The Dow Chemical Company

Robert F Phillips

James A McIntyre

Joseph D Lefevre

John R Moyer

Karel A Snoble

Joseph D Lefever

Max R Oswald

John M Kalnins

The invention is an electrochemical cell comprising:

Catalyst for the electroreduction of oxygen

A method comprising contacting an organic polymer viscosified halide ion-containing, aqueous solution with a sufficient amount of an in situ, electrochemically generated breaker suitable to reduce the viscosity of the solution.

Electrochemical methods for breaking high viscosity fluids

The invention is a method for dissolving copper in the presence of iron comprising:

Method for dissolving copper in the presence of iron

The invention is a separator-gas electrode combination comprising a separator having a first and a second face adapted to permit the flow of fluids or ions therethrough; a gas electrode adapted to permit a liquid and a gas to enter and exit the electrode and having at least a first and a second face; and a non-conductive self-draining member having a fluid outlet. The self-draining member has at least two faces; at least a portion of a first face contiguous to at least a portion of one face of the separator and at least a portion of a second face contiguous to at least a portion of one face of the gas electrode. The self-draining member has a plurality of interconnected passageways which are in fluid transferring communication with the separator, the gas electrode, and the fluid outlet and provide the major conduit therebetween.

Separator-gas electrode combination

The invention includes in its scope a method for electrochemically reacting a liquid with a gas in an electrochemical cell of the type having at least two electrodes separated by a liquid permeable separator. At least one of said electrodes is in physical contact with the separator and is porous and self-draining. A gas is flowed into at least a portion of the pores of the self-draining electrode and a liquid is controllably flowed through the separator and into the self-draining electrode at a rate about equal to the drainage rate of the electrode and in a quantity sufficient to fill only a portion of the electrode pores. The liquid and the gas are electrochemically reacted to form at least one nonvolatile product. Thereafter, the products of the electrochemical reaction are removed from said self-draining electrode.

Method of operating a liquid-gas electrochemical cell

The invention includes within its scope a method for producing a dual porosity body from a substrate having a plurality of passageways traversing the substrate and connecting a first surface with a generally opposing second surface by depositing a solid material onto the walls of at least a portion of the passageways adjoining only the first surface and stopping the deposition when the diameter of the passageways being coated have been reduced to a predetermined value.

Method for producing a dual porosity body

A particle suitable for use as an electrode material comprising a substrate at least partially coated with an admixture of a hydrophobic material and an electrochemically active, electrically conductive catalyst. The invention includes a method for producing the coated particles.

Electrode material

The invention is an electrochemical cell containing a separator-gas electrode combination comprising a separator having a first and a second face adapted to permit the flow of fluids or ions therethrough; a gas electrode adapted to permit a liquid and a gas to enter and exit the electrode and having at least a first and a second face; and a nonconductive self-draining member having a fluid outlet. The self-draining member has at least two faces; at least a portion of a first face contiguous to at least a portion of one face of the separator and at least a portion of a second face contiguous to at least a portion of one face of the gas electrode. The self-draining member has a plurality of interconnected passageways which are in fluid transferring communication with the separator, the gas electrode, and the fluid outlet and provide the major conduit therebetween. The invention also includes a method for electrochemically reacting a gas with a liquid in the cell above.

Electrochemical cell having a separator-gas electrode combination

An improved aqueous electrolyte solution adapted to minimize the decomposition of peroxide formed during electrolysis comprising an alkali metal compound, an impurity catalytically active for the decomposition of peroxides and a stabilizing agent at a concentration sufficient to render at least a portion of the catalytically active materials inactive. The invention also includes a process for the production of peroxides which comprises electrolyzing the solution described above.

Method for electrolytic production of alkaline peroxide solutions

A porous, two layer electrode which may be used as an anode or a cathode and a cell using one or more of the electrodes. The electrode is in a pocket shaped configuration with the inner layer having interstitial passageways which are larger in diameter than the diameter of the corresponding interstitial passageways in the outer layer. The layers may be composed of metallic particles. A catalytically active material may be applied to the electrode. The electrodes are particularly useful as oxygen depolarized cathodes in electrolytic processes.

Electrolytic process using oxygen-depolarized cathodes

The invention includes in its scope a method for electrochemically reacting a liquid with a gas in an electrochemical cell of the type having at least two electrodes separated by a liquid permeable separator. At least one of said electrodes supports the separator and is porous and self-draining. A gas is flowed into at least a portion of the pores of the self-draining electrode and a liquid is controllably flowed through the separator and into the self-draining electrode at a rate about equal to the drainage rate of the electrode and in a quantity sufficient to fill only a portion of the electrode pores. The liquid and the gas are electrochemically reacted to form at least one nonvolatile product. Thereafter, the products of the electrochemical reaction are removed from said self-draining electrode.

A permeable substrate is coated with a film of silver deposited from an aqueous electroless silver plating solution. The process provides substantially total extraction or depletion of the silver from the solution. The process permits deposition of closely controlled amounts of silver on well-defined permeable areas.

Process for silver coating of permeable substrates

A process for operating an electrolytic cell having a relatively-massive dual porosity gas electrode particularly well suited and adapted for utilization as a vertically-disposed oxygen gas-bearing electrochemically reducing cathode in electrolytic cells wherein, for efficient and practical, commercially-large-scale-output operations, there are required to be employed substantial electrolyte liquid depths creating considerable head pressures generally greater than at least about 1 psi (ca. 0.69 dynes/cm.sup.2) is comprised of distinct juxtaposed, contiguous, yet separate, diversely porous electrode body wall members or layer sections, one of which for immediate electrolyte contact and handling is of relatively finer pored structure and the other of which for immediate gas contact and handling is of relatively larger or coarse pored structure; the electrode being so embodied and characterizable for given application as to have a bubble point pressure that is larger than the summation of the hydraulic head pressure and the liquid capillary pressure in the coarse pore layer.

Growing community of inventors

Midland, MI, United States of America

Robert F Phillips