid so that the protective fluid retains its effectiveness for a greater distance from the injector whereby greater protection is provided to the injector and the refractory.

Method of improving the performance of submerged oxygen injectors

In the refining of metal in a bath of the molten metal, oxygen is injected into the molten metal in a stream adjacent to a stream of a protective fluid which conveys a particulate flux, which is reactive with oxygen, into the molten metal; in this way the oxygen and particulate flux are safely introduced into the interior of the molten metal.

Method of safely injecting oxygen reactive materials into a submerged

In the homogenization of molten metal with a gas, the gas is delivered to agitate the molten metal in a vessel, through an injector tube having a fine bore effective to prevent penetration of molten metal into and along the bore; when injection of gas is discontinued, molten metal is allowed to solidify on the tip of the tube to seal it; when gas is to be delivered to a second load of molten metal in the vessel, it is delivered, at least initially, at a pressure effective to unseal the tube at the tip to permit entry of the gas into the second load to agitate the molten metal and thereby homogenize it; the injector tube can be used for successive batches of molten metal without maintenance.

Homogenization of metal using gas

A biological waste water treatment carried out in a single tank. The conditions in the tank are controlled to provide a biological reaction zone containing waste water and biodegrading organisms and an overlying clarification zone from which an effluent of treated waste water flows. The recycle stream is continuously withdrawn from the biological reaction zone, supplemented with influent waste water, passed through an oxygen-dissolving device, and the supplemented stream returned to the reaction zone. The oxygen is monitored and supplied to satisfy the demands of the organisms and, at the same time, to keep the oxygen in solution. The supplemented recycle stream is continuously injected along the bottom of the biological reaction zone in a horizontal shallow inflow having a width substantially greater than its depth and a flow considerably greater than that of the influent. And, the recycle stream is withdrawn from near the bottom of the reaction zone, at a vicinity remote from the inflow, in an outflow having a substantially greater width than its depth. In this way there is created between the inflow and the outflow a horizontally relatively fast flowing undercurrent having an extensive uninterrupted interface with an overlying relatively quiescent body of mixed liquor flowing upwardly relatively slowly.

Growing community of inventors

Montreal, Canada

Robert G Lee